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Research Article

Multi-redox phenazine/non-oxidized graphene/cellulose nanohybrids as ultrathick cathodes for high-energy organic batteries

Youngjin Ham1, Vitalii Ri2, Jin Kim1, Yeoheung Yoon3, Jinho Lee1, Kisuk Kang4, Ki-Seok An3( ), Chunjoong Kim2( ), Seokwoo Jeon1( )
Department of Materials Science and Engineering, Advanced Battery Center, Korea Advanced Institute of Science and Technology (KAIST), Daejeon 34141, Republic of Korea
Department of Materials Science and Engineering, Chungnam National University, Daejeon 34134, Republic of Korea
Thin Film Materials Research Center, Korea Research Institute of Chemical Technology (KRICT), Daejeon 34114, Republic of Korea
Department of Materials Science and Engineering, Seoul National University, Seoul 08826, Republic of Korea
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Graphical Abstract

Abstract

Various redox-active organic molecules can serve as ideal electrode materials to realize sustainable energy storage systems. Yet, to be more appropriate for practical use, considerable architectural engineering of an ultrathick, high-loaded organic electrode with reliable electrochemical performance is of crucial importance. Here, by utilizing the synergetic effect of the non-covalent functionalization of highly conductive non-oxidized graphene flakes (NOGFs) and introduction of mechanically robust cellulose nanofiber (CNF)-intermingled structure, a very thick (≈ 1 mm), freestanding organic nanohybrid electrode which ensures the superiority in cycle stability and areal capacity is reported. The well-developed ion/electron pathways throughout the entire thickness and the enhanced kinetics of electrochemical reactions in the ultrathick 5,10-dihydro-5,10-dimethylphenazine/NOGF/CNF (DMPZ-NC) cathodes lead to the high areal energy of 9.4 mWh·cm-2 (= 864 Wh·kg-1 at 158 W·kg-1). This novel ultrathick electrode architecture provides a general platform for the development of the high-performance organic battery electrodes.

Keywords

grapheneenergy storagebatteriesorganic electrodescellulose nanofibers

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Nano Research
Volume 14 Issue 5,
May 2021
Pages 1382-1389
DOI: 10.1007/s12274-020-3187-9
Cite this article:
Ham Y, Ri V, Kim J, et al. Multi-redox phenazine/non-oxidized graphene/cellulose nanohybrids as ultrathick cathodes for high-energy organic batteries. Nano Research, 2021, 14(5): 1382-1389. https://doi.org/10.1007/s12274-020-3187-9
Topics:
CathodesCerium compoundsElectric batteries Energy storageGrapheneNanostructured materialsRedox reactions

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Received: 24 August 2020
Revised: 11 October 2020
Accepted: 16 October 2020
Published: 09 November 2020
© Tsinghua University Press and Springer-Verlag GmbH Germany, part of Springer Nature
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