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Nano Research 2021, 14(12): 4783-4788 https://doi.org/10.1007/s12274-021-3424-x
Research Article | Issue | Published: 23 April 2021

NiCo-LDH nanosheets strongly coupled with GO-CNTs as a hybrid electrocatalyst for oxygen evolution reaction

Show Author's Information Peiqun Yin1,2,3( ),  Geng Wu2,  Xiaoqian Wang2,  Shoujie Liu5,  Fangyao Zhou2,  Lei Dai4( ),  Xin Wang2,  Bo Yang1,  Zhen-Qiang Yu1( )
School of Chemistry and Environmental Engineering, Institute of Low-dimensional Materials Genome Initiative Shenzhen UniversityShenzhen 518060 China
School of Chemistry and Materials Science, Hefei National Laboratory for Physical Sciences at the Microscale University of Science and Technology of ChinaHefei 230026 China
School of Biomedical Engineering and Research and Engineering Center of Biomedical Materials Anhui Medical UniversityHefei 230032 China
Key Laboratory for Special Functional Materials of Ministry of Education School of Materials, Henan UniversityKaifeng 475004 China
Chemistry and Chemical Engineering of Guangdong LaboratoryShantou 515063 China
Keywords:
electrocatalysts, oxygen evolution, NiCo-LDH/GO-CNTs composite, intimate electron interaction
Topics:
Catalysis
Cite this article:
Yin P, Wu G, Wang X, et al. NiCo-LDH nanosheets strongly coupled with GO-CNTs as a hybrid electrocatalyst for oxygen evolution reaction. Nano Research, 2021, 14(12): 4783-4788. https://doi.org/10.1007/s12274-021-3424-x
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Abstract Full text Electronic supplementary material About this article

The rational fabrication of highly efficient electrocatalysts with low cost toward oxygen evolution reaction (OER) is greatly desired but remains a formidable challenge. In this work, we present a facile and straightforward method of incorporating NiCo-layered double hydroxide (NiCo-LDH) into GO-dispersed CNTs (GO-CNTs) with interconnected configuration. X-ray absorption spectroscopy (XAS) reveals the strong electron interaction between NiCo-LDH and the underlying GO-CNTs substrate, which is supposed to facilitate charge transfer and accelerate the kinetics for OER. By tuning the amount of CNTs, the optimized NiCo-LDH/GO-CNTs composite can achieve a low overpotential of 290 mV at 10 mA·cm−2 current density, a small Tafel slope of 66.8 mV·dec−1 and robust stability, superior to the pure NiCo-LDH and commercial RuO2 in alkaline media. The preeminent oxygen evolution performance is attributed to the synergistic effect stemming from the merits and the intimate electron interaction between LDH and GO-CNTs. This allows NiCo-LDH/GO-CNTs to be potentially applied in an industrial non-noble metal-based water electrolyzer as the anodic catalysts.


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Electronic supplementary material
About this article

NiCo-LDH nanosheets strongly coupled with GO-CNTs as a hybrid electrocatalyst for oxygen evolution reaction

Show Author's information Peiqun Yin1,2,3( ), Geng Wu2, Xiaoqian Wang2, Shoujie Liu5, Fangyao Zhou2, Lei Dai4( ), Xin Wang2, Bo Yang1, Zhen-Qiang Yu1( )
School of Chemistry and Environmental Engineering, Institute of Low-dimensional Materials Genome Initiative Shenzhen UniversityShenzhen 518060 China
School of Chemistry and Materials Science, Hefei National Laboratory for Physical Sciences at the Microscale University of Science and Technology of ChinaHefei 230026 China
School of Biomedical Engineering and Research and Engineering Center of Biomedical Materials Anhui Medical UniversityHefei 230032 China
Key Laboratory for Special Functional Materials of Ministry of Education School of Materials, Henan UniversityKaifeng 475004 China
Chemistry and Chemical Engineering of Guangdong LaboratoryShantou 515063 China

Abstract

The rational fabrication of highly efficient electrocatalysts with low cost toward oxygen evolution reaction (OER) is greatly desired but remains a formidable challenge. In this work, we present a facile and straightforward method of incorporating NiCo-layered double hydroxide (NiCo-LDH) into GO-dispersed CNTs (GO-CNTs) with interconnected configuration. X-ray absorption spectroscopy (XAS) reveals the strong electron interaction between NiCo-LDH and the underlying GO-CNTs substrate, which is supposed to facilitate charge transfer and accelerate the kinetics for OER. By tuning the amount of CNTs, the optimized NiCo-LDH/GO-CNTs composite can achieve a low overpotential of 290 mV at 10 mA·cm−2 current density, a small Tafel slope of 66.8 mV·dec−1 and robust stability, superior to the pure NiCo-LDH and commercial RuO2 in alkaline media. The preeminent oxygen evolution performance is attributed to the synergistic effect stemming from the merits and the intimate electron interaction between LDH and GO-CNTs. This allows NiCo-LDH/GO-CNTs to be potentially applied in an industrial non-noble metal-based water electrolyzer as the anodic catalysts.

Keywords: electrocatalysts, oxygen evolution, NiCo-LDH/GO-CNTs composite, intimate electron interaction

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Publication history
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Acknowledgements

Publication history

Received: 29 January 2021
Revised: 24 February 2021
Accepted: 24 February 2021
Published: 23 April 2021
Issue date: December 2021

Copyright

© Tsinghua University Press and Springer-Verlag GmbH Germany, part of Springer Nature 2021

Acknowledgements

Acknowledgements

This work was supported by Science and Technology Key Project of Guangdong Province of China (No. 2020B010188002), the National Major Science and Technology Program for Water Pollution Control and Treatment of China (No. 2017ZX07202). We sincerely thank the photoemission endstations beamline 1W1B station in Beijing Synchrotron Radiation Facility (BSRF), BL10B and BL11U in National Synchrotron Radiation Laboratory (NSRL) in Hefei, China.

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