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Nano Research 2020, 13(9): 2407-2412 https://doi.org/10.1007/s12274-020-2865-y
Research Article | Issue | Published: 17 June 2020

Interfacial engineering of Ni/V2O3 for hydrogen evolution reaction

Show Author's Information Yang Chen1,§,  Yuan Rao1,§,  Rongzhi Wang1,  Yanan Yu1,  Qiulin Li2,  Shujuan Bao2,  Maowen Xu2,  Qin Yue1,  Yanning Zhang1( ),  Yijin Kang1( )
Institute of Fundamental and Frontier Sciences, University of Electronic Science and Technology of China, Chengdu 610054, China
Key Laboratory of Luminescent and Real-Time Analytical Chemistry, Ministry of Education, Institute for Clean Energy and Advanced Materials, Faculty of Materials and Energy, Southwest University, Chongqing 400715, China

§ Yang Chen and Yuan Rao contributed equally to this work.

Keywords:
interface, electrocatalysis, hydrogen evolution reaction, vanadium oxide, hierarchical materials
Topics:
ElectrocatalystsElectrolytesHydrogen economyHydrogen evolution reaction Nickel compoundsPotassium hydroxide
Cite this article:
Chen Y, Rao Y, Wang R, et al. Interfacial engineering of Ni/V2O3 for hydrogen evolution reaction. Nano Research, 2020, 13(9): 2407-2412. https://doi.org/10.1007/s12274-020-2865-y
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Abstract Full text Electronic supplementary material About this article

Electrocatalytic water splitting offers a sustainable route for hydrogen production, enabling the clean and renewable alternative energy system of hydrogen economy. The scarcity and high-cost of platinum-group-metal (PGM) materials urge the exploration of high-performance non-PGM electrocatalysts. Herein, a unique hierarchical structure of Ni/V2O3 with extraordinary electrocatalytic performance (e.g., overpotentials as low as 22 mV at 20 mA·cm-2 and 94 mV at 100 mA·cm-2) toward hydrogen evolution reaction in alkaline electrolyte (1 M KOH) is reported. The investigation on the hierarchical Ni/V2O3 with a bimodal size-distribution also offers insight of interfacial engineering that only proper Ni/V2O3 interface can effectively improve H2O adsorption, H2O dissociation as well as H adsorption, for an efficient hydrogen production.


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Abstract
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Electronic supplementary material
About this article

Interfacial engineering of Ni/V2O3 for hydrogen evolution reaction

Show Author's information Yang Chen1,§, Yuan Rao1,§, Rongzhi Wang1, Yanan Yu1, Qiulin Li2, Shujuan Bao2, Maowen Xu2, Qin Yue1, Yanning Zhang1( ), Yijin Kang1( )
Institute of Fundamental and Frontier Sciences, University of Electronic Science and Technology of China, Chengdu 610054, China
Key Laboratory of Luminescent and Real-Time Analytical Chemistry, Ministry of Education, Institute for Clean Energy and Advanced Materials, Faculty of Materials and Energy, Southwest University, Chongqing 400715, China

§ Yang Chen and Yuan Rao contributed equally to this work.

Abstract

Electrocatalytic water splitting offers a sustainable route for hydrogen production, enabling the clean and renewable alternative energy system of hydrogen economy. The scarcity and high-cost of platinum-group-metal (PGM) materials urge the exploration of high-performance non-PGM electrocatalysts. Herein, a unique hierarchical structure of Ni/V2O3 with extraordinary electrocatalytic performance (e.g., overpotentials as low as 22 mV at 20 mA·cm-2 and 94 mV at 100 mA·cm-2) toward hydrogen evolution reaction in alkaline electrolyte (1 M KOH) is reported. The investigation on the hierarchical Ni/V2O3 with a bimodal size-distribution also offers insight of interfacial engineering that only proper Ni/V2O3 interface can effectively improve H2O adsorption, H2O dissociation as well as H adsorption, for an efficient hydrogen production.

Keywords: interface, electrocatalysis, hydrogen evolution reaction, vanadium oxide, hierarchical materials

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Publication history
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Acknowledgements

Publication history

Received: 07 April 2020
Revised: 04 May 2020
Accepted: 08 May 2020
Published: 17 June 2020
Issue date: September 2020

Copyright

© Tsinghua University Press and Springer-Verlag GmbH Germany, part of Springer Nature 2020

Acknowledgements

The work is supported by the National Natural Science Foundation of China (Nos. 11874005, 21701153, 51601030 and 21773023).

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