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Nano Research 2021, 14(1): 114-121 https://doi.org/10.1007/s12274-020-3052-x
Research Article | Issue | Published: 05 January 2021

Hybridized 1T/2H-MoS2/graphene fishnet tube for high-performance on-chip integrated micro-systems comprising supercapacitors and gas sensors

Show Author's Information Chi Zhang1,2,  Jing Ning1,2( ),  Boyu Wang1,2,  Haibin Guo1,2,  Xin Feng1,2,  Xue Shen1,2,  Yanqing Jia1,2,  Jianguo Dong1,2,  Dong Wang1,2,  Jincheng Zhang1,2( ),  Yue Hao1,2
The State Key Discipline Laboratory of Wide Band Gap Semiconductor Technology, Xidian University, Xi’an 710071, China
Shaanxi Joint Key Laboratory of Graphene, Xidian University, Xi’an 710071, China
Keywords:
gas sensor, supercapacitor, multifunctional system, integrate, 1T/2H-MoS2
Topics:
AmmoniaCalculationsChemical sensors Layered semiconductorsMolybdenum compoundsSulfur compoundsSupercapacitor
Cite this article:
Zhang C, Ning J, Wang B, et al. Hybridized 1T/2H-MoS2/graphene fishnet tube for high-performance on-chip integrated micro-systems comprising supercapacitors and gas sensors. Nano Research, 2021, 14(1): 114-121. https://doi.org/10.1007/s12274-020-3052-x
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Abstract Full text Electronic supplementary material About this article

The emerging micro-nano-processing technologies have propelled significant advances in multifunctional systems that can perform multiple functions within a small volume through integration. Herein, we present an on-chip multifunctional system based on a 1T/2H-MoS2/graphene fishnet tube, where a micro-supercapacitor and a gas sensor are integrated. A hybrid three-dimensional stereo nanostructure, including MoS2 nanosheets and graphene fishnet tubes, provides K+ ions with a short diffusion pathway and more active sites. Owing to the large layer spacing of 1T-MoS2 promoting fast reversible diffusion, the on-chip micro-supercapacitor exhibits excellent electrochemical properties, including an areal capacitance of 0.1 F·cm-2 (1 mV·s-1). The variation in the conductivity of 2H-MoS2 when ammonia molecules are adsorbed as derived from the first-principles calculations proves the Fermi level-changes theory. Driven by a micro-supercapacitor, the responsivity of the gas sensor can reach 55.7% at room temperature (27 °C). The multifunctional system demonstrates the possibility of achieving a two-dimensional integrated system for wearable devices and wireless sensor networks in the future.


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Electronic supplementary material
About this article

Hybridized 1T/2H-MoS2/graphene fishnet tube for high-performance on-chip integrated micro-systems comprising supercapacitors and gas sensors

Show Author's information Chi Zhang1,2, Jing Ning1,2( ), Boyu Wang1,2, Haibin Guo1,2, Xin Feng1,2, Xue Shen1,2, Yanqing Jia1,2, Jianguo Dong1,2, Dong Wang1,2, Jincheng Zhang1,2( ), Yue Hao1,2
The State Key Discipline Laboratory of Wide Band Gap Semiconductor Technology, Xidian University, Xi’an 710071, China
Shaanxi Joint Key Laboratory of Graphene, Xidian University, Xi’an 710071, China

Abstract

The emerging micro-nano-processing technologies have propelled significant advances in multifunctional systems that can perform multiple functions within a small volume through integration. Herein, we present an on-chip multifunctional system based on a 1T/2H-MoS2/graphene fishnet tube, where a micro-supercapacitor and a gas sensor are integrated. A hybrid three-dimensional stereo nanostructure, including MoS2 nanosheets and graphene fishnet tubes, provides K+ ions with a short diffusion pathway and more active sites. Owing to the large layer spacing of 1T-MoS2 promoting fast reversible diffusion, the on-chip micro-supercapacitor exhibits excellent electrochemical properties, including an areal capacitance of 0.1 F·cm-2 (1 mV·s-1). The variation in the conductivity of 2H-MoS2 when ammonia molecules are adsorbed as derived from the first-principles calculations proves the Fermi level-changes theory. Driven by a micro-supercapacitor, the responsivity of the gas sensor can reach 55.7% at room temperature (27 °C). The multifunctional system demonstrates the possibility of achieving a two-dimensional integrated system for wearable devices and wireless sensor networks in the future.

Keywords: gas sensor, supercapacitor, multifunctional system, integrate, 1T/2H-MoS2

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Publication history
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Acknowledgements

Publication history

Received: 30 June 2020
Revised: 09 August 2020
Accepted: 11 August 2020
Published: 05 January 2021
Issue date: January 2021

Copyright

© Tsinghua University Press and Springer-Verlag GmbH Germany, part of Springer Nature

Acknowledgements

The work was supported by the Natural Science Basic Research Plan in Shaanxi Province of China (Nos. 2017ZDCXL-GY-11-03 and 2019ZDLGY16-08); Youth Science and Technology Nova Program of Shaanxi Province; the Wuhu and Xidian University special fund for industry-university-research cooperation (No. HX01201909039).

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