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Nano Research 2021, 14(2): 507-511 https://doi.org/10.1007/s12274-020-2713-0
Research Article | Issue | Published: 09 March 2020

A microporous aluminum-based metal-organic framework for high methane, hydrogen, and carbon dioxide storage

Show Author's Information Bin Wang1,2,  Xin Zhang2,  Hongliang Huang4,  Zhangjing Zhang1,  Taner Yildirim3,  Wei Zhou3,  Shengchang Xiang1,( ),  Banglin Chen2,( )
Fujian Provincial Key Laboratory of Polymer Materials, College of Chemistry and Materials Science, Fujian Normal University, 32 Shangsan Road, Fuzhou 350007, China
Department of Chemistry, University of Texas at San Antonio, One UTSA Circle, San Antonio, Texas 78249-0698, USA
Center for Neutron Research, National Institute of Standards and Technology, Gaithersburg, Maryland 20899-6102, USA
State Key Laboratory of Separation Membranes and Membrane Processes, Tianjin Polytechnic University, Tianjin 300387, China
Keywords:
carbon dioxide, hydrogen, metal-organic frameworks (MOFs), gas storage, methane
Topics:
AluminumCarbon dioxideHydrogenHydrogen storageMicroporosity Organic polymersOrganometallics
Cite this article:
Wang B, Zhang X, Huang H, et al. A microporous aluminum-based metal-organic framework for high methane, hydrogen, and carbon dioxide storage. Nano Research, 2021, 14(2): 507-511. https://doi.org/10.1007/s12274-020-2713-0
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Abstract Full text Electronic supplementary material About this article

We report a microporous aluminum-based metal-organic framework (MOF), BUT-22 for high methane (CH4), hydrogen (H2), and carbon dioxide (CO2) storage. At 296 K and 80 bar, BUT-22 exhibits a high gravimetric CH4 storage capacity of 530 cm3 (STP)/g (0.379 g/g). BUT-22 also has a high gravimetric H2 storage capacity of 12 wt.% at 100 bar and 77 K. In addition, the CO2 adsorption studies revealed that BUT-22 exhibits a high absolute gravimetric CO2 uptake of 1.7 g/g at 296 K and 40 bar.


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About this article

A microporous aluminum-based metal-organic framework for high methane, hydrogen, and carbon dioxide storage

Show Author's information Bin Wang1,2, Xin Zhang2, Hongliang Huang4, Zhangjing Zhang1, Taner Yildirim3, Wei Zhou3, Shengchang Xiang1,( ), Banglin Chen2,( )
Fujian Provincial Key Laboratory of Polymer Materials, College of Chemistry and Materials Science, Fujian Normal University, 32 Shangsan Road, Fuzhou 350007, China
Department of Chemistry, University of Texas at San Antonio, One UTSA Circle, San Antonio, Texas 78249-0698, USA
Center for Neutron Research, National Institute of Standards and Technology, Gaithersburg, Maryland 20899-6102, USA
State Key Laboratory of Separation Membranes and Membrane Processes, Tianjin Polytechnic University, Tianjin 300387, China

Abstract

We report a microporous aluminum-based metal-organic framework (MOF), BUT-22 for high methane (CH4), hydrogen (H2), and carbon dioxide (CO2) storage. At 296 K and 80 bar, BUT-22 exhibits a high gravimetric CH4 storage capacity of 530 cm3 (STP)/g (0.379 g/g). BUT-22 also has a high gravimetric H2 storage capacity of 12 wt.% at 100 bar and 77 K. In addition, the CO2 adsorption studies revealed that BUT-22 exhibits a high absolute gravimetric CO2 uptake of 1.7 g/g at 296 K and 40 bar.

Keywords: carbon dioxide, hydrogen, metal-organic frameworks (MOFs), gas storage, methane

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Publication history
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Acknowledgements

Publication history

Received: 29 January 2020
Accepted: 11 February 2020
Published: 09 March 2020
Issue date: February 2021

Copyright

© Tsinghua University Press and Springer-Verlag GmbH Germany, part of Springer Nature

Acknowledgements

We acknowledge financial support from the National Natural Science Foundation of China (Nos. 21971038, 21975044, 21805039, 21673039, and 573042), the Fujian Science and Technology Department (Nos. 2019H6012 and 2018J07001), the China Postdoctoral Science Foundation (No. 2018M642556), and the Welch Foundation (No. AX-1730).

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