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Nano Research 2021, 14(4): 1218-1227 https://doi.org/10.1007/s12274-020-3221-y
Research Article | Issue | Published: 01 December 2020

Fabrication of Fe nanocomplex pillared few-layered Ti3C2Tx MXene with enhanced rate performance for lithium-ion batteries

Show Author's Information Pengfei Huang,  Shunlong Zhang,  Hangjun Ying,  Wentao Yang,  Jianli Wang,  Rongnan Guo,  Weiqiang Han( )
School of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, China
Keywords:
lithium-ion batteries, Fe ions intercalation, few-layered MXene, pillared MXene
Topics:
Charge transferElectrolytesFabricationIonsIron compoundsLithium batteriesTitanium compounds
Cite this article:
Huang P, Zhang S, Ying H, et al. Fabrication of Fe nanocomplex pillared few-layered Ti3C2Tx MXene with enhanced rate performance for lithium-ion batteries. Nano Research, 2021, 14(4): 1218-1227. https://doi.org/10.1007/s12274-020-3221-y
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Abstract Full text Electronic supplementary material About this article

Pillaring technologies have been considered as an effective way to improve lithium storage performance of Ti3C2Tx MXene. Nevertheless, the pillared hybrids suffer from sluggish Li+ diffusion kinetics and electronic transportation due to the compact multi-layered MXene structure, thus exhibiting inferior rate performance. Herein, the few-layered Ti3C2 MXene (f-Ti3C2 MXene) which is free from restacking can be prepared quickly based on the NH4+ ions method. Besides, Fe nanocomplex pillared few-layered Ti3C2Tx (FPTC) heterostructures are fabricated via the intercalation of Fe ions into the interlayer of f-Ti3C2 MXene. The f-Ti3C2 MXene which is immune to restacking can provide a highly conductive substrate for the rapid transport of Li+ ions and electrons and possess adequate electrolyte accessible area. Moreover, f-Ti3C2 MXene can efficiently relieve the aggregation, prevent the pulverization and buffer the large volume change of Fe nanocomplex during lithiation/delithiation process, leading to enhanced charge transfer kinetics and excellent structural stability of FPTC composites. Consequently, the FPTC hybrids exhibit a high capacity of 535 mAh·g−1 after 150 cycles at 0.5 A·g−1 and an enhanced rate performance with 310 mAh·g−1 after 850 cycles at 5 A·g−1. This strategy is facile, universal and can be extended to fabricate various few-layered MXene-derived hybrids with superior rate capability.


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Electronic supplementary material
About this article

Fabrication of Fe nanocomplex pillared few-layered Ti3C2Tx MXene with enhanced rate performance for lithium-ion batteries

Show Author's information Pengfei Huang, Shunlong Zhang, Hangjun Ying, Wentao Yang, Jianli Wang, Rongnan Guo, Weiqiang Han( )
School of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, China

Abstract

Pillaring technologies have been considered as an effective way to improve lithium storage performance of Ti3C2Tx MXene. Nevertheless, the pillared hybrids suffer from sluggish Li+ diffusion kinetics and electronic transportation due to the compact multi-layered MXene structure, thus exhibiting inferior rate performance. Herein, the few-layered Ti3C2 MXene (f-Ti3C2 MXene) which is free from restacking can be prepared quickly based on the NH4+ ions method. Besides, Fe nanocomplex pillared few-layered Ti3C2Tx (FPTC) heterostructures are fabricated via the intercalation of Fe ions into the interlayer of f-Ti3C2 MXene. The f-Ti3C2 MXene which is immune to restacking can provide a highly conductive substrate for the rapid transport of Li+ ions and electrons and possess adequate electrolyte accessible area. Moreover, f-Ti3C2 MXene can efficiently relieve the aggregation, prevent the pulverization and buffer the large volume change of Fe nanocomplex during lithiation/delithiation process, leading to enhanced charge transfer kinetics and excellent structural stability of FPTC composites. Consequently, the FPTC hybrids exhibit a high capacity of 535 mAh·g−1 after 150 cycles at 0.5 A·g−1 and an enhanced rate performance with 310 mAh·g−1 after 850 cycles at 5 A·g−1. This strategy is facile, universal and can be extended to fabricate various few-layered MXene-derived hybrids with superior rate capability.

Keywords: lithium-ion batteries, Fe ions intercalation, few-layered MXene, pillared MXene

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Publication history
Copyright
Acknowledgements

Publication history

Received: 02 September 2020
Revised: 18 October 2020
Accepted: 01 November 2020
Published: 01 December 2020
Issue date: April 2021

Copyright

© Tsinghua University Press and Springer-Verlag GmbH Germany, part of Springer Nature

Acknowledgements

The authors are appreciative of the financial support by the Tai hu Electric Corporation 0001 and the National Natural Science Foundation of China (No. 51901206).

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