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Research Article

Z-scheme photocatalyst based on porphyrin derivative decorated few-layer BiVO4 nanosheets for efficient visible-light-driven overall water splitting

Jinming Wang1,3, Lulu Guo1,3, Lei Xu1,3, Peng Zeng2,3( ), Renjie Li1( ), Tianyou Peng1,3( )
College of Chemistry and Molecular Sciences, Engineering Research Center of Organosilicon Compounds & Materials, Ministry of Education, Wuhan University, Wuhan 430072, China
School of Food and Pharmaceutical Engineering, Zhaoqing University, Zhaoqing 526061, China
Research Institute of Wuhan University in Shenzhen, Wuhan University, Shenzhen 518057, China
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Graphical Abstract

Abstract

It is highly desirable to simulate natural photosynthesis by using sunlight to drive the overall water splitting without using external bias and sacrificial agent. Herein, few-layer monoclinic BiVO4 nanosheets (BVNS) with a thickness of ~4.3 nm, exposed (010) facets and abundant oxygen vacancies are fabricated using graphene oxide dots as templating reagent. After decorating with asymmetric chromium porphyrin derivative bearing one benzoic acid and three phenyls as meso-position substituents (chromium-5-(4-carboxyphenyl)-10,15,20-triphenylporphrin, CrmTPP) and PtOx cocatalyst, the obtained two-dimensional (2D) hybrid nanocomposite (BVNS/CrmTPP/Pt) with an optimal component ratio delivers a robust overall water splitting performance with a relatively high apparent quantum yield (8.67%) at 400 nm monochromatic light. The ultrathin structure and widely distributed oxygen vacancies on the exposed (010) facets of BVNS not only endow strong and intimate contact with the decorated CrmTPP molecules to promote a two-step excitation Z-scheme charge transfer mechanism for preserving the high redox ability of the photogenerated charge carriers, but also alleviate their recombination, and thus causing the robust overall water splitting performance of the 2D hybrid nanocomposites. The present results provide a novel strategy to construct highly efficient artificial photosynthetic system for overall water splitting.

Keywords

Z-scheme photocatalystultrathin BiVO4 nanosheetporphyrin derivativeoverall water splittingartificial photosynthesis

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References

[1]
M. S. Zhu,; Z. C. Sun,; M. Fujitsuka,; T. Majima, Z-scheme photocatalytic water splitting on a 2D heterostructure of black phosphorus/bismuth vanadate using visible light. Angew. Chem., Int. Ed. 2018, 57, 2160-2164.
Google Scholar
[2]
Y. Zhang,; L. L. Wu,; X. Y. Zhao,; Y. N. Zhao,; H. Q. Tan,; X. Zhao,; Y. Y. Ma,; Z. Zhao,; S. Y. Song,; Y. H. Wang, et al. Leaf-mosaic-inspired vine-like graphitic carbon nitride showing high light absorption and efficient photocatalytic hydrogen evolution. Adv. Energy Mater. 2018, 8, 1801139.
Google Scholar
[3]
L. Hui,; Y. R. Xue,; B. L. Huang,; H. D. Yu,; C. Zhang,; D. Y. Zhang,; D. Z. Jia,; Y. J. Zhao,; Y. J. Li,; H. B. Liu, et al. Overall water splitting by graphdiyne-exfoliated and -sandwiched layered double-hydroxide nanosheet arrays. Nat. Commun. 2018, 9, 5309.
Google Scholar
[4]
J. M. Wang,; J. Luo,; D. Liu,; S. T. Chen,; T. Y. Peng, One-pot solvothermal synthesis of MoS2-modified Mn0.2Cd0.8S/MnS heterojunction photocatalysts for highly efficient visible-light-driven H2 production. Appl. Catal. B Environ. 2019, 241, 130-140.
Google Scholar
[5]
Y. Tsuji,; K. Yamamoto,; K. Yamauchi,; K. Sakai, Near-infrared light-driven hydrogen evolution from water using a polypyridyl triruthenium photosensitizer. Angew. Chem., Int. Ed. 2018, 57, 208-212.
Google Scholar
[6]
J. Q. Xu,; X. D. Li,; Z. Y. Ju,; Y. F. Sun,; X. C. Jiao,; J. Wu,; C. M. Wang,; W. S. Yan,; H. X. Ju,; J. F. Zhu, et al. Visible-light-driven overall water splitting boosted by tetrahedrally coordinated blende cobalt(II) oxide atomic layers. Angew. Chem., Int. Ed. 2019, 58, 3032-3036.
Google Scholar
[7]
C. W. Dong,; S. Y. Lu,; S. Y. Yao,; R. Ge,; Z. D. Wang,; Z. Wang,; P. F. An,; Y. Liu,; B. Yang,; H. Zhang, Colloidal synthesis of ultrathin monoclinic BiVO4 nanosheets for Z-scheme overall water splitting under visible light. ACS Catal. 2018, 8, 8649-8658.
Google Scholar
[8]
X. H. Zhang,; J. Xiao,; M. Hou,; Y. G. Xiang,; H. Chen, Robust visible/near-infrared light driven hydrogen generation over Z-scheme conjugated polymer/CdS hybrid. Appl. Catal. B Environ. 2018, 224, 871-876.
Google Scholar
[9]
Q. Wang,; T. Hisatomi,; Y. Suzuk,; Z. H. Pan,; J. Seo,; M. Katayama,; T. Minegishi,; H. Nishiyama,; T. Takata,; K. Seki, et al. Particulate photocatalyst sheets based on carbon conductor layer for efficient Z-scheme pure-water splitting at ambient pressure. J. Am. Chem. Soc. 2017, 139, 1675-1683.
Google Scholar
[10]
Q. Zhang,; W. J. Wang,; J. Q. Zhang,; X. H. Zhu,; Q. Q. Zhang,; Y. J. Zhang,; Z. M. Ren,; S. S. Song,; J. M. Wang,; Z. H. Ying, et al. Highly efficient photocatalytic hydrogen evolution by ReS2 via a two-electron catalytic reaction. Adv. Mater. 2018, 30, 1707123.
Google Scholar
[11]
X. Hai,; W. Zhou,; K. Chang,; H. Pang,; H. M. Liu,; L. Shi,; F. Ichihara,; J. H. Ye, Engineering the crystallinity of MoS2 monolayers for highly efficient solar hydrogen production. J. Mater. Chem. A 2017, 5, 8591-8598.
Google Scholar
[12]
S. Ida,; N. Kim,; E. Ertekin,; S. Takenaka,; T. Ishihara, Photocatalytic reaction centers in two-dimensional titanium oxide crystals. J. Am. Chem. Soc. 2015, 137, 239-244.
Google Scholar
[13]
M. Xiao,; B. Luo,; M. Q. Lyu,; S. C. Wang,; L. Z. Wang, Single-crystalline nanomesh tantalum nitride photocatalyst with improved hydrogen-evolving performance. Adv. Energy Mater. 2018, 8, 1701605.
Google Scholar
[14]
F. Ye,; H. F. Li,; H. T. Yu,; S. Chen,; X. Quan, Constructing BiVO4-Au@CdS photocatalyst with energic charge-carrier-separation capacity derived from facet induction and Z-scheme bridge for degradation of organic pollutants. Appl. Catal. B Environ. 2018, 227, 258-265.
Google Scholar
[15]
Z. F. Jiang,; W. M. Wan,; H. M Li,; S. Q. Yuan,; H. J. Zhao,; P. K. Wong, A hierarchical Z-scheme α-Fe2O3/g-C3N4 hybrid for enhanced photocatalytic CO2 reduction. Adv. Mater. 2018, 11, 1706108.
Google Scholar
[16]
W. K. Jo,; T. S. Natarajan, Facile synthesis of novel redox-mediator-free direct z-scheme CaIn2S4 marigold-flower-like/TiO2 photocatalysts with superior photocatalytic efficiency. ACS Appl. Mater. Interfaces 2015, 7, 17138-17154.
Google Scholar
[17]
A. Fateeva,; P. A. Chater,; C. P. Ireland,; A. A. Tahir,; Y. Z. Khimyak,; P. V. Wiper,; J. R. Darwent,; M. J. Rosseinsky, A water-stable porphyrin-based metal-organic framework active for visible-light photocatalysis. Angew. Chem., Int. Ed. 2012, 51, 7440-7444.
Google Scholar
[18]
J. M. Wang,; Y. Zheng,; T. Y. Peng,; J. Zhang,; R. J. Li, Asymmetric zinc porphyrin derivative-sensitized graphitic carbon nitride for efficient visible-light-driven H2 production. ACS Sustain. Chem. Eng. 2017, 5, 7549-7556.
Google Scholar
[19]
K. Li,; L. Lin,; T. Y. Peng,; Y. Y. Guo,; R. J. Li,; J. Zhang, Asymmetric zinc porphyrin-sensitized nanosized TiO2 for efficient visible-light-driven CO2 photoreduction to CO/CH4. Chem. Commun. 2015, 51, 12443-12446.
Google Scholar
[20]
J. M. Wang,; D. Liu,; Q. W. Liu,; T. Y. Peng,; R. J. Li,; S. Y. Zhou, Effects of the central metal ions on the photosensitization of metalloporphyrins over carbon nitride for visible-light-responsive H2 production. Appl. Surf. Sci. 2019, 464, 255-261.
Google Scholar
[21]
Y. Zheng,; J. M. Wang,; J. Zhang,; T. Y. Peng,; R. J. Li, Syntheses of asymmetric zinc porphyrins bearing different pseudo-pyridine substituents and their photosensitization for visible-light-driven H2 production activity. Dalton Trans. 2017, 46, 8219-8228.
Google Scholar
[22]
X. H. Zhang,; T. Y. Peng,; L. J. Yu,; R. J. Li,; Q. Q. Li,; Z. Li, visible/near-infrared-light-induced h2 production over g-C3N4 co-sensitized by organic dye and zinc phthalocyanine derivative. ACS Catal. 2015, 5, 504-510.
Google Scholar
[23]
X. H. Zhang,; T. Y. Peng,; S. S. Song, Recent advances in dye-sensitized semiconductor systems for photocatalytic hydrogen production. J. Mater. Chem. A 2016, 4, 2365-2402.
Google Scholar
[24]
H. Hagiwara,; M. Nagatomo,; C. Seto,; S. Ida,; T. Ishiahara, Dye modification effects on TaON for photocatalytic hydrogen production from water. Catalysts 2013, 3, 614-624.
Google Scholar
[25]
H. Hagiwara,; T. Inoue,; K. Kaneko,; T. Ishihara, Charge-transfer mechanism in Pt/KTa(Zr)O3 photocatalysts modified with porphyrinoids for water splitting. Chem.—Eur. J. 2009, 15, 12862-12870.
Google Scholar
[26]
H. Hagiwara,; M. Nagatomo,; C. Seto,; S. Ida,; T. Ishihara, Dye-modification effects on water splitting activity of GaN: ZnO photocatalyst. J. Photochem. Photobio. A Chem. 2013, 272, 41-48.
Google Scholar
[27]
K. Hu,; C. Y. Chen,; Y. Zhu,; G. M. Zeng,; B. B. Huang,; W. Q. Chen,; S. H. Liu,; C. Lei,; B. S. Li,; Y. Yang, Ternary Z-scheme heterojunction of Bi2WO6 with reduced graphene oxide (rGO) and meso-tetra (4-carboxyphenyl) porphyrin (TCPP) for enhanced visible-light photocatalysis. J. Colloid Interf. Sci. 2019, 540, 115-125.
Google Scholar
[28]
P. Li,; X. H. Zhang,; C. C. Hou,; Y. Chen,; T. He, Highly efficient visible-light driven solar-fuel production over tetra(4-carboxyphenyl)porphyrin iron(III) chloride using CdS/Bi2S3 heterostructure as photosensitizer. Appl. Catal. B Environ. 2018, 238, 656-663.
Google Scholar
[29]
B. S. Nguyen,; Y. K. Xiao,; C. Y. Shih,; V. C. Nguyen,; W. Y. Chou,; H. Teng, Electronic structure manipulation of graphene dots for effective hydrogen evolution from photocatalytic water decomposition. Nanoscale 2018, 10, 10721-10730.
Google Scholar
[30]
L. Stobinski,; B. Lesiak,; A. Malolepszy,; M. Mazurkiewicz,; B. Mierzwa,; J. Zemek,; P. Jiricek,; I. Bieloshapka, Graphene oxide and reduced graphene oxide studied by the XRD, TEM and electron spectroscopy methods. J. Electron Spectrosc. Relat. Phenom. 2014, 195, 145-154.
Google Scholar
[31]
R. G. Li,; F. X. Zhang,; D. G. Wang,; J. X. Yang,; M. R. Li,; J. Zhu,; X. Zhou,; H. X. Han,; C. Li, Spatial separation of photogenerated electrons and holes among {010} and {110} crystal facets of BiVO4. Nat. Commun. 2013, 4, 1432.
Google Scholar
[32]
Y. S. Fu,; X. Q. Sun,; X. Wang, BiVO4-graphene catalyst and its high photocatalytic performance under visible light irradiation. Mater. Chem. Phys. 2011, 131, 325-330.
Google Scholar
[33]
H. S. Kibombo,; C. M. Wua,; R. Peng,; J. Baltrusaitis,; R. T. Koodali, Investigation of the role of platinum oxide for the degradation of phenol under simulated solar irradiation. Appl. Catal. B Environ. 2013, 136-137, 248-259.
Google Scholar
[34]
B. Ohtani,; K. Iwai,; S. I Nishimoto,; S. Sato, Role of platinum deposits on titanium(IV) oxide particles: Structural and kinetic analyses of photocatalytic reaction in aqueous alcohol and amino acid solutions. J. Phys. Chem. B 1997, 101, 3349-3359.
Google Scholar
[35]
J. Lee,; W. Choi, Photocatalytic reactivity of surface platinized TiO2: Substrate specificity and the effect of Pt oxidation state. J. Phys. Chem. B 2005, 109, 7399-7406.
Google Scholar
[36]
J. F. Liu,; X. T. Yu,; R. F. Du,; C. Q. Zhang,; T. Zhang,; J. Llorca,; J. Arbiol,; Y. Wang,; M. Meyns,; A. Cabot, Chromium phosphide CrP as highly active and stable electrocatalysts for oxygen electroreduction in alkaline media. Appl. Catal. B Environ. 2019, 256, 117846.
Google Scholar
[37]
H. L. Tan,; A. Suyanto,; A. T. De Denko,; W. H. Saputera,; R. Amal,; F. E. Osterloh,; Y. H. Ng, Enhancing the photoactivity of faceted BiVO4 via annealing in oxygen-deficient condition. Part. Part. Syst. Charact. 2017, 34, 1600290.
Google Scholar
[38]
J. Yin,; Y. X. Li,; F. Lv,; M. Lu,; K. Sun,; W. Wang,; L. Wang,; F. Y. Cheng,; Y. F. Li,; P. X. Xi, et al. Oxygen vacancies dominated NiS2/CoS2 interface porous nanowires for portable Zn-Air batteries driven water splitting devices. Adv. Mater. 2017, 29, 1704681.
Google Scholar
[39]
S. Bai,; C. Gao,; J. X. Low,; Y. J. Xiong, Crystal phase engineering on photocatalytic materials for energy and environmental applications. Nano Res. 2019, 12, 2031-2054.
Google Scholar
[40]
D. Zu,; H. Y. Wang,; S. Lin,; G. Ou,; H. H. Wei,; S. Q. Sun,; H. Wu, Oxygen-deficient metal oxides: Synthesis routes and applications in energy and environment. Nano Res. 2019, 12, 2150-2163.
Google Scholar
[41]
S. F. Tian,; S. D. Chen,; X. T. Ren,; Y. Q. Hu,; H. Y. Hu,; J. J. Sun,; F. Bai, An efficient visible-light photocatalyst for CO2 reduction fabricated by cobalt porphyrin and graphitic carbon nitride via covalent bonding. Nano Res. 2020, 13, 2665-2672.
Google Scholar
[42]
X. F. Wang,; P. F. Sun,; H. L. Lu,; K. Tang,; Q. Li,; C. Wang,; Z. Y. Mao,; T. Ali,; C. L. Yan, Aluminum-tailored energy level and morphology of Co3-xAlxO4 porous nanosheets toward highly efficient electrocatalysts for water oxidation. Small 2019, 15, 1804886.
Google Scholar
[43]
W. J. Chun,; A. Ishikawa,; H. Fujisawa,; T. Takata,; J. N. Kondo,; M. Hara,; M. Kawai,; Y. Matsumoto,; K. Domen, Conduction and valence band positions of Ta2O5, TaON, and Ta3N5 by UPS and electrochemical methods. J. Phys. Chem. B 2003, 107, 1798-1803.
Google Scholar
[44]
H. L. Tan,; F. F. Abdi,; Y. H. Ng, Heterogeneous photocatalysts: An overview of classic and modern approaches for optical, electronic, and charge dynamics evaluation. Chem. Soc. Rev. 2019, 48, 1255-1271.
Google Scholar
[45]
S. C. Wang,; P. Chen,; Y. Bai,; J. H. Yun,; G. Liu,; L. Z. Wang, New BiVO4 dual photoanodes with enriched oxygen vacancies for efficient solar-driven water splitting. Adv. Mater. 2018, 30, 1800486.
Google Scholar
[46]
C. S. Diercks,; S. Lin,; N. Kornienko,; E. A. Kapustin,; E. M. Nichols,; C. H. Zhu,; Y. B. Zhao,; C. J. Chang,; O. M. Yaghi, Reticular electronic tuning of porphyrin active sites in covalent organic frameworks for electrocatalytic carbon dioxide reduction. J. Am. Chem. Soc. 2018, 140, 1116-1122.
Google Scholar
[47]
P. F. Xia,; B. C. Zhu,; B. Cheng,; J. G. Yu,; J. S. Xu, 2D/2D g-C3N4/MnO2 nanocomposite as a direct Z-scheme photocatalyst for enhanced photocatalytic activity. ACS Sustainable Chem. Eng. 2018, 6, 965-973.
Google Scholar
[48]
A. Iwase,; Y. H. Ng,; Y. Ishiguro,; A. Kudo,; R. Amal, Reduced graphene oxide as a solid-state electron mediator in Z-scheme photocatalytic water splitting under visible light. J. Am. Chem. Soc. 2011, 133, 11054-11057.
Google Scholar
Nano Research
Volume 14 Issue 5,
May 2021
Pages 1294-1304
DOI: 10.1007/s12274-020-3145-6
Cite this article:
Wang J, Guo L, Xu L, et al. Z-scheme photocatalyst based on porphyrin derivative decorated few-layer BiVO4 nanosheets for efficient visible-light-driven overall water splitting. Nano Research, 2021, 14(5): 1294-1304. https://doi.org/10.1007/s12274-020-3145-6
Topics:
Charge transferChromium compoundsGrapheneLightNanocompositesNanosheetsPhotocatalystsPlatinum compounds

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Received: 24 August 2020
Revised: 23 September 2020
Accepted: 24 September 2020
Published: 29 December 2020
© Tsinghua University Press and Springer-Verlag GmbH Germany, part of Springer Nature
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