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Nano Research 2022, 15(1): 285-295 https://doi.org/10.1007/s12274-021-3472-2
Research Article | Issue | Published: 24 April 2021

Ultrahigh rate capability of 1D/2D polyaniline/titanium carbide (MXene) nanohybrid for advanced asymmetric supercapacitors

Show Author's Information Jinhua Zhou1,  Qi Kang2,  Shuchi Xu1,  Xiaoge Li1,  Cong Liu1,  Lu Ni1,  Ningna Chen1,  Chunliang Lu3,  Xizhang Wang1,  Luming Peng1,  Xuefeng Guo1,  Weiping Ding1,  Wenhua Hou1( )
Key Laboratory of Mesoscopic Chemistry of MOE, School of Chemistry and Chemical Engineering Nanjing UniversityNanjing 210023 China
Department of Polymer Science and Engineering, Shanghai Key Laboratory of Electrical Insulation and Thermal Aging Shanghai Jiao Tong UniversityShanghai 200240 China
Analytical Testing Center Yangzhou UniversityYangzhou 225009 China
Keywords:
MXene, rate capability, polyaniline, asymmetric supercapacitor, nanohybrid
Topics:
Supercapacitor
Cite this article:
Zhou J, Kang Q, Xu S, et al. Ultrahigh rate capability of 1D/2D polyaniline/titanium carbide (MXene) nanohybrid for advanced asymmetric supercapacitors. Nano Research, 2022, 15(1): 285-295. https://doi.org/10.1007/s12274-021-3472-2
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Abstract Full text Electronic supplementary material About this article

High energy density and enhanced rate capability are highly sought-after for supercapacitors in today's mobile world. In this work, polyaniline/titanium carbide (MXene) (PANI/Ti3C2Tx) nanohybrid is synthesized through a facile and cost-effective self-assembly of one-dimensional (1D) PANI nanofibers and two-dimensional (2D) Ti3C2Tx nanosheets. PANI/Ti3C2Tx delivers greatly improved specific capacitance, ultrahigh rate capability (67% capacitance retention from 1 to 100 A·g−1) as well as good cycle stability. Electrochemical kinetic analysis reveals that PANI/Ti3C2Tx is featured with surface capacitance-dominated process and has a quasi-reversible kinetics at high scan rates, giving rise to an ultrahigh rate capability. By using PANI/Ti3C2Tx as positive electrode, an 1.8 V aqueous asymmetric supercapacitor (ASC) is successfully assembled, showing a maximum energy density of 50.8 Wh·kg−1 (at 0.9 kW·kg−1) and a power density of 18 kW·kg−1 (at 26 Wh·kg−1). Moreover, an 3.0 V organic ASC is also elaborately fabricated by using PANI/Ti3C2Tx, achieving an ultrahigh energy density of 67.2 Wh·kg−1 (at 1.5 kW·kg−1) and a power density of 30 kW·kg−1 (at 26.8 Wh·kg−1). The present work not only improves fundamental understanding of the structure-property relationship towards ultrahigh rate capability electrode materials, but also provides valuable guideline for the rational design of high-performance energy storage devices with both high energy and power densities.


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Electronic supplementary material
About this article

Ultrahigh rate capability of 1D/2D polyaniline/titanium carbide (MXene) nanohybrid for advanced asymmetric supercapacitors

Show Author's information Jinhua Zhou1, Qi Kang2, Shuchi Xu1, Xiaoge Li1, Cong Liu1, Lu Ni1, Ningna Chen1, Chunliang Lu3, Xizhang Wang1, Luming Peng1, Xuefeng Guo1, Weiping Ding1, Wenhua Hou1( )
Key Laboratory of Mesoscopic Chemistry of MOE, School of Chemistry and Chemical Engineering Nanjing UniversityNanjing 210023 China
Department of Polymer Science and Engineering, Shanghai Key Laboratory of Electrical Insulation and Thermal Aging Shanghai Jiao Tong UniversityShanghai 200240 China
Analytical Testing Center Yangzhou UniversityYangzhou 225009 China

Abstract

High energy density and enhanced rate capability are highly sought-after for supercapacitors in today's mobile world. In this work, polyaniline/titanium carbide (MXene) (PANI/Ti3C2Tx) nanohybrid is synthesized through a facile and cost-effective self-assembly of one-dimensional (1D) PANI nanofibers and two-dimensional (2D) Ti3C2Tx nanosheets. PANI/Ti3C2Tx delivers greatly improved specific capacitance, ultrahigh rate capability (67% capacitance retention from 1 to 100 A·g−1) as well as good cycle stability. Electrochemical kinetic analysis reveals that PANI/Ti3C2Tx is featured with surface capacitance-dominated process and has a quasi-reversible kinetics at high scan rates, giving rise to an ultrahigh rate capability. By using PANI/Ti3C2Tx as positive electrode, an 1.8 V aqueous asymmetric supercapacitor (ASC) is successfully assembled, showing a maximum energy density of 50.8 Wh·kg−1 (at 0.9 kW·kg−1) and a power density of 18 kW·kg−1 (at 26 Wh·kg−1). Moreover, an 3.0 V organic ASC is also elaborately fabricated by using PANI/Ti3C2Tx, achieving an ultrahigh energy density of 67.2 Wh·kg−1 (at 1.5 kW·kg−1) and a power density of 30 kW·kg−1 (at 26.8 Wh·kg−1). The present work not only improves fundamental understanding of the structure-property relationship towards ultrahigh rate capability electrode materials, but also provides valuable guideline for the rational design of high-performance energy storage devices with both high energy and power densities.

Keywords: MXene, rate capability, polyaniline, asymmetric supercapacitor, nanohybrid

References(88)

1

Abruña, H. D.; Kiya, Y.; Henderson, J. C. Batteries and electrochemical capacitors. Phys. Today 2008, 61, 43–47.
DOI Google Scholar
2

Chen, T.; Xu, Y. D.; Guo, S. Q.; Wei, D. L.; Peng, L. M.; Guo, X. F.; Xue, N. H.; Zhu, Y.; Chen, Z. X.; Zhao, B. et al. Ternary heterostructural Pt/CNx/Ni as a supercatalyst for oxygen reduction. iScience 2019, 11, 388–397.
DOI Google Scholar
3

Zhuang, Z. C.; Li, Y.; Huang, J. Z.; Li, Z. L.; Zhao, K. N.; Zhao, Y. L.; Xu, L.; Zhou, L.; Moskaleva, L. V.; Mai, L. Q. Sisyphus effects in hydrogen electrochemistry on metal silicides enabled by silicene subunit edge. Sci. Bull. 2019, 64, 617–624.
DOI Google Scholar
4

Xu, L.; Zhao, Y. L.; Owusu, K. A.; Zhuang, Z. C.; Liu, Q.; Wang, Z. Y.; Li, Z. H.; Mai, L. Q. Recent advances in nanowire-biosystem interfaces: From chemical conversion, energy production to electrophysiology. Chem 2018, 4, 1538–1559.
DOI Google Scholar
5

Simon, P.; Gogotsi, Y.; Dunn, B. Where do batteries end and supercapacitors begin? Science 2014, 343, 1210–1211.
DOI Google Scholar
6

Zhang, G. W.; Yao, H.; Zhang, F.; Gao, Z. T.; Li, Q. J.; Yang, Y. Y.; Lu, X. H. A high over-potential binder-free electrode constructed of prussian blue and MnO2 for high performance aqueous supercapacitors. Nano Res. 2019, 12, 1061–1069.
DOI Google Scholar
7

Wu, C. X.; Zhang, Z. F.; Chen, Z. H.; Jiang, Z. M.; Li, H. Y.; Cao, H. J.; Liu, Y. S.; Zhu, Y. Y.; Fang, Z. B.; Yu, X. R. Rational design of novel ultra-small amorphous Fe2O3 nanodots/graphene heterostructures for all-solid-state asymmetric supercapacitors. Nano Res. 2021, 14, 953–960.
DOI Google Scholar
8

Shao, Y. L.; El-Kady, M. F.; Sun, J. Y.; Li, Y. G.; Zhang, Q. H.; Zhu, M. F.; Wang, H. Z.; Dunn, B.; Kaner, R. B. Design and mechanisms of asymmetric supercapacitors. Chem. Rev. 2018, 118, 9233–9280.
DOI Google Scholar
9

Xiao, D. W.; Dou, Q. Y.; Zhang, L.; Ma, Y. L.; Shi, S. Q.; Lei, S. L.; Yu, H. Y.; Yan, X. B. Optimization of organic/water hybrid electrolytes for high-rate carbon-based supercapacitor. Adv. Funct. Mater. 2019, 29, 1904136.
DOI Google Scholar
10

Ding, J.; Hu, W. B.; Paek, E.; Mitlin, D. Review of hybrid ion capacitors: From aqueous to lithium to sodium. Chem. Rev. 2018, 118, 6457–6498.
DOI Google Scholar
11

Augustyn, V.; Simon, P.; Dunn, B. Pseudocapacitive oxide materials for high-rate electrochemical energy storage. Energy Environ. Sci. 2014, 7, 1597–1614.
DOI Google Scholar
12

Lin, T. Q.; Chen, I. W.; Liu, F. X.; Yang, C. Y.; Bi, H.; Xu, F. F.; Huang, F. Q. Nitrogen-doped mesoporous carbon of extraordinary capacitance for electrochemical energy storage. Science 2015, 350, 1508–1513.
DOI Google Scholar
13

Tie, D.; Huang, S. F.; Wang, J.; Ma, J. M.; Zhang, J. J.; Zhao, Y. F. Hybrid energy storage devices: Advanced electrode materials and matching principles. Energy Storage Mater. 2019, 21, 22–40.
DOI Google Scholar
14

Mao, N.; Wang, H. L.; Sui, Y.; Cui, Y. P.; Pokrzywinski, J.; Shi, J.; Liu, W.; Chen, S. G.; Wang, X.; Mitlin, D. Extremely high-rate aqueous supercapacitor fabricated using doped carbon nanoflakes with large surface area and mesopores at near-commercial mass loading. Nano Res. 2017, 10, 1767–1783.
DOI Google Scholar
15

Snook, G. A.; Kao, P.; Best, A. S. Conducting-polymer-based supercapacitor devices and electrodes. J. Power Sources 2011, 196, 1–12.
DOI Google Scholar
16

Wang, Y. Q.; Ding, Y.; Guo, X. L.; Yu, G. H. Conductive polymers for stretchable supercapacitors. Nano Res. 2019, 12, 1978–1987.
DOI Google Scholar
17

Zhang, K.; Zhang, L. L.; Zhao, X. S.; Wu, J. S. Graphene/polyaniline nanofiber composites as supercapacitor electrodes. Chem. Mater. 2010, 22, 1392–1401.
DOI Google Scholar
18

Wang, K.; Meng, Q. H.; Zhang, Y. J.; Wei, Z. X.; Miao, M. H. High-performance two-ply yarn supercapacitors based on carbon nanotubes and polyaniline nanowire arrays. Adv. Mater. 2013, 25, 1494–1498.
DOI Google Scholar
19

Ge, J.; Cheng, G. H.; Chen, L. W. Transparent and flexible electrodes and supercapacitors using polyaniline/single-walled carbon nanotube composite thin films. Nanoscale 2011, 3, 3084–3088.
DOI Google Scholar
20

Li, X. W.; Zhang, H.; Wang, G. C.; Jiang, Z. H. A novel electrode material based on a highly homogeneous polyaniline/titanium oxide hybrid for high-rate electrochemical capacitors. J. Mater. Chem. 2010, 20, 10598–10601.
DOI Google Scholar
21

Jun, B. M.; Kim, S.; Heo, J.; Park, C. M.; Her, M.; Jang, M.; Huang, Y.; Han, J.; Yoon, Y. Review of MXenes as new nanomaterials for energy storage/delivery and selected environmental applications. Nano Res. 2019, 12, 471–487.
DOI Google Scholar
22

Naguib, M.; Mochalin, V. N.; Barsoum, M. W.; Gogotsi, Y. 25th anniversary article: MXenes: A new family of two-dimensional materials. Adv. Mater. 2014, 26, 992–1005.
DOI Google Scholar
23
Hu, D. W.; Wang, S. Q.; Zhang, C.; Yi, P. S.; Jiang, P. K.; Huang, X. Y. Ultrathin MXene-aramid nanofiber electromagnetic interference shielding films with tactile sensing ability withstanding harsh temperatures. Nano Res. in press, DOI: 10.1007/s12274-021-3297-zhttps://doi.org/10.1007/s12274-021-3297-z
DOI
24

Khazaei, M.; Arai, M.; Sasaki, T.; Chung, C. Y.; Venkataramanan, N. S.; Estili, M.; Sakka, Y.; Kawazoe, Y. Novel electronic and magnetic properties of two-dimensional transition metal carbides and nitrides. Adv. Funct. Mater. 2013, 23, 2185–2192.
DOI Google Scholar
25

Halim, J.; Lukatskaya, M. R.; Cook, K. M.; Lu, J.; Smith, C. R.; Näslund, L. Å.; May, S. J.; Hultman, L.; Gogotsi, Y.; Eklund, P. et al. Transparent conductive two-dimensional titanium carbide epitaxial thin films. Chem. Mater. 2014, 26, 2374–2381.
DOI Google Scholar
26

VahidMohammadi, A.; Moncada, J.; Chen, H. Z.; Kayali, E.; Orangi, J.; Carrero, C. A.; Beidaghi, M. Thick and freestanding MXene/PANI pseudocapacitive electrodes with ultrahigh specific capacitance. J. Mater. Chem. A 2018, 6, 22123–22133.
DOI Google Scholar
27

Fu, J. J.; Yun, J. M.; Wu, S. X.; Li, L.; Yu, L. T.; Kim, K. H. Architecturally robust graphene-encapsulated MXene Ti2CTx@polyaniline composite for high-performance pouch-type asymmetric supercapacitor. ACS Appl. Mater. Interfaces 2018, 10, 34212–34221.
DOI Google Scholar
28

Li, K.; Wang, X. H.; Li, S.; Urbankowski, P.; Li, J. M.; Xu, Y. X.; Gogotsi, Y. An ultrafast conducting polymer@MXene positive electrode with high volumetric capacitance for advanced asymmetric supercapacitors. Small 2020, 16, 1906851.
DOI Google Scholar
29

Lukatskaya, M. R.; Mashtalir, O.; Ren, C. E.; Dall'Agnese, Y.; Rozier, P.; Taberna, P. L.; Naguib, M.; Simon, P.; Barsoum, M. W.; Gogotsi, Y. Cation intercalation and high volumetric capacitance of two-dimensional titanium carbide. Science 2013, 341, 1502–1505.
DOI Google Scholar
30

Hummers, W. S. Jr.; Offeman, R. E. Preparation of graphitic oxide. J. Am. Chem. Soc. 1958, 80, 1339.
DOI Google Scholar
31

Yang, G. Y.; Shao, S.; Ke, Y. H.; Liu, C. L.; Ren, H. F.; Dong, W. S. PtAu alloy nanoparticles supported on thermally expanded graphene oxide as a catalyst for the selective oxidation of glycerol. RSC Adv. 2015, 5, 37112–37118.
DOI Google Scholar
32

Li, X. G.; Guan, B. Y.; Gao, S. Y.; Lou, X. W. A general dual- templating approach to biomass-derived hierarchically porous heteroatom-doped carbon materials for enhanced electrocatalytic oxygen reduction. Energy Environ. Sci. 2019, 12, 648–655.
DOI Google Scholar
33

Alhabeb, M.; Maleski, K.; Anasori, B.; Lelyukh, P.; Clark, L.; Sin, S.; Gogotsi, Y. Guidelines for synthesis and processing of two-dimensional titanium carbide (Ti3C2Tx MXene). Chem. Mater. 2017, 29, 7633– 7644.
DOI Google Scholar
34

Li, J.; Yuan, X. T.; Lin, C.; Yang, Y. Q.; Xu, L.; Du, X.; Xie, J. L.; Lin, J. H.; Sun, J. L. Achieving high pseudocapacitance of 2D titanium carbide (MXene) by cation intercalation and surface modification. Adv. Energy Mater. 2017, 7, 1602725.
DOI Google Scholar
35

Xu, S.; Du, C. Y.; Xu, X.; Han, G. K.; Zuo, P. J.; Cheng, X. Q.; Ma, Y. L.; Yin, G. P. A mild surface washing method using protonated polyaniline for Ni-rich LiNi0.8Co0.1Mn0.1O2 material of lithium ion batteries. Electrochim. Acta 2017, 248, 534–540.
DOI Google Scholar
36

Mahmood, Q.; Park, S. K.; Kwon, K. D.; Chang, S. J.; Hong, J. Y.; Shen, G. Z.; Jung, Y. M.; Park, T. J.; Khang, S. W.; Kim, W. S. et al. Transition from diffusion-controlled intercalation into extrinsically pseudocapacitive charge storage of MoS2 by nanoscale heterostructuring. Adv. Energy Mater. 2016, 6, 1501115.
DOI Google Scholar
37

Zhang, C. J.; Pinilla, S.; McEvoy, N.; Cullen, C. P.; Anasori, B.; Long, E.; Park, S. H.; Seral-Ascaso, A.; Shmeliov, A.; Krishnan, D. et al. Oxidation stability of colloidal two-dimensional titanium carbides (MXenes). Chem. Mater. 2017, 29 4848–4856.
DOI Google Scholar
38

Boles, M. A.; Engel, M.; Talapin, D. V. Self-assembly of colloidal nanocrystals: From intricate structures to functional materials. Chem. Rev. 2016, 116, 11220–11289.
DOI Google Scholar
39

Lipatov, A.; Alhabeb, M.; Lukatskaya, M. R.; Boson, A.; Gogotsi, Y.; Sinitskii, A. Effect of synthesis on quality, electronic properties and environmental stability of individual monolayer Ti3C2 MXene flakes. Adv. Electron. Mater. 2016, 2, 1600255.
DOI Google Scholar
40

Luo, J. M.; Tao, X. Y.; Zhang, J.; Xia, Y.; Huang, H.; Zhang, L. Y.; Gan, Y. P.; Liang, C.; Zhang, W. K. Sn4+ ion decorated highly conductive Ti3C2 MXene: Promising lithium-ion anodes with enhanced volumetric capacity and cyclic performance. ACS Nano 2016, 10, 2491–2499.
DOI Google Scholar
41

Lian, P. C.; Dong, Y. F.; Wu, Z. S.; Zheng, S. H.; Wang, X. H.; Wang, S.; Sun, C. L.; Qin, J. Q.; Shi, X. Y.; Bao, X. H. Alkalized Ti3C2 MXene nanoribbons with expanded interlayer spacing for high-capacity sodium and potassium ion batteries. Nano Energy 2017, 40, 1–8.
DOI Google Scholar
42

Chen, N. N.; Ni, L.; Zhou, J. H.; Zhu, G. Y.; Kang, Q.; Zhang, Y.; Chen, S. Y.; Zhou, W. X.; Lu, C. L.; Chen, J. et al. Sandwich-like holey graphene/PANI/graphene nanohybrid for ultrahigh-rate supercapacitor. ACS Appl. Energy Mater. 2018, 1, 5189–5197.
Google Scholar
43

Naguib, M.; Mashtalir, O.; Lukatskaya, M. R.; Dyatkin, B.; Zhang, C. F.; Presser, V.; Gogotsi, Y.; Barsoum, M. W. One-step synthesis of nanocrystalline transition metal oxides on thin sheets of disordered graphitic carbon by oxidation of MXenes. Chem. Commun. 2014, 50, 7420–7423.
DOI Google Scholar
44

Wang, Q.; Yao, Q.; Chang, J.; Chen, L. D. Enhanced thermoelectric properties of CNT/PANI composite nanofibers by highly orienting the arrangement of polymer chains. J. Mater. Chem. 2012, 22, 17612– 17618.
DOI Google Scholar
45

Li, D. J.; Li, Y.; Feng, Y. Y.; Hu, W. P.; Feng, W. Hierarchical graphene oxide/polyaniline nanocomposites prepared by interfacial electrochemical polymerization for flexible solid-state supercapacitors. J. Mater. Chem. A 2015, 3, 2135–2143.
DOI Google Scholar
46

Wen, Y. Y.; Rufford, T. E.; Chen, X. Z.; Li, N.; Lyu, M.; Dai, L. M.; Wang, L. Z. Nitrogen-doped Ti3C2Tx MXene electrodes for high- performance supercapacitors. Nano Energy 2017, 38, 368–376.
DOI Google Scholar
47

Li, H. B.; Yu, M. H.; Wang, F. X.; Liu, P.; Liang, Y.; Xiao, J.; Wang, C. X.; Tong, Y. X.; Yang, G. W. Amorphous nickel hydroxide nanospheres with ultrahigh capacitance and energy density as electrochemical pseudocapacitor materials. Nat. Commun. 2013, 4, 1894.
DOI Google Scholar
48

Yan, J.; Ren, C. E.; Maleski, K.; Hatter, C. B.; Anasori, B.; Urbankowski, P.; Sarycheva, A.; Gogotsi, Y. Flexible MXene/graphene films for ultrafast supercapacitors with outstanding volumetric capacitance. Adv. Funct. Mater. 2017, 27, 1701264.
DOI Google Scholar
49

Ma, Z. Y.; Zhou, X. F.; Deng, W.; Lei, D.; Liu, Z. P. 3D porous MXene (Ti3C2)/reduced graphene oxide hybrid films for advanced lithium storage. ACS Appl. Mater. Interfaces 2018, 10, 3634–3643.
DOI Google Scholar
50

Wang, J.; Polleux, J.; Lim, J.; Dunn, B. Pseudocapacitive contributions to electrochemical energy storage in TiO2 (Anatase) nanoparticles. J. Phys. Chem. C 2007, 111, 14925–14931.
DOI Google Scholar
51

Yan, J.; Wei, T.; Fan, Z. J.; Qian, W. Z.; Zhang, M. L.; Shen, X. D.; Wei, F. Preparation of graphene nanosheet/carbon nanotube/polyaniline composite as electrode material for supercapacitors. J. Power Sources 2010, 195, 3041–3045.
DOI Google Scholar
52

Lesel, B. K.; Ko, J. S.; Dunn, B.; Tolbert, S. H. Mesoporous LixMn2O4 thin film cathodes for lithium-ion pseudocapacitors. ACS Nano 2016, 10, 7572–7581.
DOI Google Scholar
53

Nicholson, R. S. Theory and application of cyclic voltammetry for measurement of electrode reaction kinetics. Anal. Chem. 1965, 37, 1351–1355.
DOI Google Scholar
54

Shen, J. L.; Yang, C. Y.; Li, X. W.; Wang, G. C. High-performance asymmetric supercapacitor based on nanoarchitectured polyaniline/ graphene/carbon nanotube and activated graphene electrodes. ACS Appl. Mater. Interfaces 2013, 5, 8467–8476.
DOI Google Scholar
55

Zhao, X.; Chen, C. Y.; Huang, Z. L.; Jin, L.; Zhang, J. X.; Li, Y. Z.; Zhang, L. L.; Zhang, Q. H. Rational design of polyaniline/MnO2/carbon cloth ternary hybrids as electrodes for supercapacitors. RSC Adv. 2015, 5, 66311–66317.
DOI Google Scholar
56

Cai, J. J.; Kong, L. B.; Zhang, J.; Luo, Y. C.; Kang, L. A novel polyaniline/ mesoporous carbon nano-composite electrode for asymmetric supercapacitor. Chin. Chem. Lett. 2010, 21, 1509–1512.
DOI Google Scholar
57

Yu, P. P.; Zhang, Z. M.; Zheng, L. X.; Teng, F.; Hu, L. F.; Fang, X. S. A novel sustainable flour derived hierarchical nitrogen-doped porous carbon/polyaniline electrode for advanced asymmetric supercapacitors. Adv. Energy Mater. 2016, 6, 1601111.
DOI Google Scholar
58

Yang, J.; Yu, C.; Fan, X. M.; Liang, S. X.; Li, S. F.; Huang, H. W.; Ling, Z.; Hao, C.; Qiu, J. S. Electroactive edge site-enriched nickel- cobalt sulfide into graphene frameworks for high-performance asymmetric supercapacitors. Energy Environ. Sci. 2016, 9, 1299–1307.
DOI Google Scholar
59

Chen, T.; Li, S. Z.; Wen, J.; Gui, P. B.; Guo, Y. X.; Guan, C.; Liu, J. P.; Fang, G. J. Rational construction of hollow core-branch CoSe2 nanoarrays for high-performance asymmetric supercapacitor and efficient oxygen evolution. Small 2018, 14, 1700979.
DOI Google Scholar
60

Li, L. L.; Peng, S. J.; Wu, H. B.; Yu, L.; Madhavi, S.; Lou, X. W. A flexible quasi-solid-state asymmetric electrochemical capacitor based on hierarchical porous V2O5 nanosheets on carbon nanofibers. Adv. Energy Mater. 2015, 5, 1500753.
DOI Google Scholar
61

Li, H. Y.; Hou, Y.; Wang, F. X.; Lohe, M. R.; Zhuang, X. D.; Niu, L.; Feng, X. L. Flexible all-solid-state supercapacitors with high volumetric capacitances boosted by solution processable MXene and electrochemically exfoliated graphene. Adv. Energy Mater. 2017, 7, 1601847.
DOI Google Scholar
62

Yang, C. Q.; Schellhammer, K. S.; Ortmann, F.; Sun, S.; Dong, R. H.; Karakus, M.; Mics, Z.; Löffler, M.; Zhang, F.; Zhuang, X. D. et al. Coordination polymer framework based on-chip micro-supercapacitors with AC line-filtering performance. Angew. Chem. , Int. Ed. 2017, 56, 3920–3924.
DOI Google Scholar
63

Fu, J.; Yun, J.; Wu, S.; Li, L.; Yu, L.; Kim, K. H. Architecturally robust graphene-encapsulated MXene Ti2CTx@polyaniline composite for high-performance pouch-type asymmetric supercapacitor. ACS Appl Mater Interfaces 2018, 10, 34212-34221.
DOI Google Scholar
64

Li, K.; Wang, X.; Li, S.; Urbankowski, P.; Li, J.; Xu, Y.; Gogotsi, Y. An ultrafast conducting polymer@MXene positive electrode with high volumetric capacitance for advanced asymmetric supercapacitors. Small 2020, 16, 1906851.
DOI Google Scholar
65

Salinas-Torres, D.; Sieben, J. M.; Lozano-Castelló, D.; Cazorla-Amorós, D.; Morallón, E. Asymmetric hybrid capacitors based on activated carbon and activated carbon fibre-PANI electrodes, Electrochim. Acta 2013, 89, 326-333.
DOI Google Scholar
66

Cai, J. J.; Kong, L. B.; Zhang, J.; Luo, Y. C.; Kang, L. A novel polyaniline/mesoporous carbon nano-composite electrode for asymmetric supercapacitor, Chinese Chem. Lett. 2010, 21, 1509-1512.
DOI Google Scholar
67

Shen, J.; Yang, C.; Li, X.; Wang, G.; High-performance asymmetric supercapacitor based on graphene hydrogel and nanostructured MnO2, ACS Appl. Mater. Interaces 2013, 5, 8467-8476.
DOI Google Scholar
68

Zhou, S.; Zhang, H.; Zhao, Q.; Wang, X.; Li, J.; Wang, F. Graphene-wrapped polyaniline nanofibers as electrode materials for organic supercapacitors, Carbon 2013, 52, 440-450.
DOI Google Scholar
69

Zhao, X.; Chen, C.; Huang, Z.; Jin, L.; Zhang, J.; Li, Y.; Zhang, L.; Zhang, Q. Green and all-carbon asymmetric supercapacitor based on polyaniline nanotubes and anthraquinone functionalized porous nitrogen-doped carbon nanotubes with high energy storage performance, RSC Adv. 2015, 5, 66311-63633.
DOI Google Scholar
70

Yang, C.; Shen, J.; Wang, C.; Fei, H.; Bao, H.; Wang, G. All-solid-state asymmetric supercapacitor based on reduced graphene oxide/carbon nanotube and carbon fiber paper/polypyrrole electrodes, J. Mater. Chem. 2014, 2, 1458-1464.
DOI Google Scholar
71

Yu, P.; Zhang, Z.; Zheng, L.; Teng, F.; Hu, L.; Fang, X. A novel sustainable flour derived hierarchical nitrogen-doped porous carbon/polyaniline electrode for advanced asymmetric supercapacitors, Adv. Energy Mater. 2016, 6, 1601111.
DOI Google Scholar
72

Gao, H.; Xiao, F.; Ching, C. B.; Duan, H. High-performance asymmetric supercapacitor based on graphene hydrogel and nanostructured MnO2, ACS Appl. Mater. Interaces 2012, 4, 2801-2810.
DOI Google Scholar
73

Yang, C.; Zhou, M.; Xu, Q. Three-dimensional ordered macroporous MnO2/carbon nanocomposites as high-performance electrodes for asymmetric supercapacitors, Phys. Chem. Chem. Phys. 2013, 15, 19730.
DOI Google Scholar
74

Zhao, Y.; Ran, W.; He, J.; Huang, Y.; Liu, Z.; Liu, W.; Tang, Y.; Zhang, L.; Gao, D.; Gao, F. Asymmetric supercapacitors based on graphene/MnO2 and activated carbon nanofiber electrodes with high power and energy density, Small 2015, 11, 1310-1319.
DOI Google Scholar
75

Fan, Z.; Yan, J.; Wei, T.; Zhi, L.; Ning, G.; Li, T.; Wei, F. Asymmetric supercapacitors based on graphene/MnO2 and activated carbon nanofiber electrodes with high power and energy density, Adv. Funct. Mater. 2011, 21, 2366-2375.
DOI Google Scholar
76

Yang, J.; Yu, C.; Fan, X.; Liang, S.; Li, S.; Huang, H.; Ling, Z.; Hao, C.; Qiu, J. Electroactive edge site-enriched nickel-cobalt sulfide into graphene frameworks for high-performance asymmetric supercapacitors, Energy Environ. Sci. 2016, 9, 1299-1307.
DOI Google Scholar
77

Salunkhe, R. R.; Tang, J.; Kamachi, Y.; Nakato, T.; Kim, J. H.; Yamauchi, Y. Asymmetric supercapacitors using 3D nanoporous carbon and cobalt oxide electrodes synthesized from a single metal-organic framework, ACS Nano 2015, 9, 6288-6296.
DOI Google Scholar
78

Zhao, Y.; Hu, L.; Zhao, S.; Wu, L. Preparation of MnCo2O4@Ni(OH)2 core–shell flowers for asymmetric supercapacitor materials with ultrahigh specific capacitance, Adv. Funct. Mater. 2016, 26, 4085-4093.
DOI Google Scholar
79

Chen, T.; Li, S.; Wen, J.; Gui, P.; Guo, Y.; Guan, C.; Liu, J.; Fang, G. Rational construction of hollow core-branch CoSe2 nanoarrays for high-performance asymmetric supercapacitor and efficient oxygen evolution, Small 2018, 14, 1700979.
DOI Google Scholar
80

Qu, Q.; Zhu, Y.; Gao, X.; Wu, Y. Core-shell structure of polypyrrole grown on V2O5 nanoribbon as high performance anode material for supercapacitors, Adv. Energy Mater. 2012, 2, 950-955.
DOI Google Scholar
81

Li, L., Peng, S.; Wu, H. B.; Yu, L.; Madhavi, S.; Lou, X. W. A flexible quasi-solid-state asymmetric electrochemical capacitor based on hierarchical porous V2O5 nanosheets on carbon nanofibers, Adv. Energy Mater. 2015, 5, 1500753.
DOI Google Scholar
82

Tang, W.; Liu, L.; Tian, S.; Li, L.; Yue, Y.; Wu, Y.; Zhu, K. Aqueous supercapacitors of high energy density based on MoO3 nanoplates as anode material, Chem. Commun. 2011, 47, 10058-10060.
DOI Google Scholar
83

Chang, J.; Jin, M.; Yao, F.; Kim, T. H.; Le, V. T.; Yue, H.; Gunes, F.; Li, B.; Ghosh, A.; Xie, S.; Lee, Y. H. Asymmetric supercapacitors based on graphene/MnO2 nanospheres and graphene/MoO3 nanosheets with high energy density, Adv. Funct. Mater. 2013, 23, 5074-5083
DOI Google Scholar
84

Fu, J.; Yun, J.; Wu, S.; Li, L.; Yu, L.; Kim, K. H. Architecturally robust graphene-encapsulated MXene Ti2CTx@Polyaniline composite for high-performance pouch-type asymmetric supercapacitor, ACS Appl. Mater. Interfaces 2018, 10, 34212−34221.
DOI Google Scholar
85

Li, Y.; Kamdem, P.; Jin, X. -J. Hierarchical architecture of MXene/PANI hybrid electrode for advanced asymmetric supercapacitors, J. Alloy Compd. 2021, 850, 156608.
DOI Google Scholar
86

Jiang, K.; Baburin, I. A.; Han, P.; Yang, C.; Fu, X.; Yao, Y.; Li, J.; Cánovas, E.; Seifert, G.; Chen, J.; Bonn, M.; Feng, X.; Zhuang, X. Interfacial approach toward benzene-bridged polypyrrole film-based micro-supercapacitors with ultrahigh volumetric power density, Adv. Funct. Mater. 2020, 30, 1908243.
DOI Google Scholar
87

Li, H.; Hou, Y.; Wang, F.; Lohe, M. R.; Zhuang, X.; Niu, L.; Feng, X. Flexible all-solid-state supercapacitors with high volumetric capacitances boosted by solution processable MXene and electrochemically exfoliated graphene, Adv. Energy Mater. 2017, 7, 1601847.
DOI Google Scholar
88

Kurra, N.; Wang, R.; Alshareef, H. N. All conducting polymer electrodes for asymmetric solid-state supercapacitors, J. Mater. Chem. A 2015, 3, 7368-7374.
DOI Google Scholar
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Publication history
Copyright
Acknowledgements

Publication history

Received: 28 January 2021
Revised: 22 March 2021
Accepted: 25 March 2021
Published: 24 April 2021
Issue date: January 2022

Copyright

© Tsinghua University Press and Springer-Verlag GmbH Germany, part of Springer Nature 2021

Acknowledgements

Acknowledgements

The authors appreciate the financial support of the National Natural Science Foundation of China (No. 21773116), the Specialized Research Fund for the Doctoral Program of Higher Education (SRFDP, 20130091110010), the Natural Science Foundation of Jiangsu Province (No. BK2011438), the National Science Fund for Talent Training in Basic Science (No. J1103310) and the Modern Analysis Center of Nanjing University and the Program B for Outstanding PhD Candidate of Nanjing University.

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