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Research Article

Ultra-stable K metal anode enabled by oxygen-rich carbon cloth

Yangyang Xie1, Junxian Hu1, Zexun Han1, Hailin Fan2, Jingyu Xu1, Yanqing Lai1, Zhian Zhang1( )
School of Metallurgy and Environment, Central South University, Changsha 410083, China
Contemporary Amperex Technology Co., Ltd., Ningde 352100, China
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Abstract

The K metal batteries are emerged as promising alternatives beyond commercialized Li-ion batteries. However, suppressing uncontrolled dendrite is crucial to the accomplishment of K metal batteries. Herein, an oxygen-rich treated carbon cloth (TCC) has been designed as the K plating host to guide K homogeneous nucleation and suppress the dendrite growth. Both density function theory calculations and experimental results demonstrate that abundant oxygen functional groups as K-philic sites on TCC can guide K nucleation and deposition homogeneously. As a result, the TCC electrode exhibits an ultra-long-life over 800 cycles at high current density of 3.0 mA·cm-2 for 3.0 mA·h·cm-2. Furthermore, the symmetrical cells can run stably for 2,000 h with low over-potential less than 20 mV at 1.0 mA·cm-2 for 1.0 mA·h·cm-2. Even at a higher current of 5.0 mA·cm-2, the TCC electrode can still stably cycle for 1,400 h.

Keywords

K metal anodedendriteoxygen-rich treated carbon clothK-philic sitesultra-long-life

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Nano Research
Volume 13 Issue 11,
November 2020
Pages 3137-3141
DOI: 10.1007/s12274-020-2984-5
Cite this article:
Xie Y, Hu J, Han Z, et al. Ultra-stable K metal anode enabled by oxygen-rich carbon cloth. Nano Research, 2020, 13(11): 3137-3141. https://doi.org/10.1007/s12274-020-2984-5
Topics:
CarbonDensity functional theoryElectrodesIon batteriesLithiumOxygen

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Received: 14 May 2020
Revised: 02 July 2020
Accepted: 10 July 2020
Published: 25 August 2020
© Tsinghua University Press and Springer-Verlag GmbH Germany, part of Springer Nature 2020
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