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Research Article

Plasmonic coupling-enhanced in situ photothermal nanoreactor with shape selective catalysis for C-C coupling reaction

Zhenxing Li1( ), Yixuan Gong1, Xin Zhang1, Yangyang Wen1, Jiasai Yao1, Mingliang Hu1, Miao He1, Jiahao Liu1, Rui Li1, Fuqiang Wang2, Chuanxin Zhang2( )
Key Laboratory of Heavy Oil Processing, College of New Energy and Materials, Beijing Key Laboratory of Biogas Upgrading Utilization, China University of Petroleum (Beijing), Beijing 102249, China
School of New Energy, Harbin Institute of Technology at Weihai, 2 West Wenhua Road, Weihai 264209, China
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Abstract

Carbon-carbon (C-C) coupling reactions represent one of the most powerful tools for the synthesis of complex natural products, bioactive molecules developed as drugs and agrochemicals. In this work, a multifunctional nanoreactor for C-C coupling reaction was successfully fabricated via encapsulating the core-shell Cu@Ni nanocubes into ZIF-8 (Cu@Ni@ZIF-8). In this nanoreactor, Ni shell of the core-shell Cu@Ni nanocubes was the catalytical active center, and Cu core was in situ heating source for the catalyst by absorbing the visible light. Moreover, benefiting from the plasmonic resonance effect between Cu@Ni nanocubes encapsulated in ZIF-8, the absorption range of nanoreactor was widened and the utilization rate of visible light was enhanced. Most importantly, the microporous structure of ZIF-8 provided shape-selective of reactant. This composite was used for the highly shape-selective and stable photocatalysed C-C coupling reaction of boric acid under visible light irradiation. After five cycles, the nanoreactor still remained high catalytical activity. This Cu@Ni@ZIF-8 nanoreactor opens a way for photocatalytic C-C coupling reactions with shape-selectivity.

Keywords

photocatalysismetal-organic frameworknanoreactorshape selective catalysisC-C coupling reaction

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Nano Research
Volume 13 Issue 10,
October 2020
Pages 2812-2818
DOI: 10.1007/s12274-020-2933-3
Cite this article:
Li Z, Gong Y, Zhang X, et al. Plasmonic coupling-enhanced in situ photothermal nanoreactor with shape selective catalysis for C-C coupling reaction. Nano Research, 2020, 13(10): 2812-2818. https://doi.org/10.1007/s12274-020-2933-3
Topics:
Boric acidCarbonCatalysis LightNickel compoundsPlasmonics Shells (structures)Synthesis (chemical)

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Received: 09 April 2020
Revised: 19 May 2020
Accepted: 13 June 2020
Published: 05 October 2020
© Tsinghua University Press and Springer-Verlag GmbH Germany, part of Springer Nature 2020
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