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Nano Research 2020, 13(10): 2665-2672 https://doi.org/10.1007/s12274-020-2908-4
Research Article | Issue | Published: 26 June 2020

An efficient visible-light photocatalyst for CO2 reduction fabricated by cobalt porphyrin and graphitic carbon nitride via covalent bonding

Show Author's Information Shufang Tian1,  Sudi Chen1,  Xitong Ren1,  Yaoqing Hu1,  Haiyan Hu1,  Jiajie Sun2( ),  Feng Bai1( )
Key Laboratory for Special Functional Materials of Ministry of Education, National & Local Joint Engineering Research Center for High- efficiency Display and Lighting Technology, School of Materials Science and Engineering, and Collaborative Innovation Center of Nano Functional Materials and Applications, Henan University, Kaifeng 475004, China
School of Physics and Electronics, Henan University, Kaifeng 475004, China
Keywords:
carbon nitride, photocatalysis, CO2 reduction, two-dimensional nanosheets, porphyrin, covalent bonding, function integrated
Topics:
Carbon dioxideCarbon nitrideLightNanoparticlesSynthesis (chemical)
Cite this article:
Tian S, Chen S, Ren X, et al. An efficient visible-light photocatalyst for CO2 reduction fabricated by cobalt porphyrin and graphitic carbon nitride via covalent bonding. Nano Research, 2020, 13(10): 2665-2672. https://doi.org/10.1007/s12274-020-2908-4
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Abstract Full text Electronic supplementary material About this article

Nanoparticle photosensitizers possess technical advantages for photocatalytic reactions due to enhanced light harvesting and efficient charge transport. Here we report synthesis of semiconductor nanoparticles through covalent coupling and assembly of metalloporphyrin with condensed carbon nitride. The resultant nanoparticles consist of light harvesting component from the condensed carbon nitride and photocatalytic sites from the metalloporphyrins. This synergetic particle system effectively initiates efficient charge separation and transport and exhibits excellent photocatalytic activity for CO2 reduction. The CO production rate can reach up to 57 μmol/(g·h) with a selectivity of 79% over competing H2 evolution. Controlled experiments demonstrate that the combination of light harvesting with photocatalytic activity via covalent assembly is crucial for the high photocatalytic activity. Due to effective charge separation and transfer, the resultant nanoparticle photocatalysts show exceptional photo stability against photo-corrosion under light irradiation, enabling for long-term utilization. This research opens a new way for the development of stable, effective nanoparticle photocatalysts using naturally abundant porphyrin pigments.


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Electronic supplementary material
About this article

An efficient visible-light photocatalyst for CO2 reduction fabricated by cobalt porphyrin and graphitic carbon nitride via covalent bonding

Show Author's information Shufang Tian1, Sudi Chen1, Xitong Ren1, Yaoqing Hu1, Haiyan Hu1, Jiajie Sun2( ), Feng Bai1( )
Key Laboratory for Special Functional Materials of Ministry of Education, National & Local Joint Engineering Research Center for High- efficiency Display and Lighting Technology, School of Materials Science and Engineering, and Collaborative Innovation Center of Nano Functional Materials and Applications, Henan University, Kaifeng 475004, China
School of Physics and Electronics, Henan University, Kaifeng 475004, China

Abstract

Nanoparticle photosensitizers possess technical advantages for photocatalytic reactions due to enhanced light harvesting and efficient charge transport. Here we report synthesis of semiconductor nanoparticles through covalent coupling and assembly of metalloporphyrin with condensed carbon nitride. The resultant nanoparticles consist of light harvesting component from the condensed carbon nitride and photocatalytic sites from the metalloporphyrins. This synergetic particle system effectively initiates efficient charge separation and transport and exhibits excellent photocatalytic activity for CO2 reduction. The CO production rate can reach up to 57 μmol/(g·h) with a selectivity of 79% over competing H2 evolution. Controlled experiments demonstrate that the combination of light harvesting with photocatalytic activity via covalent assembly is crucial for the high photocatalytic activity. Due to effective charge separation and transfer, the resultant nanoparticle photocatalysts show exceptional photo stability against photo-corrosion under light irradiation, enabling for long-term utilization. This research opens a new way for the development of stable, effective nanoparticle photocatalysts using naturally abundant porphyrin pigments.

Keywords: carbon nitride, photocatalysis, CO2 reduction, two-dimensional nanosheets, porphyrin, covalent bonding, function integrated

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Publication history
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Acknowledgements

Publication history

Received: 21 May 2020
Revised: 28 May 2020
Accepted: 29 May 2020
Published: 26 June 2020
Issue date: October 2020

Copyright

© Tsinghua University Press and Springer-Verlag GmbH Germany, part of Springer Nature 2020

Acknowledgements

F. B. acknowledges the support from the National Natural Science Foundation of China (Nos. 21771055 and U1604139), Zhongyuan high level talents special support plan (No. 204200510010), and Scientific and Technological Innovation Team in University of Henan Province (No. 20IRTSTHN001).

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