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Nano Research 2022, 15(2): 1492-1499 https://doi.org/10.1007/s12274-021-3693-4
Research Article | Issue | Published: 17 August 2021

In-situ selective surface engineering of graphene micro-supercapacitor chips

Show Author's Information Yiming Chen1,§,  Minghao Guo1,§,  Lin Xu1,2( ),  Yuyang Cai1,  Xiaocong Tian1,3,  Xiaobin Liao1,  Zhaoyang Wang1,  Jiashen Meng1,  Xufeng Hong1,  Liqiang Mai1,2( )
State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070 China
Foshan Xianhu Laboratory of the Advanced Energy Science and Technology Guangdong Laboratory Xianhu Hydrogen ValleyFoshan 528200 China
Faculty of Materials Science & Chemistry China University of GeosciencesWuhan 430074 China

§ Yiming Chen and Minghao Guo contributed equally to this work.

Keywords:
micro-supercapacitors, 3D-printing, in-situ modification, selective surface engineering, edge-welded graphene
Topics:
Electrolytic capacitors
Cite this article:
Chen Y, Guo M, Xu L, et al. In-situ selective surface engineering of graphene micro-supercapacitor chips. Nano Research, 2022, 15(2): 1492-1499. https://doi.org/10.1007/s12274-021-3693-4
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Abstract Full text Electronic supplementary material About this article

Surface modification of graphene oxide (GO) is a powerful strategy to develop its energy density for electrochemical energy storage. However, pre-modified GO always exhibits unsatisfactory hydrophilia and its ink-relevant utilization is extremely limited. Although GO ink is widely utilized in fabricating micro energy storage devices via extrusion-based 3D-printing, simultaneously obtaining satisfactory hydrophilia and high energy density still remains a challenge. In this work, an in-situ surface engineering strategy was employed to enhance the performance of GO micro-supercapacitor chips. Three dimensionally printed GO micro-supercapacitor chips were treated with pyrrole monomer to achieve selective and spontaneous anchoring of polypyrrole on the microelectrodes without affecting interspaces between the finger electrodes. The interface-reinforced graphene scaffolds were edge-welded and exhibited a considerably improved specific capacitance, from 13.6 to 128.4 mF·cm−2. These results are expected to provide a new method for improving the performance of micro-supercapacitors derived from GO inks and further strengthen the practicability of 3D printing techniques in fabricating energy storage devices.


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Electronic supplementary material
About this article

In-situ selective surface engineering of graphene micro-supercapacitor chips

Show Author's information Yiming Chen1,§, Minghao Guo1,§, Lin Xu1,2( ), Yuyang Cai1, Xiaocong Tian1,3, Xiaobin Liao1, Zhaoyang Wang1, Jiashen Meng1, Xufeng Hong1, Liqiang Mai1,2( )
State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of TechnologyWuhan 430070 China
Foshan Xianhu Laboratory of the Advanced Energy Science and Technology Guangdong Laboratory Xianhu Hydrogen ValleyFoshan 528200 China
Faculty of Materials Science & Chemistry China University of GeosciencesWuhan 430074 China

§ Yiming Chen and Minghao Guo contributed equally to this work.

Abstract

Surface modification of graphene oxide (GO) is a powerful strategy to develop its energy density for electrochemical energy storage. However, pre-modified GO always exhibits unsatisfactory hydrophilia and its ink-relevant utilization is extremely limited. Although GO ink is widely utilized in fabricating micro energy storage devices via extrusion-based 3D-printing, simultaneously obtaining satisfactory hydrophilia and high energy density still remains a challenge. In this work, an in-situ surface engineering strategy was employed to enhance the performance of GO micro-supercapacitor chips. Three dimensionally printed GO micro-supercapacitor chips were treated with pyrrole monomer to achieve selective and spontaneous anchoring of polypyrrole on the microelectrodes without affecting interspaces between the finger electrodes. The interface-reinforced graphene scaffolds were edge-welded and exhibited a considerably improved specific capacitance, from 13.6 to 128.4 mF·cm−2. These results are expected to provide a new method for improving the performance of micro-supercapacitors derived from GO inks and further strengthen the practicability of 3D printing techniques in fabricating energy storage devices.

Keywords: micro-supercapacitors, 3D-printing, in-situ modification, selective surface engineering, edge-welded graphene

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Publication history
Copyright
Acknowledgements

Publication history

Received: 11 April 2021
Revised: 07 June 2021
Accepted: 16 June 2021
Published: 17 August 2021
Issue date: February 2022

Copyright

© Tsinghua University Press and Springer-Verlag GmbH Germany, part of Springer Nature 2021

Acknowledgements

Acknowledgements

This work was supported by the National Key Research and Development Program of China (No. 2020YFA715000), the National Natural Science Foundation of China (No. 51802239), the National Key Research and Development Program of China (No. 2019YFA0704902), Foshan Xianhu Laboratory of the Advanced Energy Science and Technology Guangdong Laboratory (Nos. XHT2020-005 and XHT2020-003), the Natural Science Foundation of Hubei Province (No. 2019CFA001), the Fundamental Research Funds for the Central Universities (Nos. 2020III011GX, 2020IVB057, 2019IVB054, 2019III062JL, and 2019-YB-008).

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