Cobalt phosphide nanoarrays with crystalline-amorphous hybrid phase for hydrogen production in universal-pH

Hyunseok Yoon; Hee Jo Song; Bobae Ju; Dong-Wan Kim

doi:10.1007/s12274-020-2881-y

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Research Article

Cobalt phosphide nanoarrays with crystalline-amorphous hybrid phase for hydrogen production in universal-pH

Hyunseok Yoon, Hee Jo Song, Bobae Ju, Dong-Wan Kim(

)

School of Civil, Environmental and Architectural Engineering, Korea University, Seoul 02841, Republic of Korea

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An erratum to this article is available online at:

https://doi.org/10.1007/s12274-020-2960-0

Graphical Abstract

Abstract

To accomplish mass hydrogen production by electrochemical water-splitting, it is a necessary to develop robust, highly active, stable, and cost-effective hydrogen evolution reaction (HER) electrocatalysts that perform comparably to Pt in the universal pH range. In this work, cobalt phosphide hybrid nanosheets supported on carbon felt (CoP HNS/CF) are presented, which exhibit the superior electrocatalytic hydrogen production under a universal-pH. In these nanosheets, a single CoP HNS is composed of polycrystalline CoP and oxygen-enriched amorphous Co-O-P phase. Benefiting from its unique nanoarchitecture, as-fabricated CoP HNS/CF exhibits a tremendous electrocatalytic HER activity and outperforms Pt/C as well as state-of-the-art CoP electrocatalysts in universal-pH. In acidic and neutral media, the CoP HNS/CF shows superior electrocatalytic activity while maintaining its original hybrid crystalline-amorphous phase and morphology. In alkaline medium, the unexpected phase and morphological reorganization of CoP HNS/CF results in outstanding electrocatalytic operation. CoP HNS/CF not only achieves high electrocatalytic activity and kinetics, but also a stable and long operating lifetime even under a high current density of 500 mA·cm^-2. Furthermore, the fabrication of CoP HNS/CF can be scaled up easily, and the large CoP HNS/CF electrode also exhibits similar electrocatalytic activity and stability.

Keywords

cobalt phosphide self-supporting electrocatalyst hydrogen evolution reaction universal-ph large-scale

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Nano Research

Volume 13 Issue 9,
September 2020

Pages 2469-2477

DOI: 10.1007/s12274-020-2881-y

Cite this article:

Yoon H, Song HJ, Ju B, et al. Cobalt phosphide nanoarrays with crystalline-amorphous hybrid phase for hydrogen production in universal-pH. Nano Research, 2020, 13(9): 2469-2477. https://doi.org/10.1007/s12274-020-2881-y

Topics:

Cobalt compounds Cost effectiveness Electrocatalysts Hydrogen evolution reaction Hydrogen production Nanosheets

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Received: 01 April 2020

Revised: 12 May 2020

Accepted: 14 May 2020

Published: 25 June 2020