AI Chat Paper
Note: Please note that the following content is generated by AMiner AI. SciOpen does not take any responsibility related to this content.
{{lang === 'zh_CN' ? '文章概述' : 'Summary'}}
{{lang === 'en_US' ? '中' : 'Eng'}}
Chat more with AI
Powered by AMiner. Clicking this button will take you away from SciOpen.
Home Nano Research Article
Article Link
Cite
EndNote(RIS) BibTeX
Collect
Submit Manuscript
Show Outline
Outline
Show full outline
Hide outline
Outline
Show full outline
Hide outline
Research Article

A hierarchical heterostructure of CdS QDs confined on 3D ZnIn2S4 with boosted charge transfer for photocatalytic CO2 reduction

Zezhou Zhu1,3,§, Xiaoxia Li2,§, Yunteng Qu1, Fangyao Zhou1, Zhiyuan Wang1, Wenyu Wang1, Changming Zhao1, Huijuan Wang4, Liqiang Li1,3, Yagang Yao3( ), Qun Zhang2( ), Yuen Wu1( )
School of Nano-Tech and Nano-Bionics, Hefei National Laboratory for Physical Sciences at the Microscale, Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), School of Chemistry and Materials Science, and National Synchrotron Radiation Laboratory, University of Science and Technology of China, Hefei 230026, China
Hefei National Laboratory for Physical Sciences at the Microscale, Synergetic Innovation Center of Quantum Information and Quantum Physics, Department of Chemical Physics, University of Science and Technology of China, Hefei 230026, China
Division of Advanced Nanomaterials, Suzhou Institute of Nano-tech and Nano-bionics, Chinese Academy of Sciences, Suzhou 215123, China
Center for Micro and Nanoscale Research and Fabrication, University of Science and Technology of China, Hefei 230026, China

§ Zezhou Zhu and Xiaoxia Li contributed equally to this work.

Show Author Information

Graphical Abstract

Abstract

Metal sulfide based materials as photocatalysts for energy conversion are essential to produce value-added chemical fuels, but their intrinsically slow carrier dynamics and low activity are yet to be resolved. Herein, we developed a unique heterogeneously nanostructured ZnIn2S4-CdS heterostructure that involves zero-dimensional (0D) CdS quantum dots uniformly confined on three-dimensional (3D) ZnIn2S4 nanoflowers, which achieves an excellent catalytic performance of CO2 photoconversion under visible-light irradiation. The obtained hierarchical heterostructure can significantly enhance the light harvesting, shorten the migration distance of carriers, and obviously accelerate the transport of electrons. As evidenced by the ultrafast transient absorption spectroscopy, the formed interface can effectively facilitate charge separation and transport. This work opens up a new avenue to carefully design the elaborate heterostructures for achieving optimal charge separation efficiency by lowering interfacial kinetic barriers and energy losses at the interface.

Keywords

charge transferphotocatalysisCO2 reductionhierarchical heterostructure

Electronic Supplementary Material

Download File(s)
12274_2020_3045_MOESM1_ESM.pdf (5.8 MB)

References

[1]
X. Li,; J. G. Yu,; M. Jaroniec,; X. B. Chen, Cocatalysts for selective photoreduction of CO2 into solar fuels. Chem. Rev. 2019, 119, 3962-4179.
Google Scholar
[2]
P. Zhang,; X. W. Lou, Design of heterostructured hollow photocatalysts for solar-to-chemical energy conversion. Adv. Mater. 2019, 31, 1900281.
Google Scholar
[3]
J. W. Fu,; K. X. Jiang,; X. Q. Qiu,; J. G. Yu,; M. Liu, Product selectivity of photocatalytic CO2 reduction reactions. Mater. Today 2020, 32, 222-243.
Google Scholar
[4]
J. J. Shan,; F. Raziq,; M. Humayun,; W. Zhou,; Y. Qu,; G. F. Wang,; Y. D. Li, Improved charge separation and surface activation via boron-doped layered polyhedron SrTiO3 for co-catalyst free photocatalytic CO2 conversion. Appl. Catal. B: Environ. 2017, 219, 10-17.
Google Scholar
[5]
N. Nie,; L. Y. Zhang,; J. W. Fu,; B. Cheng,; J. G. Yu, Self-assembled hierarchical direct Z-scheme g-C3N4/ZnO microspheres with enhanced photocatalytic CO2 reduction performance. Appl. Surf. Sci. 2018, 441, 12-22.
Google Scholar
[6]
Q. Li,; S. C. Wang,; Z. X. Sun,; Q. J. Tang,; Y. Q. Liu,; L. Z. Wang,; H. Q. Wang,; Z. B. Wu, Enhanced CH4 selectivity in CO2 photocatalytic reduction over carbon quantum dots decorated and oxygen doping g-C3N4. Nano Res. 2019, 12, 2749-2759.
Google Scholar
[7]
N. N. Vu,; S. Kaliaguine,; T. O. Do, Critical aspects and recent advances in structural engineering of photocatalysts for sunlight-driven photocatalytic reduction of CO2 into fuels. Adv. Funct. Mater. 2019, 29, 1901825.
Google Scholar
[8]
S. F. Ji,; Y. Qu,; T. Wang,; Y. J. Chen,; G. F. Wang,; X. Li,; C. J. Dong,; Q. Y. Chen,; W. Y. Zhang,; Z. D. Zhang, et al. Rare-earth single erbium atoms for enhanced photocatalytic CO2 reduction. Angew. Chem., Int. Ed. 2020, 59, 10651-10657.
Google Scholar
[9]
J. Bian,; J. N. Feng,; Z. Q. Zhang,; Z. J. Li,; Y. H. Zhang,; Y. D. Liu,; S. Ali,; Y. Qu,; L. L. Bai,; J. J. Xie, et al. Dimension-matched zinc phthalocyanine/BiVO4 ultrathin nanocomposites for CO2 reduction as efficient wide-visible-light-driven photocatalysts via a cascade charge transfer. Agnew. Chem., Int. Ed. 2019, 58, 10873-10878.
Google Scholar
[10]
Y. J. Ma,; Q. Tang,; W. Y. Sun,; Z. Y. Yao,; W. H. Zhu,; T. Li,; J. Y. Wang, Assembling ultrafine TiO2 nanoparticles on UiO-66 octahedrons to promote selective photocatalytic conversion of CO2 to CH4 at a low concentration. Appl. Catal. B: Environ. 2020, 270, 118856.
Google Scholar
[11]
M. Tahir,; B. Tahir,; N. A. S. Amin,; Z. Y. Zakaria, Photo-induced reduction of CO2 to CO with hydrogen over plasmonic Ag-NPs/ TiO2 NWs core/shell hetero-junction under UV and visible light. J. CO2 Util. 2017, 18, 250-260.
Google Scholar
[12]
S. Y. Zhu,; W. R. Liao,; M. Y. Zhang,; S. J. Liang, Design of spatially separated Au and CoO dual cocatalysts on hollow TiO2 for enhanced photocatalytic activity towards the reduction of CO2 to CH4. Chem. Eng. J. 2019, 361, 461-469.
Google Scholar
[13]
Z. Z. Lou,; P. Zhang,; J. Li,; X. G. Yang,; B. B. Huang,; B. J. Li, Plasmonic heterostructure TiO2-MCs/WO3-x-NWs with continuous photoelectron injection boosting hot electron for methane generation. Adv. Funct. Mater. 2019, 29, 1808696.
Google Scholar
[14]
Q. Q. Bi,; J. W. Wang,; J. X. Lv,; J. Wang,; W. Zhang,; T. B. Lu, Selective photocatalytic CO2 reduction in water by electrostatic assembly of CdS nanocrystals with a dinuclear cobalt catalyst. ACS Catal. 2018, 8, 11815-11821.
Google Scholar
[15]
Z. Z. Zhu,; Y. Han,; C. P. Chen,; Z. X. Ding,; J. L. Long,; Y. D. Hou, Reduced graphene oxide-cadmium sulfide nanorods decorated with silver nanoparticles for efficient photocatalytic reduction carbon dioxide under visible light. ChemCatChem 2018, 10, 1627-1634.
Google Scholar
[16]
Y. L. Men,; Y. You,; Y. X. Pan,; H. C. Gao,; Y. Xia,; D. G. Cheng,; J. Song,; D. X. Cui,; N. Wu,; Y. T. Li, et al. Selective CO evolution from photoreduction of CO2 on a metal-carbide-based composite catalyst. J. Am. Chem. Soc. 2018, 140, 13071-13077.
Google Scholar
[17]
H. Y. Wang,; R. Hu,; Y. J. Lei,; Z. Y. Jia,; G. L. Hu,; C. B. Li,; Q. Gu, Highly efficient and selective photocatalytic CO2 reduction based on water-soluble CdS QDs modified by the mixed ligands in one pot. Catal. Sci. Technol. 2020, 10, 2821-2829.
Google Scholar
[18]
J. N. Qin,; S. B. Wang,; H. Ren,; Y. D. Hou,; X. C. Wang, Photocatalytic reduction of CO2 by graphitic carbon nitride polymers derived from urea and barbituric acid. Appl. Catal. B: Environ. 2015, 179, 1-8.
Google Scholar
[19]
J. G. Yu,; K. Wang,; W. Xiao,; B. Cheng, Photocatalytic reduction of CO2 into hydrocarbon solar fuels over g-C3N4-Pt nanocomposite photocatalysts. Phys. Chem. Chem. Phys. 2014, 16, 11492-11501.
Google Scholar
[20]
S. F. Tian,; S. D. Chen,; X. T. Ren,; Y. Q. Hu,; H. Y. Hu,; J. J. Sun,; F. Bai, An efficient visible-light photocatalyst for CO2 reduction fabricated by cobalt porphyrin and graphitic carbon nitride via covalent bonding. Nano Res. 2020, 13, 2665-2672.
Google Scholar
[21]
S. N. Talapaneni,; G. Singh,; I. Y. Kim,; K. AlBahily,; A. H. Al-Muhtaseb,; A. S. Karakoti,; E. Tavakkoli,; A. Vinu, Nanostructured carbon nitrides for CO2 capture and conversion. Adv. Mater. 2020, 32, 1904635.
Google Scholar
[22]
J. X. Shen,; Y. Z. Li,; H. Y. Zhao,; K. Pan,; X. Li,; Y. Qu,; G. F. Wang,; D. S. Wang, Modulating the photoelectrons of g-C3N4 via coupling MgTi2O5 as appropriate platform for visible-light-driven photocatalytic solar energy conversion. Nano Res. 2019, 12, 1931-1936.
Google Scholar
[23]
Y. D. Hou,; A. B. Laursen,; J. S. Zhang,; G. G. Zhang,; Y. S. Zhu,; X. C. Wang,; S. Dahl,; I. Chorkendorff, Layered nanojunctions for hydrogen-evolution catalysis. Angew. Chem., Int. Ed. 2013, 52, 3621-3625.
Google Scholar
[24]
B. Xu,; P. L. He,; H. L. Liu,; P. P. Wang,; G. Zhou,; X. Wang, A 1D/2D helical CdS/ZnIn2S4 nano-heterostructure. Agnew. Chem., Int. Ed. 2014, 53, 2339-2343.
Google Scholar
[25]
H. F. Lin,; Y. Y. Li,; H. L. Li,; X. Wang, Multi-node CdS hetero-nanowires grown with defect-rich oxygen-doped MoS2 ultrathin nanosheets for efficient visible-light photocatalytic H2 evolution. Nano Res. 2017, 10, 1377-1392.
Google Scholar
[26]
X. D. Wang,; Y. H. Huang,; J. F. Liao,; Y. Jiang,; L. Zhou,; X. Y. Zhang,; H. Y. Chen,; D. B. Kuang, In situ construction of a Cs2SnI6 perovskite nanocrystal/SnS2 nanosheet heterojunction with boosted interfacial charge transfer. J. Am. Chem. Soc. 2019, 141, 13434-13441.
Google Scholar
[27]
S. F. Tang,; X. P. Yin,; G. Y. Wang,; X. L. Lu,; T. B. Lu, Single titanium-oxide species implanted in 2D g-C3N4 matrix as a highly efficient visible-light CO2 reduction photocatalyst. Nano Res. 2019, 12, 457-462.
Google Scholar
[28]
S. B. Wang,; Y. Wang,; S. Q. Zang,; X. W. Lou, Hierarchical hollow heterostructures for photocatalytic CO2 reduction and water splitting. Small Methods 2020, 4, 1900586.
Google Scholar
[29]
S. W. Cao,; B. J. Shen,; T. Tong,; J. W. Fu,; J. G. Yu, 2D/2D heterojunction of ultrathin MXene/Bi2WO6 nanosheets for improved photocatalytic CO2 reduction. Adv. Funct. Mater. 2018, 28, 1800136.
Google Scholar
[30]
H. Wang,; X. D. Zhang,; Y. Xie, Recent progress in ultrathin two-dimensional semiconductors for photocatalysis. Mater. Sci. Eng. R: Rep. 2018, 130, 1-39.
Google Scholar
[31]
X. C. Jiao,; Z. W. Chen,; X. D. Li,; Y. F. Sun,; S. Gao,; W. S. Yan,; C. M. Wang,; Q. Zhang,; Y. Lin,; Y. Luo, et al. Defect-mediated electron-hole separation in one-unit-cell ZnIn2S4 layers for boosted solar-driven CO2 reduction. J. Am. Chem. Soc. 2017, 139, 7586-7594.
Google Scholar
[32]
X. Wang,; J. Lv,; J. X. Zhang,; X. L. Wang,; C. Z. Xue,; G. Q. Bian,; D. S. Li,; Y. Wang,; T. Wu, Hierarchical heterostructure of SnO2 confined on CuS nanosheets for efficient electrocatalytic CO2 reduction. Nanoscale 2020, 12, 772-784.
Google Scholar
[33]
Z. L. Xu,; C. S. Zhuang,; Z. J. Zou,; J. Y. Wang,; X. C. Xu,; T. Y. Peng, Enhanced photocatalytic activity by the construction of a TiO2/carbon nitride nanosheets heterostructure with high surface area via direct interfacial assembly. Nano Res. 2017, 10, 2193-2209.
Google Scholar
[34]
J. Xiong,; P. Song,; J. Di,; H. M. Li, Ultrathin structured photocatalysts: A versatile platform for CO2 reduction. Appl. Catal. B: Environ. 2019, 256, 117788.
Google Scholar
[35]
A. Li,; T. Wang,; C. C. Li,; Z. Q. Huang,; Z. B. Luo,; J. L. Gong, Adjusting the reduction potential of electrons by quantum confinement for selective photoreduction of CO2 to methanol. Agnew. Chem., Int. Ed. 2019, 58, 3804-3808.
Google Scholar
[36]
M. Q. Yang,; Y. J. Xu,; W. H. Lu,; K. Y. Zeng,; H. Zhu,; Q. H. Xu,; G. W. Ho, Self-surface charge exfoliation and electrostatically coordinated 2D hetero-layered hybrids. Nat. Commun. 2017, 8, 14224.
Google Scholar
[37]
T. Wang,; Y. Y. Chai,; D. K. Ma,; W. Chen,; W. W. Zheng,; S. M. Huang, Multidimensional CdS nanowire/CdIn2S4 nanosheet heterostructure for photocatalytic and photoelectrochemical applications. Nano Res. 2017, 10, 2699-2711.
Google Scholar
[38]
H. Y. Li,; X. Z. Liu,; S. M. Chen,; D. R. Yang,; Q. Zhang,; L. Song,; H. Xiao,; Q. H. Zhang,; L. Gu,; X. Wang, Edge-exposed molybdenum disulfide with N-doped carbon hybridization: A hierarchical hollow electrocatalyst for carbon dioxide reduction. Adv. Energy Mater. 2019, 9, 1900072.
Google Scholar
[39]
S. B. Wang,; B. Y. Guan,; X. W. Lou, Construction of ZnIn2S4-In2O3 hierarchical tubular heterostructures for efficient CO2 photoreduction. J. Am. Chem. Soc. 2018, 140, 5037-5040.
Google Scholar
[40]
Y. Q. He,; H. Rao,; K. P. Song,; J. X. Li,; Y. Yu,; Y. Lou,; C. G. Li,; Y. Han,; Z. Shi,; S. H. Feng, 3D hierarchical ZnIn2S4 nanosheets with rich Zn vacancies boosting photocatalytic CO2 reduction. Adv. Funct. Mater. 2019, 29, 1905153.
Google Scholar
[41]
Y. Xia,; B. Cheng,; J. J. Fan,; J. G. Yu,; G. Liu, Near-infrared absorbing 2D/3D ZnIn2S4/N-doped graphene photocatalyst for highly efficient CO2 capture and photocatalytic reduction. Sci. China Mater. 2020, 63, 552-565.
Google Scholar
[42]
M. Zhou,; S. B. Wang,; P. J. Yang,; C. J. Huang,; X. C. Wang, Boron carbon nitride semiconductors decorated with CdS nanoparticles for photocatalytic reduction of CO2. ACS Catal. 2018, 8, 4928-4936.
Google Scholar
[43]
A. H. Yan,; X. W. Shi,; F. Huang,; M. Fujitsuka,; T. Majima, Efficient photocatalytic H2 evolution using NiS/ZnIn2S4 heterostructures with enhanced charge separation and interfacial charge transfer. Appl. Catal. B: Environ. 2019, 250, 163-170.
Google Scholar
[44]
H. Li,; W. J. Li,; W. Li,; M. F. Chen,; R. Snyders,; C. Bittencourt,; Z. H. Yuan, Engineering crystal phase of polytypic CuInS2 nanosheets for enhanced photocatalytic and photoelectrochemical performance. Nano Res. 2020, 13, 583-590.
Google Scholar
[45]
S. B. Wang,; B. Y. Guan,; Y. Lu,; X. W. Lou, Formation of hierarchical In2S3-CdIn2S4 heterostructured nanotubes for efficient and stable visible light CO2 reduction. J. Am. Chem. Soc. 2017, 139, 17305-17308.
Google Scholar
[46]
H. Q. Xu,; S. Z. Yang,; X. Ma,; J. E. Huang,; H. L. Jiang, Unveiling charge-separation dynamics in CdS/metal-organic framework composites for enhanced photocatalysis. ACS Catal. 2018, 8, 11615-11621.
Google Scholar
[47]
S. Q. Zhang,; X. Liu,; C. B. Liu,; S. L. Luo,; L. L. Wang,; T. Cai,; Y. X. Zeng,; J. L. Yuan,; W. Y. Dong,; Y. Pei, et al. MoS2 quantum dot growth induced by S vacancies in a ZnIn2S4 monolayer: Atomic-level heterostructure for photocatalytic hydrogen production. ACS Nano 2018, 12, 751-758.
Google Scholar
[48]
J. Wang,; T. Xia,; L. Wang,; X. S. Zheng,; Z. M. Qi,; C. Gao,; J. F. Zhu,; Z. Q. Li,; H. X. Xu,; Y. J. Xiong, Enabling visible-light-driven selective CO2 reduction by doping quantum dots: Trapping electrons and suppressing H2 evolution. Angew. Chem., Int. Ed. 2018, 57, 16447-16451.
Google Scholar
[49]
M. Zhou,; S. B. Wang,; P. J. Yang,; Z. S. Luo,; R. S. Yuan,; A. M. Asiri,; M. Wakeel,; X. C. Wang, Layered heterostructures of ultrathin polymeric carbon nitride and ZnIn2S4 nanosheets for photocatalytic CO2 reduction. Chem. —Eur. J. 2018, 24, 18529-18534.
Google Scholar
[50]
L. Ye,; Z. H. Li, Rapid microwave-assisted syntheses of reduced graphene oxide (RGO)/ZnIn2S4 microspheres as superior noble-metal-free photocatalyst for hydrogen evolutions under visible light. Appl. Catal. B: Environ. 2014, 160-161, 552-557.
Google Scholar
[51]
Y. Wu,; H. Wang,; W. G. Tu,; S. Y. Wu,; J. W. Chew, Effects of composition faults in ternary metal chalcogenides (ZnxIn2S3+x, x = 1-5) layered crystals for visible-light-driven catalytic hydrogen generation and carbon dioxide reduction. Appl. Catal. B: Environ. 2019, 256, 117810.
Google Scholar
[52]
Y. G. Chao,; P. Zhou,; N. Li,; J. P. Lai,; Y. Yang,; Y. L. Zhang,; Y. H. Tang,; W. X. Yang,; Y. P. Du,; D. Su, et al. Ultrathin visible-light-driven Mo incorporating In2O3-ZnIn2Se4 Z-scheme nanosheet photocatalysts. Adv. Mater. 2019, 31, 1807226.
Google Scholar
[53]
D. N. Liu,; D. Y. Chen,; N. J. Li,; Q. F. Xu,; H. Li,; J. H. He,; J. M. Lu, Surface engineering of g-C3N4 by stacked BiOBr sheets rich in oxygen vacancies for boosting photocatalytic performance. Angew. Chem., Int. Ed. 2020, 59, 4519-4524.
Google Scholar
[54]
L. Q. Shao,; D. L. Jiang,; P. Xiao,; L. M. Zhu,; S. C. Meng,; M. Chen, Enhancement of g-C3N4 nanosheets photocatalysis by synergistic interaction of ZnS microsphere and RGO inducing multistep charge transfer. Appl. Catal. B: Environ. 2016, 198, 200-210.
Google Scholar
[55]
M. Xiao,; Z. L. Wang,; M. Q. Lyu,; B. Luo,; S. C. Wang,; G. Liu,; H. M. Cheng,; L. Z. Wang, Hollow nanostructures for photocatalysis: Advantages and challenges. Adv. Mater. 2019, 31, 1801369.
Google Scholar
[56]
Y. Z. Wei,; J. Y. Wang,; R. B. Yu,; J. W. Wan,; D. Wang, Constructing SrTiO3-TiO2 heterogeneous hollow multi-shelled structures for enhanced solar water splitting. Angew. Chem., Int. Ed. 2019, 58, 1422-1426.
Google Scholar
[57]
Y. K. Zhu,; C, X. Lv,; Z. C. Yin,; J. Ren,; X. F. Yang,; C. L. Dong,; H. W. Liu,; R. S. Cai,; Y. C. Huang,; W. Theis, et al. A [001]-oriented Hittorf’s phosphorus nanorods/polymeric carbon nitride heterostructure for boosting wide-spectrum-responsive photocatalytic hydrogen evolution from pure water. Angew. Chem., Int. Ed. 2020, 59, 868-873.
Google Scholar
[58]
P. Zhang,; S. B. Wang,; B. Y. Guan,; X. W. Lou, Fabrication of CdS hierarchical multi-cavity hollow particles for efficient visible light CO2 reduction. Energy Environ. Sci. 2019, 12, 164-168.
Google Scholar
[59]
H. T. Li,; X. Y. Zhang,; D. R. MacFarlane, Carbon quantum dots/ Cu2O heterostructures for solar-light-driven conversion of CO2 to methanol. Adv. Energy Mater. 2015, 5, 1401077.
Google Scholar
[60]
Z. P. Zeng,; Y. B. Yan,; J. Chen,; P. Zan,; Q. H. Tian,; P. Chen, Boosting the photocatalytic ability of Cu2O nanowires for CO2 conversion by MXene quantum dots. Adv. Funct. Mater. 2019, 29, 1806500.
Google Scholar
[61]
Z. Z. Zhu,; J. N. Qin,; M. Jiang,; Z. X. Ding,; Y. D. Hou, Enhanced selective photocatalytic CO2 reduction into CO over Ag/CdS nanocomposites under visible light. Appl. Surf. Sci. 2017, 391, 572-579.
Google Scholar
[62]
X. X. Chang,; T. Wang,; P. Zhang,; J. J. Zhang,; A. Li,; J. L. Gong, Enhanced surface reaction kinetics and charge separation of p-n heterojunction Co3O4/BiVO4 photoanodes. J. Am. Chem. Soc. 2015, 137, 8356-8359.
Google Scholar
[63]
Y. Z. Wei,; J. W. Wan,; N. L. Yang,; Y. Yang,; Y. W. Ma,; S. C. Wang,; J. Y. Wang,; R. B. Yu,; L. Gu, L. H. Wang, et al. Efficient sequential harvesting of solar light by heterogeneous hollow shells with hierarchical pores. Natl. Sci. Rev., in press, .
Crossref Google Scholar
[64]
F. C. Lei,; L. Zhang,; Y. F. Sun,; L. Liang,; K. T. Liu,; J. Q. Xu,; Q. Zhang,; B. C. Pan,; Y. Lu,; Y. Xie, Atomic-layer-confined doping for atomic-level insights into visible-light water splitting. Angew. Chem., Int. Ed. 2015, 54, 9266-9270.
Google Scholar
[65]
W. L. Yang,; L. Zhang,; J. F. Xie,; X. D. Zhang,; Q. H. Liu,; T. Yao,; S. Q. Wei,; Q. Zhang,; Y. Xie, Enhanced photoexcited carrier separation in oxygen-doped ZnIn2S4 nanosheets for hydrogen evolution. Angew. Chem., Int. Ed. 2016, 55, 6716-6720.
Google Scholar
[66]
W. Shao,; L. Wang,; H. Wang,; Z. Zhao,; X. D. Zhang,; S. L. Jiang,; S. C. Chen,; X. S. Sun,; Q. Zhang,; Y. Xie, Efficient exciton dissociation in heterojunction interfaces realizing enhanced photoresponsive performance. J. Phys. Chem. Lett. 2019, 10, 2904-2910.
Google Scholar
[67]
X. Deng,; R. Li,; S. K. Wu,; L. Wang,; J. H. Hu,; J. Ma,; W. B. Jiang,; N. Zhang, X. S. Zheng,; C. Gao, et al. Metal-organic framework coating enhances the performance of Cu2O in photoelectrochemical CO2 reduction. J. Am. Chem. Soc. 2019, 141, 10924-10929.
Google Scholar
[68]
J. L. Lin,; Y. D. Hou,; Y. Zheng,; X. C. Wang Integration of [(Co(bpy)3]2+ electron mediator with heterogeneous photocatalysts for CO2 conversion. Chem. Asian J. 2014, 9, 2468-2474.
Google Scholar
[69]
L. J. Huang,; B. F. Li,; B. Su,; Z. Xiong,; C. J. Zhang,; Y. D. Hou,; Z. X. Ding,; S. B. Wang, Fabrication of hierarchical Co3O4@CdIn2S4 p-n heterojunction photocatalysts for improved CO2 reduction with visible light. J. Mater. Chem. A 2020, 8, 7177-7183.
Google Scholar
[70]
G. X. Zhao,; W. Zhou,; Y. B. Sun,; X. K. Wang,; H. M. Liu,; X. G. Meng,; K. Chang,; J. H. Ye Efficient photocatalytic CO2 reduction over Co(II) species modified CdS in aqueous solution. Appl. Catal. B: Envirmon. 2018, 226, 252-257.
Google Scholar
[71]
B. Su,; L. J. Huang,; Z. Xiong,; Y. C. Yang,; Y. D. Hou,; Z. X. Ding,; S. B. Wang, Branch-like ZnS-DETA/CdS hierarchical heterostructures as an efficient photocatalyst for visible light CO2 reduction. J. Mater. Chem. A 2019, 7, 26877-26883.
Google Scholar
Nano Research
Volume 14 Issue 1,
January 2021
Pages 81-90
DOI: 10.1007/s12274-020-3045-9
Cite this article:
Zhu Z, Li X, Qu Y, et al. A hierarchical heterostructure of CdS QDs confined on 3D ZnIn2S4 with boosted charge transfer for photocatalytic CO2 reduction. Nano Research, 2021, 14(1): 81-90. https://doi.org/10.1007/s12274-020-3045-9
Topics:
Cadmium sulfideCarbon dioxideCharge transferIIIndium compoundsLightPhotocatalystsSemiconductor quantum dotsSulfur compoundsVI semiconductorsZinc compounds

899

Views

92

Crossref

0

Web of Science

92

Scopus

11

CSCD

Altmetrics
Received: 09 July 2020
Revised: 03 August 2020
Accepted: 07 August 2020
Published: 05 January 2021
© Tsinghua University Press and Springer-Verlag GmbH Germany, part of Springer Nature
Return