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Research Article

Light-responsive color switching of self-doped TiO2-x/WO3·0.33H2O hetero-nanoparticles for highly efficient rewritable paper

Jingmei Zhao, Luntao Liu, Yun Zhang, Zhenyu Feng, Feifei Zhao, Wenshou Wang( )
National Engineering Research Center for Colloidal Materials and School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China
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Abstract

Smart materials that reversibly change color upon light illumination are widely explored for diverse appealing applications. However, light-responsive color switching materials are mainly limited to organic molecules. The synthesis of inorganic counterparts has remained a significant challenge because of their slow light response and poor reversibility. Here, we report a seeded growth strategy for the synthesis of TiO2-x/WO3·0.33H2O hetero-nanoparticles (HNPs) with networked wire-like structure of ~ 10 nm in diameters that enable the highly reversible light-responsive color switching properties. For the TiO2-x/WO3·0.33H2O HNPs, Ti3+ species self-doped in TiO2-x nanoparticles (NPs) act as efficient sacrificial electron donors (SEDs) and Ti-O-W linkages formed between TiO2-x and WO3·0.33H2O NPs ensure the nanoscale interfacial contact, endowing the HNPs enhanced photoreductive activity and efficient interfacial charge transfer upon ultraviolet (UV) illumination to achieve highly efficient color switching. The TiO2-x/WO3·0.33H2O HNPs exhibits rapid light response (< 15 s) and long reversible color switching cycles (> 180 times). We further demonstrate the applications of TiO2-x/WO3·0.33H2O HNPs in ink-free, light-printable rewritable paper that can be written on freehand or printed on through a photomask using UV light. This work opens an avenue for designing inorganic light-responsive color switching nanomaterials and their smart applications.

Keywords

light-responsecolor switchingself-dopinghetero-nanoparticlesrewritable paper

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References

[1]
C. C. Jia,; A. Migliore,; N. Xin,; S. Y. Huang,; J. Y. Wang,; Q. Yang,; S. P. Wang,; H. L. Chen,; D. M. Wang,; B. Y. Feng, et al. Covalently bonded single-molecule junctions with stable and reversible photoswitched conductivity. Science 2016, 352, 1443-1445.
Crossref Google Scholar
[2]
P. K. Kundu,; D. Samanta,; R. Leizrowice,; B. Margulis,; H. Zhao,; M. Börner,; T. Udayabhaskararao,; D. Manna,; R. Klajn, Light-controlled self-assembly of non-photoresponsive nanoparticles. Nat. Chem. 2015, 7, 646-652.
Crossref Google Scholar
[3]
Z. Q. Li,; G. N. Wang,; Y. X. Ye,; B. Li,; H. R. Li,; B. L. Chen, Loading photochromic molecules into a luminescent metal-organic framework for information anticounterfeiting. Angew. Chem., Int. Ed. 2019, 58, 18025-18031.
Crossref Google Scholar
[4]
M. I. Khazi,; W. Jeong,; J. M. Kim, Functional materials and systems for rewritable paper. Adv. Mater. 2018, 30, 1705310.
Crossref Google Scholar
[5]
W. S. Wang,; N. Xie,; L. He,; Y. D. Yin, Photocatalytic colour switching of redox dyes for ink-free light-printable rewritable paper. Nat. Commun. 2014, 5, 5459.
Crossref Google Scholar
[6]
Y. Q. Yang,; J. Q. Li,; X. Y. Li,; L. Guan,; Z. J. Gao,; L. J. Duan,; F. Jia,; G. H. Gao, Easily prepared and reusable films for fast-response rewritable light printing. ACS Appl. Mater. Interfaces 2019, 11, 14322-14328.
Crossref Google Scholar
[7]
A. Fihey,; A. Perrier,; W. R. Browne,; D. Jacquemin, Multiphotochromic molecular systems. Chem. Soc. Rev. 2015, 44, 3719-3759.
Crossref Google Scholar
[8]
M. Irie,; T. Fukaminato,; K. Matsuda,; S. Kobatake, Photochromism of diarylethene molecules and crystals: Memories, switches, and actuators. Chem. Rev. 2014, 114, 12174-12277.
Crossref Google Scholar
[9]
G. X. Huang,; Q. Xia,; W. B. Huang,; J. W. Tian,; Z. K. He,; B. S. Li,; B. Z. Tang, Multiple anti-counterfeiting guarantees from a simple tetraphenylethylene derivative-high-contrasted and multi-state mechanochromism and photochromism. Angew. Chem., Int. Ed. 2019, 58, 17814-17819.
Crossref Google Scholar
[10]
W. S. Wang,; L. T. Liu,; J. Feng,; Y. D. Yin, Photocatalytic reversible color switching based on titania nanoparticles. Small Methods 2018, 2, 1700273.
Crossref Google Scholar
[11]
H. X. Gu,; C. S. Guo,; S. H. Zhang,; L. H. Bi,; T. C. Li,; T. D. Sun,; S. Q. Liu, Highly efficient, near-infrared and visible light modulated electrochromic devices based on polyoxometalates and W18O49 nanowires. ACS Nano 2018, 12, 559-567.
Google Scholar
[12]
J. X. Zhao,; Y. Y. Tian,; Z. Wang,; S. Cong,; D. Zhou,; Q. Z. Zhang,; M. Yang,; W. K. Zhang,; F. X. Geng,; Z. G. Zhao, Trace H2O2-assisted high-capacity tungsten oxide electrochromic batteries with ultrafast charging in seconds. Angew. Chem., Int. Ed. 2016, 55, 7161-7165.
Google Scholar
[13]
L. Santos,; P. Wojcik,; J. V. Pinto,; E. Elangovan,; J. Viegas,; L. Pereira,; R. Martins,; E. Fortunato, Structure and morphologic influence of WO3 nanoparticles on the electrochromic performance of dual-phase a-WO3/WO3 inkjet printed films. Adv. Electron. Mater. 2015, 1, 1400002.
Google Scholar
[14]
S. Yamazaki,; H. Ishida,; D. Shimizu,; K. Adachi, Photochromic properties of tungsten oxide/methylcellulose composite film containing dispersing agents. ACS Appl. Mater. Interfaces 2015, 7, 26326-26332.
Google Scholar
[15]
J. Dong,; J. P. Zhang, Photochromic and super anti-wetting coatings based on natural nanoclays. J. Mater. Chem. A 2019, 7, 3120-3127.
Google Scholar
[16]
S. Yamazaki,; D. Shimizu,; S. Tani,; K. Honda,; M. Sumimoto,; K. Komaguchi, Effect of dispersants on photochromic behavior of tungsten oxide nanoparticles in methylcellulose. ACS Appl. Mater. Interfaces 2018, 10, 19889-19896.
Google Scholar
[17]
R. T. Wen,; C. G. Granqvist,; G. A. Niklasson, Eliminating degradation and uncovering ion-trapping dynamics in electrochromic WO3 thin films. Nat. Mater. 2015, 14, 996-1001.
Google Scholar
[18]
A. Azam,; J. Kim,; J. Park,; T. G. Novak,; A. P. Tiwari,; S. H. Song,; B. Kim,; S. Jeon, Two-dimensional WO3 nanosheets chemically converted from layered WS2 for high-performance electrochromic devices. Nano Lett. 2018, 18, 5646-5651.
Google Scholar
[19]
J. Wei,; X. L. Jiao,; T. Wang,; D. R. Chen, Electrospun photochromic hybrid membranes for flexible rewritable media. ACS Appl. Mater. Interfaces 2016, 8, 29713-29720.
Google Scholar
[20]
S. F. Wang,; W. R. Fan,; Z. C. Liu,; A. B. Yu,; X. C. Jiang, Advances on tungsten oxide based photochromic materials: Strategies to improve their photochromic properties. J. Mater. Chem. C 2018, 6, 191-212.
Google Scholar
[21]
Z. Z. Lou,; P. Zhang,; J. Li,; X. G. Yang,; B. B. Huang,; B. J. Li, Plasmonic heterostructure TiO2-MCs/WO3-x-NWs with continuous photoelectron injection boosting hot electron for methane generation. Adv. Funct. Mater. 2019, 29, 1808696.
Google Scholar
[22]
H. Khan,; M. G. Rigamonti,; G. S. Patience,; D. C. Boffito, Spray dried TiO2/WO3 heterostructure for photocatalytic applications with residual activity in the dark. Appl. Catal. B 2018, 226, 311-323.
Google Scholar
[23]
M. Grandcolas,; T. Cottineau,; A. Louvet,; N. Keller,; V. Keller, Solar light-activated photocatalytic degradation of gas phase diethylsulfide on WO3-modified TiO2 nanotubes. Appl. Catal. B 2013, 138-139, 128-140.
Google Scholar
[24]
M. Nolan,; A. Iwaszuk,; A. K. Lucid,; J. J. Carey,; M. Fronzi, Design of novel visible light active photocatalyst materials: Surface modified TiO2. Adv. Mater. 2016, 28, 5425-5446.
Google Scholar
[25]
G. Xi,; L. Sheng,; J. H. Du,; J. Y. Zhang,; M. J. Li,; H. Z. Wang,; Y. F. Ma,; S. X. A. Zhang, Water assisted biomimetic synergistic process and its application in water-jet rewritable paper. Nat. Commun. 2018, 9, 4819.
Google Scholar
[26]
H. B. Sun,; S. J. Liu,; W. P. Lin,; K. Y. Zhang,; W. Lv,; X. Huang,; F. W. Huo,; H. R. Yang,; G. Jenkins,; Q. Zhao, et al. Smart responsive phosphorescent materials for data recording and security protection. Nat. Commun. 2014, 5, 3601.
Google Scholar
[27]
L. Sheng,; M. J. Li,; S. Y. Zhu,; H. Li,; G. Xi,; Y. G. Li,; Y. Wang,; Q. S. Li,; S. J. Liang,; K. Zhong, et al. Hydrochromic molecular switches for water-jet rewritable paper. Nat. Commun. 2014, 5, 3044.
Google Scholar
[28]
Y. Ma,; P. F. She,; K. Y. Zhang,; H. R. Yang,; Y. Y. Qin,; Z. H. Xu,; S. J. Liu,; Q. Zhao,; W. Huang, Dynamic metal-ligand coordination for multicolour and water-jet rewritable paper. Nat. Commun. 2018, 9, 3.
Google Scholar
[29]
Z. P. Gao,; L. T. Liu,; Z. Tian,; Z. Y. Feng,; B. L. Jiang,; W. S. Wang, Fast-response flexible photochromic gels for self-erasing rewritable media and colorimetric oxygen indicator applications. ACS Appl. Mater. Interfaces 2018, 10, 33423-33433.
Google Scholar
[30]
B. X. Liu,; J. S. Wang,; J. S. Wu,; H. Y. Li,; H. Wang,; Z. F. Li,; M. L. Zhou,; T. Y. Zuo, Proton exchange growth to mesoporous WO3·0.33H2O structure with highly photochromic sensitivity. Mater. Lett. 2013, 91, 334-337.
Google Scholar
[31]
X. N. Song,; C. Y. Wang,; W. K. Wang,; X. Zhang,; N. N. Hou,; H. Q. Yu, A dissolution-regeneration route to synthesize blue tungsten oxide flowers and their applications in photocatalysis and gas sensing. Adv. Mater. Interfaces 2016, 3, 1500417.
Google Scholar
[32]
K. W. Yang,; X. Y. Chen,; Z. H. Zheng,; J. Q. Wan,; M. Feng,; Y. Yu, Solvent-induced surface disorder and doping-induced lattice distortion in anatase TiO2 nanocrystals for enhanced photoreversible color switching. J. Mater. Chem. A 2019, 7, 3863-3873.
Google Scholar
[33]
X. G. Wang,; M. H. Sun,; M. Murugananthan,; Y. R. Zhang,; L. Z. Zhang, Electrochemically self-doped WO3/TiO2 nanotubes for photocatalytic degradation of volatile organic compounds. Appl. Catal. B 2020, 260, 118205.
Google Scholar
[34]
P. H. Yang,; P. Sun,; Z. S. Chai,; L. H. Huang,; X. Cai,; S. Z. Tan,; J. H. Song,; W. J. Mai, Large-scale fabrication of pseudocapacitive glass windows that combine electrochromism and energy storage. Angew. Chem., Int. Ed. 2014, 53, 11935-11939.
Google Scholar
[35]
S. B. Wang,; L. Pan,; J. J. Song,; W. B. Mi,; J. J. Zou,; L. Wang,; X. W. Zhang, Titanium-defected undoped anatase tio2 with p-type conductivity, room-temperature ferromagnetism, and remarkable photocatalytic performance. J. Am. Chem. Soc. 2015, 137, 2975-2983.
Google Scholar
[36]
Z. J. Yao,; H. Y. Yin,; L. M. Zhou,; G. X. Pan,; Y. D. Wang,; X. H. Xia,; J. B. Wu,; X. L. Wang,; J. P. Tu, Ti3+ self-doped Li4Ti5O12 anchored on N-doped carbon nanofiber arrays for ultrafast lithium-ion storage. Small 2019, 15, 1905296.
Google Scholar
[37]
G. R. Hanson,; G. L. Wilson,; T. D. Bailey,; J. R. Pilbrow,; A. G. Wedd, Multifrequency electron spin resonance of molybdenum(V) and tungsten(V) compounds. J. Am. Chem. Soc. 1987, 109, 2609-2616.
Google Scholar
[38]
C. H. Jiang,; Y. S. Li,; S. T. Wang,; Z. T. Zhang,; Z. L. Tang, Hierarchical hydrated WO3·0.33H2O/graphene composites with improved lithium storage. Electrochim. Acta 2018, 278, 290-301.
Google Scholar
[39]
A. Tribalis,; G. D. Panagiotou,; G. Tsilomelekis,; A. G. Kalampounias,; K. Bourikas,; C. Kordulis,; S. Boghosian,; A. Lycourghiotis, Temperature-dependent evolution of the molecular configuration of oxo-tungsten(VI) species deposited on the surface of titania. J. Phys. Chem. C 2014, 118, 11319-11332.
Google Scholar
[40]
R. Fricke,; H. G. Jerschkewitz,; G. Öhlmann, Electron spin resonance studies of free and supported 12-heteropoly acids. Part 6.-The investigation of reduced H4(SiW12O40)·xH2O and Ag4(SiW12O40)·xH2O and Ag4(SiW12O40)·x H2O and the effects of oxygen adsorption. J. Chem. Soc. Faraday Trans. 1 1987, 83, 3115-3128.
Google Scholar
[41]
G. Wang,; Q. H. Chen,; Y. J. Xin,; Y. P. Liu,; Z. L. Zang,; C. G. Hu,; B. Zhang, Construction of graphene-WO3/TiO2 nanotube array photoelectrodes and its enhanced performance for photocatalytic degradation of dimethyl phthalate. Electrochim. Acta 2016, 222, 1903-1913.
Google Scholar
[42]
Y. Peng,; W. Z. Si,; X. Li,; J. M. Luo,; J. H. Li,; J. Crittenden,; J. M. Hao, Comparison of MoO3 and WO3 on arsenic poisoning V2O5/TiO2 catalyst: DRIFTS and DFT study. Appl. Catal. B 2016, 181, 692-698.
Google Scholar
[43]
Y. J. Ma,; J. X. Hu,; S. D. Han,; J. Pan,; J. H. Li,; G. M. Wang, Photochromism and photomagnetism in crystalline hybrid materials actuated by nonphotochromic units. Chem. Commun. 2019, 55, 5631-5634.
Google Scholar
[44]
Y. X. Shi,; W. H. Zhang,; B. F. Abrahams,; P. Braunstein,; J. P. Lang, Fabrication of photoactuators: Macroscopic photomechanical responses of metal-organic frameworks to irradiation by UV light. Angew. Chem., Int. Ed. 2019, 58, 9453-9458.
Google Scholar
Nano Research
Volume 14 Issue 1,
January 2021
Pages 165-171
DOI: 10.1007/s12274-020-3061-9
Cite this article:
Zhao J, Liu L, Zhang Y, et al. Light-responsive color switching of self-doped TiO2-x/WO3·0.33H2O hetero-nanoparticles for highly efficient rewritable paper. Nano Research, 2021, 14(1): 165-171. https://doi.org/10.1007/s12274-020-3061-9
Topics:
Charge transferNanoparticlesOptical propertiesOxide mineralsSynthesis (chemical)TiO2 nanoparticlesTitanium DioxideTungsten compounds

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Received: 07 July 2020
Revised: 17 August 2020
Accepted: 20 August 2020
Published: 05 January 2021
© Tsinghua University Press and Springer-Verlag GmbH Germany, part of Springer Nature
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