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Nano Research 2021, 14(8): 2711-2716 https://doi.org/10.1007/s12274-020-3276-9
Research Article | Issue | Published: 25 January 2021

Achieving ultrahigh electrocatalytic NH3 yield rate on Fe-doped Bi2WO6 electrocatalyst

Show Author's Information Yongqin Liu1,2,  Liang Huang2,  Youxing Fang2,  Xinyang Zhu2,  Shaojun Dong1,2( )
College of Chemistry, Jilin University, Changchun 130012, China
State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Science, Changchun 130022, China
Keywords:
electrocatalytic ammonia synthesis, ultrahigh NH3 yield rate, Fe-doped Bi2WO6, synergy effect, suppressing HER
Topics:
AmmoniaBismuth compoundsElectrocatalystsHydrogen evolution reaction Nuclear magnetic resonance spectroscopy
Cite this article:
Liu Y, Huang L, Fang Y, et al. Achieving ultrahigh electrocatalytic NH3 yield rate on Fe-doped Bi2WO6 electrocatalyst. Nano Research, 2021, 14(8): 2711-2716. https://doi.org/10.1007/s12274-020-3276-9
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Abstract Full text Electronic supplementary material About this article

NH3, derived from electrocatalytic nitrogen reduction reaction (NRR), is promising to satisfy the need of food production and serve as a carbon-free liquid energy carrier in the near future. Yet major challenges remain in enhancing NH3 yield rate and conversion efficiency of available electrocatalysts. This work achieved an ultrahigh electrocatalytic NH3 yield rate on the 0.50Fe-Bi2WO6 catalyst by a facile Fe-doped strategy. Up to 289 μg·h-1·mgcat-1 of NH3 formation rate was obtained at -0.75 V vs. RHE, which was reliably quantized by indophenol blue and 1H NMR methods. The impressive result is an order of magnitude higher than that of the reported Fe- and Bi-based catalysts, even more superior than the result of single atom Ru catalyst. The key of the outstanding NRR behaviors on the 0.50Fe-Bi2WO6 catalyst is the significant hydrogen evolution reaction (HER) suppression and the synergy between Bi and Fe, which can effectively modulate the electron distribution and accelerate the electron transport. This work endows a new insight to further explore the high-performance electrocatalysts toward NRR.


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About this article

Achieving ultrahigh electrocatalytic NH3 yield rate on Fe-doped Bi2WO6 electrocatalyst

Show Author's information Yongqin Liu1,2, Liang Huang2, Youxing Fang2, Xinyang Zhu2, Shaojun Dong1,2( )
College of Chemistry, Jilin University, Changchun 130012, China
State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Science, Changchun 130022, China

Abstract

NH3, derived from electrocatalytic nitrogen reduction reaction (NRR), is promising to satisfy the need of food production and serve as a carbon-free liquid energy carrier in the near future. Yet major challenges remain in enhancing NH3 yield rate and conversion efficiency of available electrocatalysts. This work achieved an ultrahigh electrocatalytic NH3 yield rate on the 0.50Fe-Bi2WO6 catalyst by a facile Fe-doped strategy. Up to 289 μg·h-1·mgcat-1 of NH3 formation rate was obtained at -0.75 V vs. RHE, which was reliably quantized by indophenol blue and 1H NMR methods. The impressive result is an order of magnitude higher than that of the reported Fe- and Bi-based catalysts, even more superior than the result of single atom Ru catalyst. The key of the outstanding NRR behaviors on the 0.50Fe-Bi2WO6 catalyst is the significant hydrogen evolution reaction (HER) suppression and the synergy between Bi and Fe, which can effectively modulate the electron distribution and accelerate the electron transport. This work endows a new insight to further explore the high-performance electrocatalysts toward NRR.

Keywords: electrocatalytic ammonia synthesis, ultrahigh NH3 yield rate, Fe-doped Bi2WO6, synergy effect, suppressing HER

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Publication history
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Acknowledgements

Publication history

Received: 11 October 2020
Revised: 25 November 2020
Accepted: 01 December 2020
Published: 25 January 2021
Issue date: August 2021

Copyright

© Tsinghua University Press and Springer-Verlag GmbH Germany, part of Springer Nature 2020

Acknowledgements

This work is supported by the National Natural Science Foundation of China (Nos. 21675151, 21705145 and 21721003), and the Ministry of Science and Technology of China (No. 2016YFA0203203).

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