References(44)
[1]
Buchwalter, P.; Rosé, J.; Braunstein, P. Multimetallic catalysis based on heterometallic complexes and clusters. Chem. Rev. 2015, 115, 28-126.
[2]
Zhu, D. D.; Liu, J. L.; Qiao, S. Z. Recent advances in inorganic heterogeneous electrocatalysts for reduction of carbon dioxide. Adv. Mater. 2016, 28, 3423-3452.
[3]
Fan, Z. X.; Zhang, H. Template synthesis of noble metal nanocrystals with unusual crystal structures and their catalytic applications. Acc. Chem. Res. 2016, 49, 2841-2850.
[4]
Zhao, X. J.; Dai, L.; Qin, Q.; Pei, F.; Hu, C. Y.; Zheng, N. F. Self-supported 3D PdCu alloy nanosheets as a bifunctional catalyst for electrochemical reforming of ethanol. Small 2017, 13, 1602970.
[5]
Xu, L.; Liang, H. W.; Yang, Y.; Yu, S. H. Stability and reactivity: Positive and negative aspects for nanoparticle processing. Chem. Rev. 2018, 118, 3209-3250.
[6]
Yang, X. C.; Xu, Q. Gold-containing metal nanoparticles for catalytic hydrogen generation from liquid chemical hydrides. Chin. J. Catal. 2016, 37, 1594-1599.
[7]
Kumar, A.; Yang, X. C.; Xu, Q. Ultrafine bimetallic Pt-Ni nanoparticles immobilized on 3-dimensional N-doped graphene networks: A highly efficient catalyst for dehydrogenation of hydrous hydrazine. J. Mater. Chem. A 2019, 7, 112-115.
[8]
Yang, X. C.; Pachfule, P.; Chen, Y.; Tsumori, N.; Xu, Q. Highly efficient hydrogen generation from formic acid using a reduced graphene oxide-supported AuPd nanoparticle catalyst. Chem. Commun. 2016, 52, 4171-4174.
[9]
Christensen, A.; Stoltze, P.; Norskov, J. K. Size dependence of phase separation in small bimetallic clusters. J. Phys.: Condens. Matter 1995, 7, 1047-1057.
[10]
Essinger-Hileman, E. R.; DeCicco, D.; Bondi, J. F.; Schaak, R. E. Aqueous room-temperature synthesis of Au-Rh, Au-Pt, Pt-Rh, and Pd-Rh alloy nanoparticles: Fully tunable compositions within the miscibility gaps. J. Mater. Chem. 2011, 21, 11599-11604.
[11]
García, S.; Zhang, L.; Piburn, G. W.; Henkelman, G.; Humphrey, S. M. Microwave synthesis of classically immiscible rhodium-silver and rhodium-gold alloy nanoparticles: Highly active hydrogenation catalysts. ACS Nano 2014, 8, 11512-11521.
[12]
Chen, L. Y.; Chen, X. D.; Liu, H. L.; Li, Y. W. Encapsulation of mono- or bimetal nanoparticles inside metal-organic frameworks via in situ incorporation of metal precursors. Small 2015, 11, 2642-2648.
[13]
Zhang, Q.; Kusada, K.; Wu, D. S.; Yamamoto, T.; Toriyama, T.; Matsumura, S.; Kawaguchi, S.; Kubota, Y.; Kitagawa, H. Selective control of fcc and hcp crystal structures in Au-Ru solid-solution alloy nanoparticles. Nat. Commun. 2018, 9, 510.
[14]
Liu, H. L.; Chang, L. N.; Bai, C. H.; Chen, L. Y.; Luque, R.; Li, Y. W. Controllable encapsulation of “clean” metal clusters within MOFs through kinetic modulation: Towards advanced heterogeneous nanocatalysts. Angew. Chem., Int. Ed. 2016, 55, 5019-5023.
[15]
Liu, B.; Yao, H. Q.; Song, W. Q.; Jin, L.; Mosa, I. M.; Rusling, J. F.; Suib, S. L.; He, J. Ligand-free noble metal nanocluster catalysts on carbon supports via “soft” nitriding. J. Am. Chem. Soc. 2016, 138, 4718-4721.
[16]
Gao, W. B.; Wang, P. K.; Guo, J. P.; Chang, F.; He, T.; Wang, Q. R.; Wu, G. T.; Chen, P. Barium hydride-mediated nitrogen transfer and hydrogenation for ammonia synthesis: A case study of cobalt. ACS Catal. 2017, 7, 3654-3661.
[17]
Yang, X. C.; Sun, J. K.; Kitta, M.; Pang, H.; Xu, Q. Encapsulating highly catalytically active metal nanoclusters inside porous organic cages. Nat. Catal. 2018, 1, 214-220.
[18]
Liu, G. Y.; Sheng, Y.; Ager, J. W.; Kraft, M.; Xu, R. Research advances towards large-scale solar hydrogen production from water. EnergyChem 2019, 1, 100014.
[19]
Zheng, Y.; Jiao, Y.; Zhu, Y. H.; Li, L. H.; Han, Y.; Chen, Y.; Du, A. J.; Jaroniec, M.; Qiao, S. Z. Hydrogen evolution by a metal-free electrocatalyst. Nat. Commun. 2014, 5, 3783.
[20]
Kohl, M.; Borrmann, F.; Althues, H.; Kaskel, S. Hard carbon anodes and novel electrolytes for long-cycle-life room temperature sodium-sulfur full cell batteries. Adv. Energy Mater. 2016, 6, 1502185.
[21]
Hou, Y.; Qiu, M.; Zhang, T.; Ma, J.; Liu, S. H.; Zhuang, X. D.; Yuan, C.; Feng, X. L. Efficient electrochemical and photoelectrochemical water splitting by a 3D nanostructured carbon supported on flexible exfoliated graphene foil. Adv. Mater. 2017, 29, 1604480.
[22]
Pachfule, P.; Yang, X. C.; Zhu, Q. L.; Tsumori, N.; Uchida, T.; Xu, Q. From Ru nanoparticle-encapsulated metal-organic frameworks to highly catalytically active Cu/Ru nanoparticle-embedded porous carbon. J. Mater. Chem. A 2017, 5, 4835-4841.
[23]
He, L.; Weniger, F.; Neumann, H.; Beller, M. Synthesis, characterization, and application of metal nanoparticles supported on nitrogen-doped carbon: Catalysis beyond electrochemistry. Angew. Chem., Int. Ed. 2016, 55, 12582-12594.
[24]
Zhong, S.; Kitta, M.; Xu, Q. Hierarchically porous carbons derived from metal-organic framework/chitosan composites for high-performance supercapacitors. Chem. Asian J. 2019, 14, 3583-3589.
[25]
Lu, L. L.; Wu, B. Y.; Shi, W.; Chen, P. Metal-organic framework-derived heterojunctions as nanocatalysts for photocatalytic hydrogen production. Inorg. Chem. Front., in press, .
[26]
Huang, J. H.; Akita, T.; Faye, J.; Fujitani, T.; Takei, T.; Haruta, M. Propene epoxidation with dioxygen catalyzed by gold clusters. Angew. Chem., Int. Ed. 2009, 48, 7862-7866.
[27]
Zhong, R. Y.; Sun, K. Q.; Hong, Y. C.; Xu, B. Q. Impacts of organic stabilizers on catalysis of Au nanoparticles from colloidal preparation. ACS Catal. 2014, 4, 3982-3993.
[28]
Sun, J. K.; Zhan, W. W.; Akita, T.; Xu, Q. Toward homogenization of heterogeneous metal nanoparticle catalysts with enhanced catalytic performance: Soluble porous organic cage as a stabilizer and homogenizer. J. Am. Chem. Soc. 2015, 137, 7063-7066.
[29]
Okamoto, H.; Massalski, T. B. The Au-Rh (gold-rhodium) system. Bull. Alloy Phase Diagrams 1984, 5, 384-387.
[30]
Richardson, M. J.; Johnston, J. H. Sorption and binding of nanocrystalline gold by Merino wool fibres—An XPS study. J. Colloid Interface Sci. 2007, 310, 425-430.
[31]
Arrigo, R.; Hävecker, M.; Wrabetz, S.; Blume, R.; Lerch, M.; McGregor, J.; Parrott, E. P. J.; Zeitler, J. A.; Gladden, L. F.; Knop-Gericke, A. et al. Tuning the acid/base properties of nanocarbons by functionalization via amination. J. Am. Chem. Soc. 2010, 132, 9616-9630.
[32]
Wong, A.; Liu, Q.; Griffin, S.; Nicholls, A.; Regalbuto, J. R. Synthesis of ultrasmall, homogeneously alloyed, bimetallic nanoparticles on silica supports. Science 2017, 358, 1427-1430.
[33]
Moret, S.; Dyson, P. J.; Laurenczy, G. Direct synthesis of formic acid from carbon dioxide by hydrogenation in acidic media. Nat. Commun. 2014, 5, 4017.
[34]
Wang, W. H.; Ertem, M. Z.; Xu, S. A.; Onishi, N.; Manaka, Y.; Suna, Y.; Kambayashi, H.; Muckerman, J. T.; Fujita, E.; Himeda, Y. Highly robust hydrogen generation by bioinspired Ir complexes for dehydrogenation of formic acid in water: Experimental and theoretical mechanistic investigations at different pH. ACS Catal. 2015, 5, 5496-5504.
[35]
Mellmann, D.; Sponholz, P.; Junge, H.; Beller, M. Formic acid as a hydrogen storage material-development of homogeneous catalysts for selective hydrogen release. Chem. Soc. Rev. 2016, 45, 3854-3988.
[36]
Sun, Q. M.; Wang, N.; Bing, Q. M.; Si, R.; Liu, J. Y.; Bai, R. S.; Zhang, P.; Jia, M. J.; Yu, J. H. Subnanometric hybrid Pd-M(OH)2, M = Ni, Co, clusters in zeolites as highly efficient nanocatalysts for hydrogen generation. Chem 2017, 3, 477-493.
[37]
Li, Z. P.; Xu, Q. Metal-nanoparticle-catalyzed hydrogen generation from formic acid. Acc. Chem. Res. 2017, 50, 1449-1458.
[38]
Sordakis, K.; Tang, C. H.; Vogt, L. K.; Junge, H.; Dyson, P. J.; Beller, M.; Laurenczy, G. Homogeneous catalysis for sustainable hydrogen storage in formic acid and alcohols. Chem. Rev. 2018, 118, 372-433.
[39]
Mori, K.; Sano, T.; Kobayashi, H.; Yamashita, H. Surface engineering of a supported PdAg catalyst for hydrogenation of CO2 to formic acid: Elucidating the active Pd atoms in alloy nanoparticles. J. Am. Chem. Soc. 2018, 140, 8902-8909.
[40]
Hong, C. B.; Zhu, D. J.; Ma, D. D.; Wu, X. T.; Zhu, Q. L. An effective amino acid-assisted growth of ultrafine palladium nanocatalysts toward superior synergistic catalysis for hydrogen generation from formic acid. Inorg. Chem. Front. 2019, 6, 975-981.
[41]
Li, S. J.; Zhou, Y. T.; Kang, X.; Liu, D. X.; Gu, L.; Zhang, Q. H.; Yan, J. M.; Jiang, Q. A simple and effective principle for a rational design of heterogeneous catalysts for dehydrogenation of formic acid. Adv. Mater. 2019, 31, 1806781.
[42]
Madon, R. J.; Boudart, M. Experimental criterion for the absence of artifacts in the measurement of rates of heterogeneous catalytic reactions. Ind. Eng. Chem. Fundamen. 1982, 21, 438-447.
[43]
Singh, U. K.; Vannice, M. A. Kinetic and thermodynamic analysis of liquid-phase benzene hydrogenation. AIChE J. 1999, 45, 1059-1071.
[44]
Schaber, P. M.; Colson, J; Higgins, S.; Thielen, D.; Anspach, B.; Brauer, J. Thermal decomposition (pyrolysis) of urea in an open reaction vessel. Thermochim. Acta 2004, 424, 131-142.