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Research Article

N, P-codoped graphene supported few-layered MoS2 as a long-life and high-rate anode materials for potassium-ion storage

Guangyao Ma1, Yanli Zhou2( ), Yingying Wang3, Zhenyu Feng1, Jian Yang1,4( )
Key Laboratory of Colloid and Interface Chemistry,Ministry of Education, School of Chemistry and Chemical Engineering, Shandong University,Jinan,250100,China;
School of Environmental and Materials Engineering,Yantai University,Yantai,264005,China;
Shandong Vocational College of Light Industry,Zibo 255300, China 4Shenzhen Research Institute of Shandong University,Shenzhen,518000,China;
Shenzhen Research Institute of Shandong University,Shenzhen,518000,China;
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Graphical Abstract

Abstract

Layer-structured MoS2 is regarded as a promising anode material for potassium ion batteries. Herein, MoS2 nanosheets on N, P-codoping reduced graphene oxide (MoS2/N, P-rGO) have been successfully prepared via a facile two-step synthesis, where few-layered MoS2 nanosheets are chemically bonded onto the surface of N, P-rGO. As an anode material, MoS2/N, P-rGO exhibits a high specific capacity (462.7 mAhdg-1 at 100 mAdg-1 over 200 cycles), outstanding rate capability (224.9 mAhdg-1 at 20 Adg-1), and excellent cycle life (236.6 mAhdg-1 at 2 Adg-1 after 7, 000 cycles), much better than those of MoS2 and MoS2/rGO. These advanced performances outperform most of the reported anode materials for potassium ion batteries to date. Meanwhile, the K-storage reactions of MoS2/N, P-rGO have been disclosed through in-situ and ex-situ characterizations. The kinetics analysis confirms that K-storage of MoS2/N, P-rGO is predominant by pseudo-capacitance.

Keywords

MoS2heteroatom dopingelectrochemical reactionsanode materialspotassium-ion batteries

Electronic Supplementary Material

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Nano Research
Volume 14 Issue 10,
October 2021
Pages 3523-3530
DOI: 10.1007/s12274-021-3606-6
Cite this article:
Ma G, Zhou Y, Wang Y, et al. N, P-codoped graphene supported few-layered MoS2 as a long-life and high-rate anode materials for potassium-ion storage. Nano Research, 2021, 14(10): 3523-3530. https://doi.org/10.1007/s12274-021-3606-6
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Received: 14 March 2021
Revised: 18 May 2021
Accepted: 19 May 2021
Published: 04 June 2021
© Tsinghua University Press and Springer-Verlag GmbH Germany, part of Springer Nature 2021
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