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Nano Research 2021, 14(2): 392-397 https://doi.org/10.1007/s12274-020-2830-9
Research Article | Issue | Published: 22 May 2020

Discovery of Zr-based metal-organic polygon: Unveiling new design opportunities in reticular chemistry

Show Author's Information Jiyeon Kim1,  Dongsik Nam1,  Hiroshi Kitagawa2,  Dae-Woon Lim2,†,( ),  Wonyoung Choe1,( )
Department of Chemistry, Ulsan National Institute of Science and Technology, 50 UNIST-gil, Ulsan 44919, Republic of Korea
Department of Chemistry, Graduate School of Science, Kyoto University, Kitashirakawa Oiwake-cho, Sakyo-ku, Kyoto 606-8502, Japan

† Present address: Department of Chemistry and Medical Chemistry, College of Science and Technology, Yonsei University, 1 Yonseidae-gil, Wonju, Gangwon-do 26493, Republic of Korea

Keywords:
reticular chemistry, Zr-based metal-organic polygon, geometrical frustration, ditopic, secondary building unit
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Ligands Organometallics
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Kim J, Nam D, Kitagawa H, et al. Discovery of Zr-based metal-organic polygon: Unveiling new design opportunities in reticular chemistry. Nano Research, 2021, 14(2): 392-397. https://doi.org/10.1007/s12274-020-2830-9
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Abstract Full text Electronic supplementary material About this article

Metal-based secondary building unit and the shape of organic ligands are the two crucial factors for determining the final topology of metal-organic materials. A careful choice of organic and inorganic structural building units occasionally produces unexpected structures, facilitating deeper fundamental understanding of coordination-driven self-assembly behind metal-organic materials. Here, we have synthesized a triangular metal-organic polygon (MOT-1), assembled from bulky tetramethyl terephthalate and Zr-based secondary building unit. Surprisingly, the Zr-based secondary building unit serves as an unusual ditopic Zr-connector, to form metal-organic polygon MOT-1, proven to be a good candidate for water adsorption with recyclability. This study highlights the interplay of the geometrically frustrated ligand and secondary building unit in controlling the connectivity of metal-organic polygon. Such a strategy can be further used to unveil a new class of metal-organic materials.


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Electronic supplementary material
About this article

Discovery of Zr-based metal-organic polygon: Unveiling new design opportunities in reticular chemistry

Show Author's information Jiyeon Kim1, Dongsik Nam1, Hiroshi Kitagawa2, Dae-Woon Lim2,†,( ), Wonyoung Choe1,( )
Department of Chemistry, Ulsan National Institute of Science and Technology, 50 UNIST-gil, Ulsan 44919, Republic of Korea
Department of Chemistry, Graduate School of Science, Kyoto University, Kitashirakawa Oiwake-cho, Sakyo-ku, Kyoto 606-8502, Japan

† Present address: Department of Chemistry and Medical Chemistry, College of Science and Technology, Yonsei University, 1 Yonseidae-gil, Wonju, Gangwon-do 26493, Republic of Korea

Abstract

Metal-based secondary building unit and the shape of organic ligands are the two crucial factors for determining the final topology of metal-organic materials. A careful choice of organic and inorganic structural building units occasionally produces unexpected structures, facilitating deeper fundamental understanding of coordination-driven self-assembly behind metal-organic materials. Here, we have synthesized a triangular metal-organic polygon (MOT-1), assembled from bulky tetramethyl terephthalate and Zr-based secondary building unit. Surprisingly, the Zr-based secondary building unit serves as an unusual ditopic Zr-connector, to form metal-organic polygon MOT-1, proven to be a good candidate for water adsorption with recyclability. This study highlights the interplay of the geometrically frustrated ligand and secondary building unit in controlling the connectivity of metal-organic polygon. Such a strategy can be further used to unveil a new class of metal-organic materials.

Keywords: reticular chemistry, Zr-based metal-organic polygon, geometrical frustration, ditopic, secondary building unit

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Acknowledgements

Publication history

Received: 28 March 2020
Accepted: 24 April 2020
Published: 22 May 2020
Issue date: February 2021

Copyright

© Tsinghua University Press and Springer-Verlag GmbH Germany, part of Springer Nature

Acknowledgements

This work was supported by Korea Environment Industry & Technology Institute (KEITI) through Public Technology Program based on Environmental Policy Program, funded by Korea Ministry of Environment (MOE) (No. 2018000210002) and National Research Foundation (NRF) of Korea (Nos. NRF-2016R1A5A1009405 and NRF-2017M3C1B4051161). D.-W. L. and H. K. acknowledge the support from the ACCEL program, Japan Science and Technology Agency (JST), JPMJAC1501. J. K. acknowledges the support from NRF Grant funded by the Korean Government (No. NRF-2018H1A2A1061391-Global Ph.D. Fellowship Program). We acknowledge the Pohang Accelerator Laboratory (PAL) for 2D beamline use (2019- 1st-2D-038). We would like to thank Hyeonsoo Cho for providing 3D models for possible structures shown in Fig. 8.

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