Journal Home > Volume 15 , Issue 1
Nano Research 2022, 15(1): 255-263 https://doi.org/10.1007/s12274-021-3468-y
Research Article | Issue | Published: 26 April 2021

Generalized assembly of sandwich-like 0D/2D/0D heterostructures with highly exposed surfaces toward superior electrochemical performances

Show Author's Information Shuqing Xue1,§,  Guanhong Wu2,§,  Mingzhong Li2,  Zihan Liu2,  Yuwei Deng2,  Wenqian Han2,  Xuanyu Lv1,  Siyu Wan2,  Xiangyun Xi1,  Dong Yang1( ),  Angang Dong2( )
State Key Laboratory of Molecular Engineering of Polymers and Department of Macromolecular Science Fudan UniversityShanghai 200438 China
Collaborative Innovation Center of Chemistry for Energy Materials, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials Department of Chemistry, Fudan UniversityShanghai 200438 China

§ Shuqing Xue and Guanhong Wu contributed equally to this work.

Keywords:
assembly, MXene, supercapacitor, heterostructures, oxygen evolution, ligand-exchange
Topics:
Self assembly
Cite this article:
Xue S, Wu G, Li M, et al. Generalized assembly of sandwich-like 0D/2D/0D heterostructures with highly exposed surfaces toward superior electrochemical performances. Nano Research, 2022, 15(1): 255-263. https://doi.org/10.1007/s12274-021-3468-y
Download citation
EndNote(RIS)
BibTeX

574

Views

50

Downloads

Citations

15

Crossref

14

WoS

14

Scopus

0

CSCD

Abstract Full text Electronic supplementary material About this article

Heterostructures composed of two-dimensional (2D) nanosheets and zero-dimensional (0D) nanoparticles (NPs) have attracted increasing attention because of the synergy arising from the coupling interactions between the two mixed-dimensional components. Despite recent advances, it remains a challenge to fabricate 2D/0D heterostructures with clean and accessible surfaces, which is highly desirable for the diversity of catalytic, sensing, and energy storage applications. Herein, we report a generalized methodology that enables the facile assembly of sandwich-like 0D/2D/0D heterostructures with facilitated mass-transport channels and exposed surface active sites. A ligand-exchange strategy with HBF4 is employed to strip off the surface-coating ligands of colloidal NPs, rendering them positively charged and dispersible in polar solvents. This allows subsequent electrostatic assembly of NPs with oppositely charged 2D nanosheets to afford sandwich-like 0D/2D/0D heterostructures. The barely covered surfaces and the advantageous architectures of such sandwich-like 0D/2D/0D heterostructures induce the desired synergistic effect, making them particularly suitable for electrochemical energy storage and conversion. We demonstrate this by employing MXene/NiFe2O4 and MXene/Fe3O4 heterostructures for high-performance electrocatalytic oxygen evolution and supercapacitors, respectively.


menu
Abstract
Full text
Outline
Electronic supplementary material
About this article

Generalized assembly of sandwich-like 0D/2D/0D heterostructures with highly exposed surfaces toward superior electrochemical performances

Show Author's information Shuqing Xue1,§, Guanhong Wu2,§, Mingzhong Li2, Zihan Liu2, Yuwei Deng2, Wenqian Han2, Xuanyu Lv1, Siyu Wan2, Xiangyun Xi1, Dong Yang1( ), Angang Dong2( )
State Key Laboratory of Molecular Engineering of Polymers and Department of Macromolecular Science Fudan UniversityShanghai 200438 China
Collaborative Innovation Center of Chemistry for Energy Materials, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials Department of Chemistry, Fudan UniversityShanghai 200438 China

§ Shuqing Xue and Guanhong Wu contributed equally to this work.

Abstract

Heterostructures composed of two-dimensional (2D) nanosheets and zero-dimensional (0D) nanoparticles (NPs) have attracted increasing attention because of the synergy arising from the coupling interactions between the two mixed-dimensional components. Despite recent advances, it remains a challenge to fabricate 2D/0D heterostructures with clean and accessible surfaces, which is highly desirable for the diversity of catalytic, sensing, and energy storage applications. Herein, we report a generalized methodology that enables the facile assembly of sandwich-like 0D/2D/0D heterostructures with facilitated mass-transport channels and exposed surface active sites. A ligand-exchange strategy with HBF4 is employed to strip off the surface-coating ligands of colloidal NPs, rendering them positively charged and dispersible in polar solvents. This allows subsequent electrostatic assembly of NPs with oppositely charged 2D nanosheets to afford sandwich-like 0D/2D/0D heterostructures. The barely covered surfaces and the advantageous architectures of such sandwich-like 0D/2D/0D heterostructures induce the desired synergistic effect, making them particularly suitable for electrochemical energy storage and conversion. We demonstrate this by employing MXene/NiFe2O4 and MXene/Fe3O4 heterostructures for high-performance electrocatalytic oxygen evolution and supercapacitors, respectively.

Keywords: assembly, MXene, supercapacitor, heterostructures, oxygen evolution, ligand-exchange

References(80)

1

Boles, M. A.; Engel, M.; Talapin, D. V. Self-assembly of colloidal nanocrystals: From intricate structures to functional materials. Chem. Rev. 2016, 116, 11220–11289.
DOI Google Scholar
2

Zhang, S. D.; Geryak, R.; Geldmeier, J.; Kim, S.; Tsukruk, V. V. Synthesis, assembly, and applications of hybrid nanostructures for biosensing. Chem. Rev. 2017, 117, 12942–13038.
DOI Google Scholar
3

Borges, J.; Mano, J. F. Molecular interactions driving the layer-by- layer assembly of multilayers. Chem. Rev. 2014, 114, 8883–8942.
DOI Google Scholar
4

Vogel, N.; Retsch, M.; Fustin, C. A.; Del Campo, A.; Jonas, U. Advances in colloidal assembly: The design of structure and hierarchy in two and three dimensions. Chem. Rev. 2015, 115, 6265–6311.
DOI Google Scholar
5

Fang, Z. W.; Xing, Q. Y.; Fernandez, D.; Zhang, X.; Yu, G. H. A mini review on two-dimensional nanomaterial assembly. Nano Res. 2020, 13, 1179–1190.
DOI Google Scholar
6

Min, Y.; Im E.; Hwang, G. T.; Kim, J. W.; Ahn, C. W.; Choi, J. J.; Hahn, B. D.; Choi, J. H.; Yoon, W. H.; Park, D. S. et al. Heterostructures in two-dimensional colloidal metal chalcogenides: Synthetic fundamentals and applications. Nano Res. 2019, 12, 1750–1769.
DOI Google Scholar
7

Murray, C. B.; Kagan, C. R.; Bawendi, M. G. Synthesis and characterization of monodisperse nanocrystals and close-packed nanocrystal assemblies. Annu. Rev. Mater. Sci. 2000, 30, 545–610.
DOI Google Scholar
8

Talapin, D. V.; Lee, J. S.; Kovalenko, M. V.; Shevchenko, E. V. Prospects of colloidal nanocrystals for electronic and optoelectronic applications. Chem. Rev. 2010, 110, 389–458.
DOI Google Scholar
9

Kovalenko, M. V.; Manna, L.; Cabot, A.; Hens, Z.; Talapin, D. V.; Kagan, C. R.; Klimov, V. I.; Rogach, A. L.; Reiss, P.; Milliron, D. J. et al. Prospects of nanoscience with nanocrystals. ACS Nano 2015, 9, 1012–1057.
DOI Google Scholar
10

Talapin, D. V.; Murray, C. B. PbSe nanocrystal solids for n-and p-channel thin film field-effect transistors. Science 2005, 310, 86–89.
DOI Google Scholar
11

Law, M.; Luther, J. M.; Song, Q.; Hughes, B. K.; Perkins, C. L.; Nozik, A. J. Structural, optical, and electrical properties of PbSe nanocrystal solids treated thermally or with simple amines. J. Am. Chem. Soc. 2008, 130, 5974–5985.
DOI Google Scholar
12

Kang, Y. J.; Murray, C. B. Synthesis and electrocatalytic properties of cubic Mn-Pt nanocrystals (nanocubes). J. Am. Chem. Soc. 2010, 132, 7568–7569.
DOI Google Scholar
13

Tan, C. L.; Cao, X. H.; Wu, X. J.; He, Q. Y.; Yang, J.; Zhang, X.; Chen, J. Z.; Zhao, W.; Han, S. K.; Nam, G. H. et al. Recent advances in ultrathin two-dimensional nanomaterials. Chem. Rev. 2017, 117, 6225–6331.
DOI Google Scholar
14

Zhang, H. Ultrathin two-dimensional nanomaterials. ACS Nano 2015, 9, 9451–9469.
DOI Google Scholar
15

Xu, M. S.; Liang, T.; Shi, M. M.; Chen, H. Z. Graphene-like two-dimensional materials. Chem. Rev. 2013, 113, 3766–3798.
DOI Google Scholar
16

Butler, S. Z.; Hollen, S. M.; Cao, L. Y.; Cui, Y.; Gupta, J. A.; Gutiérrez, H. R.; Heinz, T. F.; Hong, S. S.; Huang, J. X.; Ismach, A. F. et al. Progress, challenges, and opportunities in two-dimensional materials beyond graphene. ACS Nano 2013, 7, 2898–2926.
DOI Google Scholar
17

Jun, B. M.; Kim, S.; Heo, J.; Park, C. M.; Her, N.; Jang, M.; Huang, Y.; Han, J.; Yoon, Y. Review of MXenes as new nanomaterials for energy storage/delivery and selected environmental applications. Nano Res. 2019, 12, 471–489.
DOI Google Scholar
18

Yu, Q. M.; Luo, Y. T.; Mahmood, A.; Liu, B. L.; Cheng, H. M. Engineering two-dimensional materials and their heterostructures as high-performance electrocatalysts. Electrochem. Energy Rev. 2019, 2, 373–394.
DOI Google Scholar
19

Wang, J.; Tang, J.; Ding, B.; Malgras, V.; Chang, Z.; Hao, X. D.; Wang, Y.; Dou, H.; Zhang, X. G.; Yamauchi, Y. Hierarchical porous carbons with layer-by-layer motif architectures from confined soft-template self-assembly in layered materials. Nat. Commun. 2017, 8, 15717.
DOI Google Scholar
20

Simon, P. Two-dimensional MXene with controlled interlayer spacing for electrochemical energy storage. ACS Nano 2017, 11, 2393–2396.
DOI Google Scholar
21

Yang, X. W.; Cheng, C.; Wang, Y. F.; Qiu, L.; Li, D. Liquid-mediated dense integration of graphene materials for compact capacitive energy storage. Science 2013, 341, 534–537.
DOI Google Scholar
22

Peng, L. L.; Zhu, Y.; Li, H. S.; Yu, G. H. Chemically integrated inorganic-graphene two-dimensional hybrid materials for flexible energy storage devices. Small 2016, 12, 6183–6199.
DOI Google Scholar
23

Shifa, T. A.; Wang, F. M.; Liu, Y.; He, J. Heterostructures based on 2D materials: A versatile platform for efficient catalysis. Adv. Mater. 2019, 31, 1804828.
DOI Google Scholar
24

Xi, Q.; Chen, X.; Evans, D. G.; Yang, W. S. Gold nanoparticle- embedded porous graphene thin films fabricated via layer-by-layer self-assembly and subsequent thermal annealing for electrochemical sensing. Langmuir 2012, 28, 9885–9892.
DOI Google Scholar
25

Kim, M. S.; Lim, E.; Kim, S.; Jo, C.; Chun, J.; Lee, J. General synthesis of N-doped macroporous graphene-encapsulated mesoporous metal oxides and their application as new anode materials for sodium-ion hybrid supercapacitors. Adv. Funct. Mater. 2017, 27, 1603921.
DOI Google Scholar
26

Li, Y. G.; Wang, H. L.; Xie, L. M.; Liang, Y. Y.; Hong, G. S.; Dai, H. J. MoS2 nanoparticles grown on graphene: An advanced catalyst for the hydrogen evolution reaction. J. Am. Chem. Soc. 2011, 133, 7296–7299.
DOI Google Scholar
27

Wang, Y. S.; Li, Y. Y.; Qiu, Z. P.; Wu, X. Z.; Zhou, P. F.; Zhou, T.; Zhao, J. P.; Miao, Z. C.; Zhou, J.; Zhuo, S. P. Fe3O4@Ti3C2 MXene hybrids with ultrahigh volumetric capacity as an anode material for lithium-ion batteries. J. Mater. Chem. A 2018, 6, 11189–11197.
DOI Google Scholar
28

Liu, Y. T.; Zhang, P.; Sun, N.; Anasori, B.; Zhu, Q. Z.; Liu, H.; Gogotsi, Y.; Xu, B. Self-assembly of transition metal oxide nanostructures on MXene nanosheets for fast and stable lithium storage. Adv. Mater. 2018, 30, 1707334.
DOI Google Scholar
29

Wu, D. Q.; Zhang, F.; Liang, H. W.; Feng, X. L. Nanocomposites and macroscopic materials: Assembly of chemically modified graphene sheets. Chem. Soc. Rev. 2012, 41, 6160–6177.
DOI Google Scholar
30

Fang, Y. X.; Guo, S. J.; Zhu, C. Z.; Zhai, Y. M.; Wang, E. K. Self- assembly of cationic polyelectrolyte-functionalized graphene nanosheets and gold nanoparticles: A two-dimensional heterostructure for hydrogen peroxide sensing. Langmuir 2010, 26, 11277–11282.
DOI Google Scholar
31

Lv, Z. Z.; Yang, X.; Wang, E. K. Highly concentrated polycations- functionalized graphenenanosheets with excellent solubility and stability, and its fast, facile and controllable assembly of multiple nanoparticles. Nanoscale 2013, 5, 663–670.
DOI Google Scholar
32

Dong, A. G.; Ye, X. C.; Chen, J.; Kang, Y. J.; Gordon, T.; Kikkawa, J. M.; Murray, C. B. A generalized ligand-exchange strategy enabling sequential surface functionalization of colloidal nanocrystals. J. Am. Chem. Soc. 2011, 133, 998–1006.
DOI Google Scholar
33

Li, D.; Müller, M. B.; Gilje, S.; Kaner, R. B.; Wallace, G. G. Processable aqueous dispersions of graphene nanosheets. Nat. Nanotechnol. 2008, 3, 101–105.
DOI Google Scholar
34

Shekhirev, M.; Shuck, C. E.; Sarycheva, A.; Gogotsi, Y. Characterization of MXenes at every step, from their precursors to single flakes and assembled films. Prog. Mater. Sci. 2020, https://doi.org/10.1016/j.pmatsci.2020.100757.
DOI Google Scholar
35

Chou, S. S.; De, M.; Kim, J.; Byun, S.; Dykstra, C.; Yu, J.; Huang, J. X.; Dravid, V. P. Ligand conjugation of chemically exfoliated MoS2. J. Am. Chem. Soc. 2013, 135, 4584–4587.
DOI Google Scholar
36

Forsberg, V.; Zhang, R. Y.; Bäckström, J.; Dahlström, C.; Andres, B.; Norgren, M.; Andersson, M.; Hummelgård, M.; Olin, H. Exfoliated MoS2 in water without additives. PLoS One 2016, 11, e0154522.
DOI Google Scholar
37

Xiong, P.; Zhang, X. Y.; Zhang, F.; Yi, D.; Zhang, J. Q.; Sun, B.; Tian, H.; Shanmukaraj, D.; Rojo, T.; Armand, M. et al. Two-dimensional unilamellar cation-deficient metal oxide nanosheet superlattices for high-rate sodium ion energy storage. ACS Nano 2018, 12, 12337–12346.
DOI Google Scholar
38

Xiong, P.; Ma, R. Z.; Sakai, N.; Sasaki, T. Genuine unilamellar metal oxide nanosheets confined in a superlattice-like structure for superior energy storage. ACS Nano 2018, 12, 1768–1777.
DOI Google Scholar
39

Alhabeb, M.; Maleski, K.; Anasori, B.; Lelyukh, P.; Clark, L.; Sin, S.; Gogotsi, Y. Guidelines for synthesis and processing of two- dimensional titanium carbide (Ti3C2Tx MXene). Chem. Mater. 2017, 29, 7633–7644.
DOI Google Scholar
40

Ying, G. B.; Dillon, A. D.; Fafarman, A. T.; Barsoum, M. W. Transparent, conductive solution processed spincast 2D Ti2CTx (MXene) films. Mater. Res. Lett. 2017, 5, 391–398.
DOI Google Scholar
41

Zhou, Y. Y.; Jiang, K.; Zhao, Z. G.; Li, Q. W.; Ma, R. Z.; Sasaki, T.; Geng, F. X. Giant two-dimensional titania sheets for constructing a flexible fiber sodium-ion battery with long-term cycling stability. Energy Storage Mater. 2020, 24, 504–511.
DOI Google Scholar
42

Kai, K.; Yoshida, Y.; Kageyama, H.; Saito, G.; Ishigaki, T.; Furukawa, Y.; Kawamata, J. Room-temperature synthesis of manganese oxide monosheets. J. Am. Chem. Soc. 2008, 130, 15938–15943.
DOI Google Scholar
43

Park, J.; An, K.; Hwang, Y.; Park, J. G.; Noh, H. J.; Kim, J. Y.; Park, J. H.; Hwang, N. M.; Hyeon, T. Ultra-large-scale syntheses of monodisperse nanocrystals. Nat. Mater. 2004, 3, 891–895.
DOI Google Scholar
44

Sun, S. H.; Zeng, H.; Robinson, D. B.; Raoux, S.; Rice, P. M.; Wang, S. X.; Li, G. X. Monodisperse MFe2O4 (M = Fe, Co, Mn) nanoparticles. J. Am. Chem. Soc. 2004, 126, 273–279.
DOI Google Scholar
45

Wang, D. Y.; Kang, Y. J.; Doan-Nguyen, V.; Chen, J.; Küngas, R.; Wieder, N. L.; Bakhmutsky, K.; Gorte, R. J.; Murray, C. B. Synthesis and oxygen storage capacity of two-dimensional ceria nanocrystals. Angew. Chem., Int. Ed. 2011, 123, 4470–4473.
DOI Google Scholar
46

Mai, H. X.; Zhang, Y. W.; Si, R.; Yan, Z. G.; Sun, L. D.; You, L. P.; Yan, C. H. High-quality sodium rare-earth fluoride nanocrystals: Controlled synthesis and optical properties. J. Am. Chem. Soc. 2006, 128, 6426–6436.
DOI Google Scholar
47

Naguib, M.; Kurtoglu, M.; Presser, V.; Lu, J.; Niu, J. J.; Heon, M.; Hultman, L.; Gogotsi, Y.; Barsoum, M. W. Two-dimensional nanocrystals produced by exfoliation of Ti3AlC2. Adv. Mater. 2011, 23, 4248–4253.
DOI Google Scholar
48

Yu, M. Z.; Zhou, S.; Wang, Z. Y.; Zhao, J. J.; Qiu, J. S. Boosting electrocatalytic oxygen evolution by synergistically coupling layered double hydroxide with MXene. Nano Energy 2018, 44, 181–190.
DOI Google Scholar
49

Yu, M. Z.; Wang, Z. Y.; Liu, J. S.; Sun, F.; Yang, P. J.; Qiu, J. S. A hierarchically porous and hydrophilic 3D nickel–iron/MXene electrode for accelerating oxygen and hydrogen evolution at high current densities. Nano Energy 2019, 63, 103880.
DOI Google Scholar
50

Augustyn, V.; Come, J.; Lowe, M. A.; Kim, J. W.; Taberna, P. L.; Tolbert, S. H.; Abruña, H. D.; Simon, P.; Dunn, B. High-rate electrochemical energy storage through Li+ intercalation pseudocapacitance. Nat. Mater. 2013, 12, 518–522.
DOI Google Scholar
51

Zhang, J. T.; Zhao, X. S. On the configuration of supercapacitors for maximizing electrochemical performance. ChemSusChem 2012, 5, 818–841.
DOI Google Scholar
52

Ardizzone, S.; Fregonara, G.; Trasatti, S. "Inner" and "outer" active surface of RuO2 electrodes. Electrochim. Acta 1990, 35, 263–267.
DOI Google Scholar
53

Ma, Y.; Dai, X.; Liu, M.; Yong, J.; Qiao, H.; Jin, A.; Li, Z.; Huang, X.; Wang, H.; Zhang, X. Strongly coupled FeNi alloys/NiFe2O4@carbonitride layers-assembled microboxes for enhanced oxygen evolution reaction. ACS Appl. Mater. Inter. 2016, 8, 34396-34404.
DOI Google Scholar
54

Lim, D.; Kong, H.; Kim, N.; Lim, C.; Ahn, W. S.; Baeck, S. H. Oxygen-Deficient NiFe2O4 Spinel Nanoparticles as an Enhanced Electrocatalyst for the Oxygen Evolution Reaction. ChemNanoMat 2019, 5, 1296-1302.
DOI Google Scholar
55

Bao, J.; Zhang, X.; Fan, B.; Zhang, J.; Zhou, M.; Yang, W.; Hu, X.; Wang, H.; Pan, B.; Xie, Y. Ultrathin spinel-structured nanosheets rich in oxygen deficiencies for enhanced electrocatalytic water oxidation. Angew. Chem. 2015, 127, 7507-7512.
DOI Google Scholar
56

Zhang, Z.; Zhang, J.; Wang, T.; Li, Z.; Yang, G.; Bian, H.; Li, J.; Gao, D. Durable oxygen evolution reaction of one dimensional spinel CoFe2O4 nanofibers fabricated by electrospinning. RSC Adv. 2018, 8, 5338-5343.
DOI Google Scholar
57

Huang, Y.; Yang, W.; Yu, Y.; Hao, S. Ordered mesoporous spinel CoFe2O4 as efficient electrocatalyst for the oxygen evolution reaction. J. Electroanal. Chem. 2019, 840, 409-414.
DOI Google Scholar
58

Mahala, C.; Sharma, M. D.; Basu, M. 2D nanostructures of CoFe2O4 and NiFe2O4: efficient oxygen evolution catalyst. Electrochim. Acta 2018, 273, 462-473.
DOI Google Scholar
59

Li, Z.; Yu, X. -Y.; Paik, U. Facile preparation of porous Co3O4 nanosheets for high-performance lithium ion batteries and oxygen evolution reaction. J. Power Sources 2016, 310, 41-46.
DOI Google Scholar
60

Lu, Y.; Fan, D.; Chen, Z.; Xiao, W.; Cao, C.; Yang, X. Anchoring Co3O4 nanoparticles on MXene for efficient electrocatalytic oxygen evolution. Sci. Bull. 2020, 65, 460-466.
DOI Google Scholar
61

Wang, C.; Zhu, X. -D.; Mao, Y. -C.; Wang, F.; Gao, X. -T.; Qiu, S. -Y.; Le, S. -R.; Sun, K. -N. MXene-supported Co3O4 quantum dots for superior lithium storage and oxygen evolution activities. Chem. Commun. 2019, 55, 1237-1240.
DOI Google Scholar
62

Leng, M.; Huang, X.; Xiao, W.; Ding, J.; Liu, B.; Du, Y.; Xue, J. Enhanced oxygen evolution reaction by Co-OC bonds in rationally designed Co3O4/graphene nanocomposites. Nano Energy 2017, 33, 445-452.
DOI Google Scholar
63

Chen, S.; Zhao, Y.; Sun, B.; Ao, Z.; Xie, X.; Wei, Y.; Wang, G. Microwave-assisted synthesis of mesoporous Co3O4 nanoflakes for applications in lithium ion batteries and oxygen evolution reactions. ACS Appl. Mater. Inter. 2015, 7, 3306-3313.
DOI Google Scholar
64

Tang, Y.; Fang, X.; Zhang, X.; Fernandes, G.; Yan, Y.; Yan, D.; Xiang, X.; He, J. Space-confined earth-abundant bifunctional electrocatalyst for high-efficiency water splitting. ACS Appl. Mater. Inter. 2017, 9, 36762-36771.
DOI Google Scholar
65

Dong, D.; Liu, Y.; Li, J. Co3O4 hollow polyhedrons as bifunctional electrocatalysts for reduction and evolution reactions of oxygen. Part. Part. Syst. Char. 2016, 33, 887-895.
DOI Google Scholar
66

Zhao, L.; Dong, B.; Li, S.; Zhou, L.; Lai, L.; Wang, Z.; Zhao, S.; Han, M.; Gao, K.; Lu, M. Interdiffusion reaction-assisted hybridization of two-dimensional metal–organic frameworks and Ti3C2Tx nanosheets for electrocatalytic oxygen evolution. ACS nano 2017, 11, 5800-5807.
DOI Google Scholar
67

Wen, Y.; Wei, Z.; Ma, C.; Xing, X.; Li, Z.; Luo, D. MXene boosted CoNi-ZIF-67 as highly efficient electrocatalysts for oxygen evolution. Nanomaterials 2019, 9, 775.
DOI Google Scholar
68

Kulal, P. M.; Dubal, D. P.; Lokhande, C. D.; Fulari, V. J. Chemical synthesis of Fe2O3 thin films for supercapacitor application. J. Alloy. Compd. 2011, 509, 2567-2571.
DOI Google Scholar
69

Sethuraman, B.; Purushothaman, K. K.; Muralidharan, G. Synthesis of mesh-like Fe2O3/C nanocomposite via greener route for high performance supercapacitors. RSC Adv. 2014, 4, 4631-4637.
DOI Google Scholar
70

Wang, D.; Li, Y.; Wang, Q.; Wang, T. Nanostructured Fe2O3-graphene composite as a novel electrode material for supercapacitors. J. Solid State Electr. 2012, 16, 2095-2102.
DOI Google Scholar
71

Mitchell, E.; Gupta, R. K.; Mensah-Darkwa, K.; Kumar, D.; Ramasamy, K.; Gupta, B. K.; Kahol, P. Facile synthesis and morphogenesis of superparamagnetic iron oxide nanoparticles for high-performance supercapacitor applications. New J. Chem. 2014, 38, 4344-4350.
DOI Google Scholar
72

Wang, G.; Xu, H.; Lu, L.; Zhao, H. Magnetization-induced double-layer capacitance enhancement in active carbon/Fe3O4 nanocomposites. J. Energy Chem. 2014, 23, 809-815.
DOI Google Scholar
73

Meng, W.; Chen, W.; Zhao, L.; Huang, Y.; Zhu, M.; Huang, Y.; Fu, Y.; Geng, F.; Yu, J.; Chen, X. Porous Fe3O4/carbon composite electrode material prepared from metal-organic framework template and effect of temperature on its capacitance. Nano Energy 2014, 8, 133-140.
DOI Google Scholar
74

Guan, D.; Gao, Z.; Yang, W.; Wang, J.; Yuan, Y.; Wang, B.; Zhang, M.; Liu, L. Hydrothermal synthesis of carbon nanotube/cubic Fe3O4 nanocomposite for enhanced performance supercapacitor electrode material. Mater. Sci. Eng. B 2013, 178, 736-743.
DOI Google Scholar
75

Fu, C.; Mahadevegowda, A.; Grant, P. S. Fe3O4/carbon nanofibres with necklace architecture for enhanced electrochemical energy storage. J. Mater. Chem. A 2015, 3, 14245-14253.
DOI Google Scholar
76

Wang, L.; Yu, J.; Dong, X.; Li, X.; Xie, Y.; Chen, S.; Li, P.; Hou, H.; Song, Y. Three-dimensional macroporous carbon/Fe3O4-doped porous carbon nanorods for high-performance supercapacitor. ACS Sustain. Chem. Eng. 2016, 4, 1531-1537.
DOI Google Scholar
77

Wang, Q.; Jiao, L.; Du, H.; Wang, Y.; Yuan, H. Fe3O4 nanoparticles grown on graphene as advanced electrode materials for supercapacitors. J. Power Sources 2014, 245, 101-106.
DOI Google Scholar
78

Li, L.; Gao, P.; Gai, S.; He, F.; Chen, Y.; Zhang, M.; Yang, P. Ultra small and highly dispersed Fe3O4 nanoparticles anchored on reduced graphene for supercapacitor application. Electrochim. Acta 2016, 190, 566-573.
DOI Google Scholar
79

Yan, F.; Ding, J.; Liu, Y.; Wang, Z.; Cai, Q.; Zhang, J. Fabrication of magnetic irregular hexagonal-Fe3O4 sheets/reduced graphene oxide composite for supercapacitors. Synthetic Met. 2015, 209, 473-479.
DOI Google Scholar
80

Arun, T.; Prabakaran, K.; Udayabhaskar, R.; Mangalaraja, R.; Akbari-Fakhrabadi, A. Carbon decorated octahedral shaped Fe3O4 and α-Fe2O3 magnetic hybrid nanomaterials for next generation supercapacitor applications. Appl. Surf. Sci. 2019, 485, 147-157.
DOI Google Scholar
File
12274_2021_3468_MOESM1_ESM.pdf (3.5 MB)
Publication history
Copyright
Acknowledgements

Publication history

Received: 26 February 2021
Revised: 24 March 2021
Accepted: 24 March 2021
Published: 26 April 2021
Issue date: January 2022

Copyright

© Tsinghua University Press and Springer-Verlag GmbH Germany, part of Springer Nature 2021

Acknowledgements

Acknowledgements

The authors acknowledge the financial support from the National Natural Science Foundation of China (NSFC) (Nos. 22025501, 21872038, 21733003, 51773042, and 51973040), and the National Key R & D Program of China (Nos. 2020YFB1505803 and 2017YFA0207303), and Foshan Science and Technology Innovation Program (No. 2017IT100121).

Return