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Nano Research 2021, 14(11): 3977-3987 https://doi.org/10.1007/s12274-021-3323-1
Research Article | Issue | Published: 06 February 2021

Low-temperature synthesis of Fe2(MoO4)3 nanosheets: A cathode for sodium ion batteries with kinetics enhancement

Show Author's Information Ha Tran Huu1,  N. S. M. Viswanath2,  Ngoc Hung Vu3,4,  Jong-Won Lee5( ),  Won Bin Im1( )
Division of Materials Science and EngineeringHanyang University, 222, Wangsimni-ro, Seongdong-guSeoul04763Republic of Korea
School of Materials Science and EngineeringChonnam National University, 77 Yongbong-ro, Buk-guGwangju61186Republic of Korea
Falcuty of BiotechnologyChemistry and Environmental Engineering, Phenikaa UniversityHanoi10000Vietnam
A & A Green Phoenix GroupPhenikaa Research and Technology Institute (PRATI), 167 Hoang NganHanoi10000Vietnam
Department of Energy Science and EngineeringDaegu Gyeongbuk Institute of Science and Technology (DGIST), 333 Techno Jungang-daero, Hyeonpung-eup, DalseonggunDaegu42988Republic of Korea
Keywords:
sodium ion batteries, kinetics, cathode, low-temperature synthesis, Na+ super ionic conductor (NASICON)
Topics:
CathodesCharge transferIon batteriesIron compoundsLithiumMetal ionsMolybdenum compoundsMorphologyNanocrystalline materials Temperature
Cite this article:
Huu HT, Viswanath NSM, Vu NH, et al. Low-temperature synthesis of Fe2(MoO4)3 nanosheets: A cathode for sodium ion batteries with kinetics enhancement. Nano Research, 2021, 14(11): 3977-3987. https://doi.org/10.1007/s12274-021-3323-1
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Abstract Full text Electronic supplementary material About this article

Sodium ion batteries (SIBs) are alternatives to lithium ion batteries (LIBs), and offer some significant benefits such as cost reduction and a lower environmental impact; however, to compete with LIBs, further research is required to improve the performance of SIBs. In this study, an orthorhombic Na super ionic conductor structural Fe2(MoO4)3 nanosheet with amorphous-crystalline core-shell alignment was synthesized using a facile low-temperature water-vapor-assisted solid-state reaction and applied as a cathode material for SIBs. The obtained material has a well-defined three-dimensional stacking structure, and exhibits a high specific capacity of 87.8 mAh·g-1 at a current density of 1 C = 91 mA·g-1 after 1, 000 cycles, which is due to the considerable contribution of extra surface-related reaction such as the pseudo-capacitive process. This material shows significantly improved cycling and rated behavior as well as enhanced performance under high- and low-temperature conditions, as compared to the same materials prepared by the conventional high-temperature solid-state reaction. This enhancement is explained by the unique morphology in combination with the improved kinetics of the electrochemical reaction due to its lower charge transfer resistance and higher sodium ion conductivity.


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About this article

Low-temperature synthesis of Fe2(MoO4)3 nanosheets: A cathode for sodium ion batteries with kinetics enhancement

Show Author's information Ha Tran Huu1, N. S. M. Viswanath2, Ngoc Hung Vu3,4, Jong-Won Lee5( ), Won Bin Im1( )
Division of Materials Science and EngineeringHanyang University, 222, Wangsimni-ro, Seongdong-guSeoul04763Republic of Korea
School of Materials Science and EngineeringChonnam National University, 77 Yongbong-ro, Buk-guGwangju61186Republic of Korea
Falcuty of BiotechnologyChemistry and Environmental Engineering, Phenikaa UniversityHanoi10000Vietnam
A & A Green Phoenix GroupPhenikaa Research and Technology Institute (PRATI), 167 Hoang NganHanoi10000Vietnam
Department of Energy Science and EngineeringDaegu Gyeongbuk Institute of Science and Technology (DGIST), 333 Techno Jungang-daero, Hyeonpung-eup, DalseonggunDaegu42988Republic of Korea

Abstract

Sodium ion batteries (SIBs) are alternatives to lithium ion batteries (LIBs), and offer some significant benefits such as cost reduction and a lower environmental impact; however, to compete with LIBs, further research is required to improve the performance of SIBs. In this study, an orthorhombic Na super ionic conductor structural Fe2(MoO4)3 nanosheet with amorphous-crystalline core-shell alignment was synthesized using a facile low-temperature water-vapor-assisted solid-state reaction and applied as a cathode material for SIBs. The obtained material has a well-defined three-dimensional stacking structure, and exhibits a high specific capacity of 87.8 mAh·g-1 at a current density of 1 C = 91 mA·g-1 after 1, 000 cycles, which is due to the considerable contribution of extra surface-related reaction such as the pseudo-capacitive process. This material shows significantly improved cycling and rated behavior as well as enhanced performance under high- and low-temperature conditions, as compared to the same materials prepared by the conventional high-temperature solid-state reaction. This enhancement is explained by the unique morphology in combination with the improved kinetics of the electrochemical reaction due to its lower charge transfer resistance and higher sodium ion conductivity.

Keywords: sodium ion batteries, kinetics, cathode, low-temperature synthesis, Na+ super ionic conductor (NASICON)

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Publication history
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Publication history

Received: 30 October 2020
Revised: 28 December 2020
Accepted: 10 January 2021
Published: 06 February 2021
Issue date: November 2021

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© Tsinghua University Press and Springer-Verlag GmbH Germany, part of Springer Nature 2021
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