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Nano Research 2021, 14(11): 4006-4013 https://doi.org/10.1007/s12274-021-3327-x
Research Article | Issue | Published: 04 June 2021

Evolution of dielectric loss-dominated electromagnetic patterns in magnetic absorbers for enhanced microwave absorption performances

Show Author's Information Xiaogu Huang1,  Man Qiao1,  Xiaochi Lu1,  Yafei Li3,  Yabin Ma1,  Bo Kang1,  Bin Quan1( ),  Guangbin Ji4( )
Institute of Advanced Materials and Flexible Electronics (IAMFE) School of Chemistry and Materials Science, Nanjing University of Information Science & TechnologyNanjing 210044 China
College of Electronic and Optical Engineering & College of Microelectronics Nanjing University of Posts and TelecommunicationsNanjing210023 China
Jiangsu Collaborative Innovation Centre of Biomedical Functional Materials School of Chemistry and Materials Science, Nanjing Normal UniversityNanjing 210023 China
College of Materials Science and Technology Nanjing University of Aeronautics and AstronauticsNanjing 211100 China
Keywords:
microwave absorption, impedance matching, dielectric loss, magnetic loss, geometric interference
Topics:
Iron oxides
Cite this article:
Huang X, Qiao M, Lu X, et al. Evolution of dielectric loss-dominated electromagnetic patterns in magnetic absorbers for enhanced microwave absorption performances. Nano Research, 2021, 14(11): 4006-4013. https://doi.org/10.1007/s12274-021-3327-x
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Abstract Full text Electronic supplementary material About this article

As the growing criterion of electromagnetic wave (EMW)absorption materials, micro/nano-scale magnetic materials are drawing more and more attention for their unique features compared to bulky absorbers. Generally, the complex permeability of micro/nano-scale magnetic absorbers varies in a relatively narrow range, whatever for the storage of magnetic energy or the dissipation of magnetic energy. If so, how the small variation of permeability affects the ultimate performances is still unclear. Here, a strategy of electromagnetic parameters regulation for the magnetic materials is applied to understand the loss contribution in micro/nano- scale magnetic absorbers. After analyzing the evolution of electromagnetic maps of ten ferrosoferric oxide samples, it can be found that the dissipation contribution of permeability for magnetic materials is weaker than that of permittivity, in spite of its significant role in determining the impedance matching characteristics. In summary, this work systematically explores the loss contribution in micro/nano-magnetic absorbers for the first time, which is of great importance in designing and optimizing the microwave absorption properties of magnetic absorbers.


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Abstract
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Electronic supplementary material
About this article

Evolution of dielectric loss-dominated electromagnetic patterns in magnetic absorbers for enhanced microwave absorption performances

Show Author's information Xiaogu Huang1, Man Qiao1, Xiaochi Lu1, Yafei Li3, Yabin Ma1, Bo Kang1, Bin Quan1( ), Guangbin Ji4( )
Institute of Advanced Materials and Flexible Electronics (IAMFE) School of Chemistry and Materials Science, Nanjing University of Information Science & TechnologyNanjing 210044 China
College of Electronic and Optical Engineering & College of Microelectronics Nanjing University of Posts and TelecommunicationsNanjing210023 China
Jiangsu Collaborative Innovation Centre of Biomedical Functional Materials School of Chemistry and Materials Science, Nanjing Normal UniversityNanjing 210023 China
College of Materials Science and Technology Nanjing University of Aeronautics and AstronauticsNanjing 211100 China

Abstract

As the growing criterion of electromagnetic wave (EMW)absorption materials, micro/nano-scale magnetic materials are drawing more and more attention for their unique features compared to bulky absorbers. Generally, the complex permeability of micro/nano-scale magnetic absorbers varies in a relatively narrow range, whatever for the storage of magnetic energy or the dissipation of magnetic energy. If so, how the small variation of permeability affects the ultimate performances is still unclear. Here, a strategy of electromagnetic parameters regulation for the magnetic materials is applied to understand the loss contribution in micro/nano- scale magnetic absorbers. After analyzing the evolution of electromagnetic maps of ten ferrosoferric oxide samples, it can be found that the dissipation contribution of permeability for magnetic materials is weaker than that of permittivity, in spite of its significant role in determining the impedance matching characteristics. In summary, this work systematically explores the loss contribution in micro/nano-magnetic absorbers for the first time, which is of great importance in designing and optimizing the microwave absorption properties of magnetic absorbers.

Keywords: microwave absorption, impedance matching, dielectric loss, magnetic loss, geometric interference

References(33)

1

Zhang, Y.; Huang, Y.; Zhang, T. F.; Chang, H. C.; Xiao, P. S.; Chen, H. H.; Huang, Z. Y.; Chen, Y. S. Broadband and tunable high- performance microwave absorption of an ultralight and highly compressible graphene foam. Adv. Mater. 2015, 27, 2049-2053.
DOI Google Scholar
2
Quan, B.; Gu, W. H.; Sheng, J. Q.; Lv, X. F.; Mao, Y. Y.; Liu, L.; Huang, X. G.; Tian, Z. J.; Ji, G. B. From intrinsic dielectric loss to geometry patterns: Dual-principles strategy for ultrabroad band microwave absorption. Nano Res. in press, DOI: 10.1007/s12274-020-3208-8.https://doi.org/10.1007/s12274-020-3208-8
DOI
3

Sun, H.; Che, R. C.; You, X.; Jiang, Y. S; Yang, Z. B.; Deng, J.; Qiu, L. B.; Peng, H. S. Cross-stacking aligned carbon-nanotube films to tune microwave absorption frequencies and increase absorption intensities. Adv. Mater. 2014, 26, 8120-8125.
DOI Google Scholar
4

Shu, J. C.; Cao, M. S.; Zhang, M.; Wang, X. X.; Cao, W. Q.; Fang, X. Y.; Cao, M. Q. Molecular patching engineering to drive energy conversion as efficient and environment-friendly cell toward wireless power transmission. Adv. Funct. Mater. 2020, 30, 1908299.
DOI Google Scholar
5

Zhao, B.; Li, Y.; Zeng, Q. W.; Wang, L.; Ding, J. J.; Zhang, R.; Che, R. C. Galvanic replacement reaction involving core-shell magnetic chains and orientation-tunable microwave absorption properties. Small 2020, 16, 2003502.
DOI Google Scholar
6

Xu, J.; Zhang, X.; Yuan, H. R.; Zhang, S.; Zhu, C. L.; Zhang, X. T.; Chen, Y. J. N-doped reduced graphene oxide aerogels containing pod-like N-doped carbon nanotubes and FeNi nanoparticles for electromagnetic wave absorption. Carbon 2020, 159, 357-365.
DOI Google Scholar
7

Yan, F.; Guo, D.; Zhang, S.; Li, C. Y.; Zhu, C. L.; Zhang, X. T.; Chen, Y. J. An ultra-small NiFe2O4 hollow particle/graphene hybrid: Fabrication and electromagnetic wave absorption property. Nanoscale 2018, 10, 2697-2703.
DOI Google Scholar
8

Liu, Q. H.; Cao, Q.; Bi, H.; Liang, C. Y.; Yuan, K. P.; She, W.; Yang, Y. J.; Che, R. C. CoNi@SiO2@TiO2 and CoNi@Air@TiO2 microspheres with strong wideband microwave absorption. Adv. Mater. 2016, 28, 486-490.
DOI Google Scholar
9

Yang, W. Y.; Zhang, Y. F.; Qiao, G. Y.; Lai, Y. F.; Liu, S. Q.; Wang, C. S.; Han, J. Z.; Du, H. L.; Zhang, Y.; Yang, Y. C. et al. Tunable magnetic and microwave absorption properties of Sm1.5Y0.5Fe17-xSix and their composites. Acta Mater. 2018, 145, 331-336.
DOI Google Scholar
10

Qu, B.; Zhu, C. L.; Li, C. Y.; Zhang, X. T.; Chen, Y. J. Coupling hollow Fe3O4-Fe Nanoparticles with graphene sheets for high-performance electromagnetic wave absorbing material. ACS Appl. Mater. Interfaces 2016, 8, 3730-3735.
DOI Google Scholar
11

Chang, Y. D.; Zhang, Y. N.; Meng, C.; Liu, S. Q.; Chang, H.; Liu, Z. Strong and wide microwave absorption of SrFe12-2xNixRuxO19 enhanced by dislocation stripes. Appl. Phys. Lett. 2020, 116, 082404.
DOI Google Scholar
12

Liang, X. H.; Man, Z. M.; Quan, B.; Zheng, J.; Gu, W. H.; Zhang, Z.; Ji, G. B. Environment-stable CoxNiy encapsulation in stacked porous carbon nanosheets for enhanced microwave absorption. Nano-Micro Lett. 2020, 12, 102.
DOI Google Scholar
13

Wang, X. Y.; Lu, Y. K.; Zhu, T.; Chang, S. C.; Wang, W. CoFe2O4/N-doped reduced graphene oxide aerogels for high-performance microwave absorption. Chem. Eng. J. 2020, 388, 124317.
DOI Google Scholar
14

Ding, J. J.; Wang, L.; Zhao, Y. H.; Xing, L. S.; Yu, X. F.; Chen, G. Y.; Zhang, J.; Che, R. C. Boosted interfacial polarization from multishell TiO2@Fe3O4@Ppy heterojunction for enhanced microwave absorption. Small 2019, 15, 1902885.
DOI Google Scholar
15

Wu, H. J.; Liu, J. L.; Liang, H. S.; Zang, D. Y. Sandwich-like Fe3O4/Fe3S4 composites for electromagnetic wave absorption. Chem. Eng. J. 2020, 393, 24743.
Google Scholar
16

Kresse, G.; Furthmüller, J. Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set. Phys. Rev. B 1996, 54, 11169-11186.
DOI Google Scholar
17

Kresse, G.; Furthmüller, J. Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set. J. Comput. Mater. Sci. 1996, 6, 15-50.
DOI Google Scholar
18

Kresse, G.; Joubert, D. From ultrasoft pseudopotentials to the projector augmented-wave method. Phys. Rev. B 1999, 59, 1758-1775.
DOI Google Scholar
19

Perdew, J. P.; Burke, K.; Ernzerhof, K. M. Generalized gradient approximation made simple. Phys. Rev. Lett. 1996, 77, 3865-3868.
DOI Google Scholar
20

Dudarev, S. L.; Botton, G. A.; Savrasov, S. Y.; Humphreys, C. J.; Sutton, A. P. Electron-energy-loss spectra and the structural stability of nickel oxide: An LSDA+U study. Phys. Rev. B 1998, 57, 1505-1509.
DOI Google Scholar
21

Yang, T.; Wen, X. D.; Huo, C. F.; Li, Y. W.; Wang, J. G.; Jiao, H. J. Structure and energetics of hydrogen adsorption on Fe3O4(111). J. Mol. Catal. A: Chem. 2009, 302, 129-136.
DOI Google Scholar
22

Lou, Z. C.; Li, R.; Wang, P.; Zhang, Y.; Chen, B.; Huang, C. X.; Wang, C. C.; Han, H.; Li, Y. J. Phenolic foam-derived magnetic carbon foams (MCFs) with tunable electromagnetic wave absorption behavior. Chem. Eng. J. 2020, 391, 123571.
DOI Google Scholar
23

Chen, Y. M.; Pang, L.; Li, Y.; Luo, H.; Duan, G. G.; Mei, C. T.; Xu, W. H.; Zhou, W.; Liu, K. M.; Jiang, S. H. Ultra-thin and highly flexible cellulose nanofiber/silver nanowire conductive paper for effective electromagnetic interference shielding. Composites Part A 2020, 135, 105960.
DOI Google Scholar
24

Liu, Q. L.; Zhang, D.; Fan, T. X. Electromagnetic wave absorption properties of porous carbon/Co nanocomposites. Appl. Phys. Lett. 2008, 93, 013110.
DOI Google Scholar
25

Lu, B.; Huang, H.; Dong, X. L.; Zhang, X. F.; Lei, J. P.; Sun, J. P.; Dong, C. Influence of alloy components on electromagnetic characteristics of core/shell-type Fe-Ni nanoparticles. J. Appl. Phys. 2008, 104, 114313.
DOI Google Scholar
26

Zhang, X. M.; Ji, G. B.; Liu, W.; Quan, B.; Liang, X. H.; Shang, C. M.; Cheng, Y.; Du, Y. W. Thermal conversion of an Fe3O4@metal-organic framework: A new method for an efficient Fe-Co/nanoporous carbon microwave absorbing material. Nanoscale 2015, 7, 12932-12942.
DOI Google Scholar
27

Quan, B.; Liang, X. H.; Ji, G. B.; Lv, J.; Dai, S. S.; Xu, G. Y.; Du, Y. W. Laminated graphene oxide-supported high-efficiency microwave absorber fabricated by an in situ growth approach. Carbon 2018, 129, 310-320.
DOI Google Scholar
28

Quan, B.; Shi, W. H.; Ong, S. J. H.; Lu, X. C.; Wang, P. L.; Ji, G. B.; Guo, Y. F.; Zheng, L. R.; Xu, Z. C. J. Defect engineering in two common types of dielectric materials for electromagnetic absorption applications. Adv. Funct. Mater. 2019, 29, 1901236.
DOI Google Scholar
29

Li, X. K.; Paier, J. Adsorption of water on the Fe3O4(111) surface: Structures, stabilities, and vibrational properties studied by density functional theory. J. Phys. Chem. C 2016, 120, 1056-1065.
DOI Google Scholar
30

Cao, W. T.; Chen, F. F.; Zhu, Y. J.; Zhang, Y. G.; Jiang, Y. Y.; Ma, M. G.; Chen, F. Binary strengthening and toughening of MXene/cellulose nanofiber composite paper with nacre-inspired structure and superior electromagnetic interference shielding properties. ACS Nano 2018, 12, 4583-4593.
DOI Google Scholar
31

Quan, B.; Liang, X. H.; Zhang, X.; Xu, G. Y.; Ji, G. B.; Du, Y. W. Functionalized carbon nanofibers enabling stable and flexible absorbers with effective microwave response at low thickness. ACS Appl. Mater. Interfaces 2018, 10, 41535-41543.
DOI Google Scholar
32

Zhao, Z. H.; Zhou, X. J.; Kou, K. C.; Wu, H. J. PVP-assisted transformation of ZIF-67 into cobalt layered double hydroxide/carbon fiber as electromagnetic wave absorber. Carbon 2021, 173, 80-90.
DOI Google Scholar
33

Cao, M. S.; Wang, X. X.; Zhang, M.; Shu, J. C.; Cao, W. Q.; Yang, H. J.; Fang, X. Y.; Yuan, J. Electromagnetic response and energy conversion for functions and devices in low-dimensional materials. Adv. Funct. Mater. 2019, 29, 1807398.
DOI Google Scholar
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Publication history
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Publication history

Received: 21 December 2020
Revised: 31 December 2020
Accepted: 11 January 2021
Published: 04 June 2021
Issue date: November 2021

Copyright

© Tsinghua University Press and Springer-Verlag GmbH Germany, part of Springer Nature 2021
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