Journal Home > Volume 14 , Issue 5

As electromagnetic absorbers with wide absorption bandwidth are highly pursued in the cutting-edge electronic and telecommunication industries, the traditional dielectric or magnetic bulky absorbers remain concerns of extending the effective absorption bandwidth. In this work, a dual-principle strategy has been proposed to make a better understanding of the impact of utilizing conductive absorption fillers coupled with implementing artificial structures design on the absorption performance. In the comparison based on the microscopic studies, the carbon nanotubes (CNTs)-based absorbers are confined to narrow operating bandwidth and relatively fixed response frequency range, which can not fulfill the ever-growing demands in the application. With subsequent macroscopic structure design based on the CNTs-based dielectric fillers, the artificial patterns show much more broadened absorption bandwidth, covering the majority of C-band, the whole X-band, and Ku-band, due to the tailored electromagnetic parameters and more reflections and scatterings. The results suggest that the combination of developing microscopic powder/bulky absorbers and macroscopic configuration design will fundamentally extend the effective operating bandwidth of microwave.


menu
Abstract
Full text
Outline
Electronic supplementary material
About this article

From intrinsic dielectric loss to geometry patterns: Dual-principles strategy for ultrabroad band microwave absorption

Show Author's information Bin Quan1,2Weihua Gu1Jiaqi Sheng1Xinfeng Lv3Yuyi Mao3Lie Liu4Xiaogu Huang2( )Zongjun Tian5( )Guangbin Ji1( )
College of Materials Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, China
School of Chemistry and Materials Science, Nanjing University of Information Science & Technology, Nanjing 210044, China
National Center of Supervision and Inspection on Additive Manufacturing Products Quality, Wuxi 214000, China
Shenzhen General Test Systems Inc, Taohuayuan Hi-Tech Park, Shenzhen 518102, China
College of Mechanical and Electrical Engineering, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, China

Abstract

As electromagnetic absorbers with wide absorption bandwidth are highly pursued in the cutting-edge electronic and telecommunication industries, the traditional dielectric or magnetic bulky absorbers remain concerns of extending the effective absorption bandwidth. In this work, a dual-principle strategy has been proposed to make a better understanding of the impact of utilizing conductive absorption fillers coupled with implementing artificial structures design on the absorption performance. In the comparison based on the microscopic studies, the carbon nanotubes (CNTs)-based absorbers are confined to narrow operating bandwidth and relatively fixed response frequency range, which can not fulfill the ever-growing demands in the application. With subsequent macroscopic structure design based on the CNTs-based dielectric fillers, the artificial patterns show much more broadened absorption bandwidth, covering the majority of C-band, the whole X-band, and Ku-band, due to the tailored electromagnetic parameters and more reflections and scatterings. The results suggest that the combination of developing microscopic powder/bulky absorbers and macroscopic configuration design will fundamentally extend the effective operating bandwidth of microwave.

Keywords: numerical simulation, geometry patterns, three-dimensional (3D) printing, broadband microwave absorption

References(34)

[1]
Z. H. Zeng,; T. T. Wu,; D. X. Han,; Q. Ren,; G. Siqueira,; G. Nyström, Ultralight, flexible, and biomimetic nanocellulose/silver nanowire aerogels for electromagnetic interference shielding. ACS Nano 2020, 14, 2927-2938.
[2]
Y. K. Chang,; C. P. Mu,; B. C. Yang,; A. M. Nie,; B. C. Wang,; J. Y. Xiang,; Y. Yang,; F. S. Wen,; Z. Y. Liu, Microwave absorbing properties of two dimensional materials GeP5 enhanced after annealing treatment. Appl. Phys. Lett. 2019, 114, 013103.
[3]
M. S. Cao,; X. X. Wang,; M. Zhang,; J. C. Shu,; W. Q. Cao,; H. J. Yang,; X. Y. Fang,; J. Yuan, Electromagnetic response and energy conversion for functions and devices in low-dimensional materials. Adv. Funct. Mater. 2019, 29, 1807398.
[4]
Y. Cheng,; J. Z. Yeow Seow,; H. Q. Zhao,; Z. C. J. Xu,; G. B. Ji, A flexible and lightweight biomass-reinforced microwave absorber. Nano-Micro Lett. 2020, 12, 125.
[5]
Z. C. Lou,; R. Li,; P. Wang,; Y. Zhang,; B. Chen,; C. X. Huang,; C. C. Wang,; H. Han,; Y. J. Li, Phenolic foam-derived magnetic carbon foams (MCFs) with tunable electromagnetic wave absorption behavior. Chem. Eng. J. 2020, 391, 123571.
[6]
M. S. Cao,; X. X. Wang,; W. Q. Cao,; X. Y. Fang,; B. Wen,; J. Yuan, Thermally driven transport and relaxation switching self-powered electromagnetic energy conversion. Small 2018, 14, 1800987.
[7]
L. X. Huang,; Y. P. Duan,; X. H. Dai,; Y. S. Zeng,; G. J. Ma,; Y. Liu,; S. H. Gao,; W. P. Zhang, Bioinspired metamaterials: Multibands electromagnetic wave adaptability and hydrophobic characteristics. Small 2019, 15, 1902730.
[8]
H. Sun,; R. C. Che,; X. You,; Y. S. Jiang,; Z. B. Yang,; J. Deng,; L. B. Qiu,; H. S. Peng, Cross-stacking aligned carbon-nanotube films to tune microwave absorption frequencies and increase absorption intensities. Adv. Mater. 2014, 26, 8120-8125.
[9]
X. H. Liang,; Z. M. Man,; B. Quan,; J. Zheng,; W. H. Gu,; Z. Zhang,; G. B. Ji, Environment-stable CoxNiy encapsulation in stacked porous carbon nanosheets for enhanced microwave absorption. Nano-Micro Lett. 2020, 12, 102.
[10]
B. Quan,; W. H. Shi,; S. J. H. Ong,; X. C. Lu,; P. L. Wang,; G. B. Ji,; Y. F. Guo,; L. R. Zheng,; Z. J. Xu, Defect engineering in two common types of dielectric materials for electromagnetic absorption applications. Adv. Funct. Mater. 2019, 29, 1901236.
[11]
X. Li,; L. Wang,; W. B. You,; L. S. Xing,; X. F. Yu,; Y. S. Li,; R. C. Che, Morphology-controlled synthesis and excellent microwave absorption performance of ZnCo2O4 nanostructures via a self-assembly process of flake units. Nanoscale 2019, 11, 2694-2702.
[12]
Y. Li,; X. F. Liu,; X. Y. Nie,; W. W. Yang,; Y. D. Wang,; R. H. Yu,; J. L. Shui, Multifunctional organic-inorganic hybrid aerogel for self-cleaning, heat-insulating, and highly efficient microwave absorbing material. Adv. Funct. Mater. 2019, 29, 1807624.
[13]
X. Yin,; L. Chen,; X. Li, Ultra-broadband super light absorber based on multi-sized tapered hyperbolic metamaterial waveguide arrays. J. Lightwave Technol. 2015, 33, 3704-3710.
[14]
S. Agarwal,; Y. K. Prajapati,; V. Singh,; J. P. Saini, Polarization independent broadband metamaterial absorber based on tapered helical structure. Opt. Commun. 2015, 356, 565-570.
[15]
J. Y. Yin,; X. Wan,; J. Ren,; T. J. Cui, A circular polarizer with beamforming feature based on frequency selective surfaces. Sci. Rep. 2017, 7, 41505.
[16]
N. Zhang,; P. H. Zhou,; S. Y. Wang,; X. L. Weng,; J. L. Xie,; L. J. Deng, Broadband absorption in mid-infrared metamaterial absorbers with multiple dielectric layers. Opt. Commun. 2015, 338, 388-392.
[17]
J. Ren,; J. Y. Yin, 3D-printed low-cost dielectric-resonator-based ultra-broadband microwave absorber using carbon-loaded acrylonitrile butadiene styrene polymer. Materials 2018, 11, 1249.
[18]
R. Kronberger,; P. Soboll, New 3D printed microwave metamaterial absorbers with conductive printing materials. In Proceedings of the 46th European Microwave Conference, London, UK, 2016, pp 596-599.
[19]
Q. M. Hu,; R. L. Yang,; Z. C. Mo,; D. W. Lu,; L. L. Yang,; Z. F. He,; H. Zhu,; Z. K. Tang,; X. C. Gui, Nitrogen-doped and Fe-filled CNTs/NiCo2O4 porous sponge with tunable microwave absorption performance. Carbon 2019, 153, 737-744.
[20]
H. Han,; Z. C. Lou,; P. Wang,; Q. Y. Wang,; R. Li,; Y. Zhang,; Y. J. Li, Synthesis of ultralight and porous magnetic g-C3N4/g-carbon foams with excellent electromagnetic wave (EMW) absorption performance and their application as a reinforcing agent for 3D printing EMW absorbers. Ind. Eng. Chem. Res. 2020, 59, 7633-7645.
[21]
B. Quan,; X. H. Liang,; G. B. Ji,; J. Lv,; S. S. Dai,; G. Y. Xu,; Y. W. Du, Laminated graphene oxide-supported high-efficiency microwave absorber fabricated by an in situ growth approach. Carbon 2018, 129, 310-320.
[22]
Q. H. Liu,; Q. Cao,; H. Bi,; C. Y. Liang,; K. P. Yuan,; W. She,; Y. J. Yang,; R. C. Che, CoNi@SiO2@TiO2 and CoNi@Air@TiO2 Microspheres with strong wideband microwave absorption. Adv. Mater. 2016, 28, 486-490.
[23]
X. J. Liao,; W. Ye,; L. L. Chen,; S. H. Jiang,; G. Wang,; L. Zhang,; H. Q. Hou, Flexible hdC-G reinforced polyimide composites with high dielectric permittivity. Compos. Part A 2017, 101, 50-58.
[24]
P. Y. Hu,; J. Lyu,; C. Fu,; W. B. Gong,; J. H. Liao,; W. B. Lu,; Y. P. Chen,; X. T. Zhang, Multifunctional aramid nanofiber/carbon nanotube hybrid aerogel films. ACS Nano 2020, 14, 688-697.
[25]
B. Wen,; M. S. Cao,; Z. L. Hou,; W. L. Song,; L. Zhang,; M. M. Lu,; H. B. Jin,; X. Y. Fang,; W. Z. Wang,; J. Yuan, Temperature dependent microwave attenuation behavior for carbon-nanotube/silica composites. Carbon 2013, 65, 124-139.
[26]
M. S. Cao,; W. L. Song,; Z. L. Hou,; B. Wen,; J. Yuan, The effects of temperature and frequency on the dielectric properties, electromagnetic interference shielding and microwave-absorption of short carbon fiber/silica composites. Carbon 2010, 48, 788-796.
[27]
K. Aydin,; V. E. Ferry,; R. M. Briggs,; H. A. Atwater, Broadband polarization-independent resonant light absorption using ultrathin plasmonic super absorbers. Nat. Commun. 2011, 2, 517.
[28]
X. L. Liu,; T. Starr,; A. F. Starr,; W. J. Padilla, Infrared spatial and frequency selective metamaterial with near-unity absorbance. Phys. Rev. Lett. 2010, 104, 207403.
[29]
Y. X. Huang,; W. L. Song,; C. X. Wang,; Y. N. Xu,; W. Y. Wei,; M. J. Chen,; L. Q. Tang,; D. N. Fang, Multi-scale design of electromagnetic composite metamaterials for broadband microwave absorption. Compos. Sci. Technol. 2018, 162, 206-214.
[30]
A. B. Li,; X. G. Zhao,; G. W. Duan,; S. Anderson,; X. Zhang, Diatom Frustule-inspired metamaterial absorbers: The effect of hierarchical pattern arrays. Adv. Funct. Mater. 2019, 29, 1809029.
[31]
M. Layani,; X. F. Wang,; S. Magdassi, Novel materials for 3D printing by photopolymerization. Adv. Mater. 2018, 30, 1706344.
[32]
L. Hirt,; A. Reiser,; R. Spolenak,; T. Zambelli, Additive manufacturing of metal structures at the micrometer scale. Adv. Mater. 2017, 29, 1604211.
[33]
G. H. Hu,; J. Kang,; L. W. T. Ng,; X. X. Zhu,; R. C. T. Howe,; C. G. Jones,; M. C. Hersam,; T. Hasan, Functional inks and printing of two-dimensional materials. Chem. Soc. Rev. 2018, 47, 3265-3300.
[34]
Y. Si,; X. Q. Wang,; L. Y. Dou,; J. Y. Yu,; B. Ding, Ultralight and fire-resistant ceramic nanofibrous aerogels with temperature-invariant superelasticity. Sci. Adv. 2018, 4, eaas8925.
File
12274_2020_3208_MOESM1_ESM.pdf (3.2 MB)
Publication history
Copyright
Acknowledgements

Publication history

Received: 14 August 2020
Revised: 18 October 2020
Accepted: 22 October 2020
Published: 02 December 2020
Issue date: May 2021

Copyright

© Tsinghua University Press and Springer-Verlag GmbH Germany, part of Springer Nature

Acknowledgements

Financial supports from the National Natural Science Foundation of China (No. 51971111), the Startup Foundation for Introducing Talent of NUIST, and the Jiangsu Provincial Key Laboratory of Bionic Functional Materials were gratefully acknowledged.

Return