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02 September 2020
Plasmon-generated hot holes for chemical reactions
Gang Lu(
)
)
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Zhang C, Jia F, Li Z, et al.
Plasmon-generated hot holes for chemical reactions.
Nano Research,
2020, 13(12): 3183-3197.
https://doi.org/10.1007/s12274-020-3031-2
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Plasmonic nanostructures have been widely used for photochemical conversions due to their unique and easy-tuning optical properties in visible and near-infrared range. Compared with the plasmon-generated hot electrons, the hot holes usually have a shorter lifetime, which makes them more difficult to drive redox reactions. This review focuses on the photochemistry driven by the plasmon-generated hot holes. First, we discuss the generation and energy distribution of the plasmon-generated hot carriers, especially hot holes. Then, the dynamics of the hot holes are discussed at the interface between plasmonic metal and semiconductor or adsorbed molecules. Afterwards, the utilization of these hot holes in redox reactions is reviewed on the plasmon-semiconductor heterostructures as well as on the surface of the molecule-adsorbed plasmonic metals. Finally, the remaining challenges and future perspectives in this field are presented. This review will be helpful for further improving the efficiency of the photochemical reactions involving the plasmon-generated hot holes and expanding the applications of these hot holes in varieties of chemical reactions, especially the ones with high conversion rate and selectivity.
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Plasmon-generated hot holes for chemical reactions
Gang Lu(
)
)
Abstract
Plasmonic nanostructures have been widely used for photochemical conversions due to their unique and easy-tuning optical properties in visible and near-infrared range. Compared with the plasmon-generated hot electrons, the hot holes usually have a shorter lifetime, which makes them more difficult to drive redox reactions. This review focuses on the photochemistry driven by the plasmon-generated hot holes. First, we discuss the generation and energy distribution of the plasmon-generated hot carriers, especially hot holes. Then, the dynamics of the hot holes are discussed at the interface between plasmonic metal and semiconductor or adsorbed molecules. Afterwards, the utilization of these hot holes in redox reactions is reviewed on the plasmon-semiconductor heterostructures as well as on the surface of the molecule-adsorbed plasmonic metals. Finally, the remaining challenges and future perspectives in this field are presented. This review will be helpful for further improving the efficiency of the photochemical reactions involving the plasmon-generated hot holes and expanding the applications of these hot holes in varieties of chemical reactions, especially the ones with high conversion rate and selectivity.
Keywords:
photocatalysis, photochemistry, surface plasmon, hot hole
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Publication history
Copyright
Acknowledgements
Publication history
Received: 08 June 2020
Revised: 27 July 2020
Accepted: 04 August 2020
Published:
02 September 2020
Issue date: December 2020
Copyright
© Tsinghua University Press and Springer-Verlag GmbH Germany, part of Springer Nature
Acknowledgements
This work was supported by the National Natural Science Foundation of China (No. 11974180), Key University Science Research Project of Jiangsu Province (No. 17KJA150005), Six Talent Peaks Project in Jiangsu Province (No. XCL-038) and Postgraduate Research & Practice Innovation Program of Jiangsu Province (No. KYCX20_1060).
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