[1]
Vitousek, P. M.; Mooney, H. A.; Lubchenco, J.; Melillo, J. M. Human domination of earth’s ecosystems. Science 1997, 277, 494-499.
[2]
Wang, W. H.; Himeda, Y.; Muckerman, J. T.; Manbeck, G. F.; Fujita, E. CO2 Hydrogenation to formate and methanol as an alternative to photo- and electrochemical CO2 reduction. Chem. Rev. 2015, 115, 12936-12973.
[3]
Lee, J. H.; Kattel, S.; Jiang, Z.; Xie, Z. H.; Yao, S. Y.; Tackett, B. M.; Xu, W. Q.; Marinkovic, N. S.; Chen, J. G. Tuning the activity and selectivity of electroreduction of CO2 to synthesis gas using bimetallic catalysts. Nat. Commun. 2019, 10, 3724.
[4]
Turner, J. A. A realizable renewable energy future. Science 1999, 285, 687-689.
[5]
Chu, S.; Cui, Y.; Liu, N. The path towards sustainable energy. Nat. Mater. 2017, 16, 16-22.
[6]
Li, F. W.; Thevenon, A.; Rosas-Hernández, A.; Wang, Z. Y.; Li, Y. L.; Gabardo, C. M.; Ozden, A.; Dinh, C. T.; Li, J.; Wang, Y. H. et al. Molecular tuning of CO2-to-ethylene conversion. Nature 2020, 577, 509-513.
[7]
Zhu, D. D.; Liu, J. L.; Qiao, S. Z. Recent advances in inorganic heterogeneous electrocatalysts for reduction of carbon dioxide. Adv. Mater. 2016, 28, 3423-3452.
[8]
Vasileff, A.; Xu, C. C.; Jiao, Y.; Zheng, Y.; Qiao, S. Z. Surface and interface engineering in copper-based bimetallic materials for selective CO2 electroreduction. Chem 2018, 4, 1809-1831.
[9]
Li, F. W.; MacFarlane, D. R.; Zhang, J. Recent advances in the nanoengineering of electrocatalysts for CO2 reduction. Nanoscale 2018, 10, 6235-6260.
[10]
Ju, W.; Bagger, A.; Hao, G. P.; Varela, A. S.; Sinev, I.; Bon, V.; Cuenya, B. R.; Kaskel, S.; Rossmeisl, J.; Strasser, P. Understanding activity and selectivity of metal-nitrogen-doped carbon catalysts for electrochemical reduction of CO2. Nat. Commun. 2017, 8, 944.
[11]
Li, C. H.; Tong, X.; Yu, P.; Du, W.; Wu, J.; Rao, H.; Wang, Z. M. Carbon dioxide photo/electroreduction with cobalt. J. Mater. Chem. A 2019, 7, 16622-16642.
[12]
Varela, A. S.; Sahraie, N. R.; Steinberg, J.; Ju, W.; Oh, H. S.; Strasser, P. Metal-doped nitrogenated carbon as an efficient catalyst for direct CO2 electroreduction to CO and hydrocarbons. Angew. Chem., Int. Ed. 2015, 54, 10758-10762.
[13]
Hu, X. M.; Hval, H. H.; Bjerglund, E. T.; Dalgaard, K. J.; Madsen, M. R.; Pohl, M. M.; Welter, E.; Lamagni, P.; Buhl, K. B.; Bremholm, M. et al. Selective CO2 reduction to CO in water using earth- abundant metal and nitrogen-doped carbon electrocatalysts. ACS Catal. 2018, 8, 6255-6264.
[14]
Jiang, K.; Siahrostami, S.; Zheng, T. T.; Hu, Y. F.; Hwang, S.; Stavitski, E.; Peng, Y. D.; Dynes, J.; Gangisetty, M.; Su, D. et al. Isolated Ni single atoms in graphenenanosheets for high-performance CO2 reduction. Energy Environ. Sci. 2018, 11, 893-903.
[15]
Yang, H. B.; Hung, S. F.; Liu, S.; Yuan, K. D.; Miao, S.; Zhang, L. P.; Huang, X.; Wang, H. Y.; Cai, W. Z.; Chen, R. et al. Atomically dispersed Ni(I) as the active site for electrochemical CO2 reduction. Nat. Energy 2018, 3, 140-147.
[16]
Zhao, C. M.; Dai, X. Y.; Yao, T.; Chen, W. X.; Wang, X. Q.; Wang, J.; Yang, J.; Wei, S. Q.; Wu, Y. E.; Li, Y. D. Ionic exchange of metal- organic frameworks to access single nickel sites for efficient electroreduction of CO2. J. Am. Chem. Soc. 2017, 139, 8078-8081.
[17]
Li, X. G.; Bi, W. T.; Chen, M. L.; Sun, Y. X.; Ju, H. X.; Yan, W. S.; Zhu, J. F.; Wu, X. J.; Chu, W. S.; Wu, C. Z. et al. Exclusive Ni-N4 sites realize near-unity CO selectivity for electrochemical CO2 reduction. J. Am. Chem. Soc. 2017, 139, 14889-14892.
[18]
Yan, C. C.; Li, H. B.; Ye, Y. F.; Wu, H. H.; Cai, F.; Si, R.; Xiao, J. P.; Miao, S.; Xie, S. H.; Yang, F. et al. Coordinatively unsaturated nickel- nitrogen sites towards selective and high-rate CO2 electroreduction. Energy Environ. Sci. 2018, 11, 1204-1210.
[19]
Pan, F. P.; Li, B. Y.; Sarnello, E.; Hwang, S.; Gang, Y.; Feng, X. H.; Xiang, X. M.; Adli, N. M.; Li, T.; Su, D. et al. Boosting CO2 reduction on Fe-N-C with sulfur incorporation: Synergistic electronic and structural engineering. Nano Energy 2020, 68, 104384.
[20]
Wang, Y. C.; Lai, Y. J.; Song, L.; Zhou, Z. Y.; Liu, J. G.; Wang, Q.; Yang, X. D.; Chen, C.; Shi, W.; Zheng, Y. P. et al. S-doping of an Fe/N/C ORR catalyst for polymer electrolyte membrane fuel cells with high power density. Angew. Chem., Int. Ed. 2015, 54, 9907-9910.
[21]
Wu, Q.; Yang, L. J.; Wang, X. Z.; Hu, Z. From carbon-based nanotubes to nanocages for advanced energy conversion and storage. Acc. Chem. Res. 2017, 50, 435-444.
[22]
Wu, Q.; Yang, L. J.; Wang, X. Z.; Hu, Z. Carbon-based nanocages: A new platform for advanced energy storage and conversion. Adv. Mater., in press, .
[23]
Sun, T.; Wu, Q.; Zhuo, O.; Jiang, Y. F.; Bu, Y. F.; Yang, L. J.; Wang, X. Z.; Hu, Z. Manganese oxide-induced strategy to high-performance iron/nitrogen/carbon electrocatalysts with highly exposed active sites. Nanoscale 2016, 8, 8480-8485.
[24]
Delley, B. An all-electron numerical method for solving the local density functional for polyatomic molecules. J. Chem. Phys. 1990, 92, 508-517.
[25]
Delley, B. From molecules to solids with the DMol3 approach. J. Chem. Phys. 2000, 113, 7756-7764.
[26]
Perdew, J. P.; Burke, K.; Ernzerhof, M. Generalized gradient approximation made simple. Phys. Rev. Lett. 1996, 77, 3865-3868.
[27]
Peterson, A. A.; Abild-Pedersen, F.; Studt, F.; Rossmeisl, J.; Nørskov, J. K. How copper catalyzes the electroreduction of carbon dioxide into hydrocarbonfuels. Energy Environ. Sci. 2010, 3, 1311-1315.
[28]
Yang, H. Z.; Shang, L.; Zhang, Q. H.; Shi, R.; Waterhouse, G. I. N.; Gu, L.; Zhang, T. R. A universal ligand mediated method for large scale synthesis of transition metal single atom catalysts. Nat. Commun. 2019, 10, 4585.
[29]
Chen, H.; Yang, Y.; Hu, Z.; Huo, K. F.; Ma, Y. W.; Chen, Y.; Wang, X. S.; Lu, Y. N. Synergism of C5N six-membered ring and vapor- liquid-solid growth of CNx nanotubes with pyridine precursor. J. Phys. Chem. B 2006, 110, 16422-16427.
[30]
Lu, J. Z.; Yang, L. J.; Xu, B. L.; Wu, Q.; Zhang, D.; Yuan, S. J.; Zhai, Y.; Wang, X. Z.; Fan, Y. N.; Hu, Z. Promotion effects of nitrogen doping into carbon nanotubes on supported iron fischer-tropsch catalysts for lower olefins. ACS Catal. 2014, 4, 613-621.
[31]
Kim, S. J.; Park, Y. J.; Ra, E. J.; Kim, K. K.; An, K. H.; Lee, Y. H.; Choi, J. Y.; Park, C. H.; Doo, S. K.; Park, M. H. et al. Defect- induced loading of Ptnanoparticles on carbon nanotubes. Appl. Phys. Lett. 2007, 90, 023114.
[32]
Pieta, I. S.; Rathi, A.; Pieta, P.; Nowakowski, R.; Hołdynski, M.; Pisarek, M.; Kaminska, A.; Gawande, M. B.; Zboril, R. Electrocatalytic methanol oxidation over Cu, Ni and bimetallic Cu-Ni nanoparticles supported on graphitic carbon nitride. Appl. Catal. B: Environ. 2019, 244, 272-283.
[33]
Zhang, J.; An, Z.; Zhu, Y. R.; Shu, X.; Song, H. Y.; Jiang, Y. T.; Wang, W. L.; Xiang, X.; Xu, L. L.; He, J. Ni0/Niδ+ synergistic catalysis on a nanosized Ni surface for simultaneous formation of C-C and C-N bonds. ACS Catal. 2019, 9, 11438-11446.
[34]
Fan, L. L.; Liu, P. F.; Yan, X. C.; Gu, L.; Yang, Z. Z.; Yang, H. G.; Qiu, S. L.; Yao, X. D. Atomically isolated nickel species anchored on graphitized carbon for efficient hydrogen evolution electrocatalysis. Nat. Commun. 2016, 7, 10667.
[35]
Chen, Z. P.; Mou, K. W.; Wang, X. H.; Liu, L. C. Nitrogen-doped graphene quantum dots enhance the activity of Bi2O3 nanosheets for electrochemical reduction of CO2 in a wide negative potential region. Angew. Chem., Int. Ed. 2018, 130, 12972-12976.
[36]
Ross, M. B.; De Luna, P.; Li, Y. F.; Dinh, C.; Kim, D.; Yang, P. D.; Sargent, E. H. Designing materials for electrochemical carbon dioxide recycling. Nat. Catal. 2019, 2, 648-658.
[37]
Chen, P. Z.; Zhou, T. P.; Xing, L. L.; Xu, K.; Tong, Y.; Xie, H.; Zhang, L. D.; Yan, W. S.; Chu, W. S.; Wu, C. Z. et al. Atomically dispersed iron-nitrogen species as electrocatalysts for bifunctional oxygen evolution and reduction reactions. Angew. Chem., Int. Ed. 2017, 56, 610-614.
[38]
Shen, H. J.; Gracia-Espino, E.; Ma, J. Y.; Zang, K. T.; Luo, J.; Wang, L.; Gao, S. S.; Mamat, X.; Hu, G. Z.; Wagberg, T. et al. Synergistic effects between atomically dispersed Fe-N-C and C-S-C for the oxygen reduction reaction in acidic media. Angew. Chem., Int. Ed. 2017, 56, 13800-13804.
[39]
Li, Q. H.; Chen, W. X.; Xiao, H.; Gong, Y.; Li, Z.; Zheng, L. R.; Zheng, X. S.; Yan, W. S.; Cheong, W. C.; Shen, R. A. et al. Fe isolated single atoms on S, N codoped carbon by copolymer pyrolysis strategy for highly efficient oxygen reduction reaction. Adv. Mater. 2018, 30, 1800588.
[40]
Zhang, C. H.; Yang, S. Z.; Wu, J. J.; Liu, M. J.; Yazdi, S.; Ren, M. Q.; Sha, J. W.; Zhong, J.; Nie, K. Q.; Jalilov, A. S. et al. Electrochemical CO2 reduction with atomic iron-dispersed on nitrogen-doped graphene. Adv. Energy Mater. 2018, 8, 1703487.
[41]
Lei, F. C.; Liu, W.; Sun, Y. F.; Xu, J. Q.; Liu, K. T.; Liang, L.; Yao, T.; Pan, B. C.; Wei, S. Q.; Xie, Y. Metallic tin quantum sheets confined in graphene toward high-efficiency carbon dioxide electroreduction. Nat. Commun. 2016, 7, 12697.
[42]
Li, X. Y.; Shen, J.; Wu, C.; Wu, K. B. Ball-mill-exfoliated graphene: Tunable electrochemistry and phenol sensing. Small 2019, 15, 1805567.
[43]
Zhu, J. Y.; Childress, A. S.; Karakaya, M.; Dandeliya, S.; Srivastava, A.; Lin, Y.; Rao, A. M.; Podila, R. Defect-engineered graphene for high-energy- and high-power-density supercapacitor devices. Adv. Mater. 2016, 28, 7185-7192.
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