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Nano Research 2019, 12(8): 1921-1930 https://doi.org/10.1007/s12274-019-2459-8
Research Article | Issue | Published: 06 July 2019

Function-regeneration of non-porous hydrolyzed-MOF-derived materials

Show Author's Information Yo Chan Jeong1,  Jin Weon Seo2,  Jae Ho Kim1,  Seunghoon Nam3,  Min Chang Shin2,  Young Shik Cho1,  Jin Syul Byeon2,  Chong Rae Park1( ),  Seung Jae Yang2( )
Carbon Nanomaterials Design Laboratory, Research Institute of Advanced Materials and Department of Materials Science and Engineering,Seoul National University,Seoul,08826,Republic of Korea;
Advanced Nanohybrids Lab., Department of Chemical Engineering,Inha University,Incheon,22212,Republic of Korea;
School of Advanced Materials Engineering,College of Engineering, Andong National University,Andong, Gyeongsangbuk-do,36729,Republic of Korea;
Keywords:
nanomaterials, porous materials, metal–organic framework (MOF), MOF-derived carbon, hydrolyzed MOF
Topics:
Crystalline materials GrapheneIIIon batteriesLithiumNanostructured materialsOrganic polymersOrganometallicsPorous materialsTin oxidesVI semiconductors
Cite this article:
Jeong YC, Seo JW, Kim JH, et al. Function-regeneration of non-porous hydrolyzed-MOF-derived materials. Nano Research, 2019, 12(8): 1921-1930. https://doi.org/10.1007/s12274-019-2459-8
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Abstract Full text Electronic supplementary material About this article

A facile synthetic strategy based on a water-based process is developed for the preparation of metal–organic framework (MOF)-derived materials by revisiting the hydrolyzed non-porous metal–organic frameworks (h-MOF). The poor water stability of MOF has been recognized as key limitations for its commercialization and large-scale applications because the hydrolysis resulted in the complete loss of their functionalities. However, we found that the negative effect of hydrolysis on MOF can be nullified during the heat treatment. As similar to the intact MOF, h-MOF can be used as a precursor for the preparation of MOF-derived materials from porous MOF-derived carbons (MDCs) to MDC@ZnO composites. The property of h-MOF-derived materials is almost equivalent to that of MOF-derived materials. In addition, h-MOF turned the weakness of water instability to the strength of facile water-based process for hybridization. With the demonstration of the hybrid composite between h-MDC@ZnO and reduced graphene oxide (rGO) as a prototype example, it exhibited superior electrochemical performance when evaluated as an electrode material for lithium-ion batteries.


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Electronic supplementary material
About this article

Function-regeneration of non-porous hydrolyzed-MOF-derived materials

Show Author's information Yo Chan Jeong1, Jin Weon Seo2, Jae Ho Kim1, Seunghoon Nam3, Min Chang Shin2, Young Shik Cho1, Jin Syul Byeon2, Chong Rae Park1( ), Seung Jae Yang2( )
Carbon Nanomaterials Design Laboratory, Research Institute of Advanced Materials and Department of Materials Science and Engineering,Seoul National University,Seoul,08826,Republic of Korea;
Advanced Nanohybrids Lab., Department of Chemical Engineering,Inha University,Incheon,22212,Republic of Korea;
School of Advanced Materials Engineering,College of Engineering, Andong National University,Andong, Gyeongsangbuk-do,36729,Republic of Korea;

Abstract

A facile synthetic strategy based on a water-based process is developed for the preparation of metal–organic framework (MOF)-derived materials by revisiting the hydrolyzed non-porous metal–organic frameworks (h-MOF). The poor water stability of MOF has been recognized as key limitations for its commercialization and large-scale applications because the hydrolysis resulted in the complete loss of their functionalities. However, we found that the negative effect of hydrolysis on MOF can be nullified during the heat treatment. As similar to the intact MOF, h-MOF can be used as a precursor for the preparation of MOF-derived materials from porous MOF-derived carbons (MDCs) to MDC@ZnO composites. The property of h-MOF-derived materials is almost equivalent to that of MOF-derived materials. In addition, h-MOF turned the weakness of water instability to the strength of facile water-based process for hybridization. With the demonstration of the hybrid composite between h-MDC@ZnO and reduced graphene oxide (rGO) as a prototype example, it exhibited superior electrochemical performance when evaluated as an electrode material for lithium-ion batteries.

Keywords: nanomaterials, porous materials, metal–organic framework (MOF), MOF-derived carbon, hydrolyzed MOF

References(78)

1

Davis, M. E. Ordered porous materials for emerging applications. Nature 2002, 417, 813-821.
DOI Google Scholar
2

Kitagawa, S. Future porous materials. Acc. Chem. Res. 2017, 50, 514-516.
DOI Google Scholar
3

Lee, K. J.; Lee, J. H.; Jeoung, S.; Moon, H. R. Transformation of metal-organic frameworks/coordination polymers into functional nanostructured materials: Experimental approaches based on mechanistic insights. Acc. Chem. Res. 2017, 50, 2684-2692.
DOI Google Scholar
4

Liu, C.; Li, F.; Ma, L. P.; Cheng, H. M. Advanced materials for energy storage. Adv. Mater. 2010, 22, E28-E62.
DOI Google Scholar
5

Chen, K.; Sun, Z. H; Fang, R. P; Shi, Y.; Cheng, H. M.; Li, F. Metal-organic frameworks (MOFs)-derived nitrogen-doped porous carbon anchored on graphene with multifunctional effects for lithium-sulfur batteries. Adv. Funct. Mater. 2018, 28, 1707592.
DOI Google Scholar
6

Krause, S.; Bon, V.; Senkovska, I.; Többens, D. M.; Wallacher, D.; Pillai, R. S.; Maurin, G.; Kaskel, S. The effect of crystallite size on pressure amplification in switchable porous solids. Nat. Commun. 2018, 9, 1573.
DOI Google Scholar
7

Zheng, F. C.; Yang, Y.; Chen, Q. W. High lithium anodic performance of highly nitrogen-doped porous carbon prepared from a metal-organic framework. Nat. Commun. 2014, 5, 5261.
DOI Google Scholar
8

Jiang, H. L.; Liu, B.; Akita, T.; Haruta, M.; Sakurai, H.; Xu, Q. Au@ZIF-8: CO oxidation over gold nanoparticles deposited to metal-organic framework. J. Am. Chem. Soc. 2009, 131, 11302-11303.
DOI Google Scholar
9

Liu, B.; Shioyama, H.; Jiang, H. L.; Zhang, X. B.; Xu, Q. Metal-organic framework (MOF) as a template for syntheses of nanoporous carbons as electrode materials for supercapacitor. Carbon 2010, 48, 456-463.
DOI Google Scholar
10

Kim, T. K.; Lee, K. J.; Cheon, J. Y.; Lee, J. H.; Joo, S. H.; Moon, H. R. Nanoporous metal oxides with tunable and nanocrystalline frameworks via conversion of metal-organic frameworks. J. Am. Chem. Soc. 2013, 135, 8940-8946.
DOI Google Scholar
11

Zhou, H. C. J.; Kitagawa, S. Metal-organic frameworks (MOFs). Chem. Soc. Rev. 2014, 43, 5415-5418.
DOI Google Scholar
12

Zheng, H. Q.; Zhang, Y. N.; Liu, L. F.; Wan, W.; Guo, P.; Nyström, A. M.; Zou, X. D. One-pot synthesis of metal-organic frameworks with encapsulated target molecules and their applications for controlled drug delivery. J. Am. Chem. Soc. 2016, 138, 962-968.
DOI Google Scholar
13

Chen, Y. Z.; Zhang, R.; Jiao, L.; Jiang, H. L. Metal-organic framework-derived porous materials for catalysis. Coord. Chem. Rev. 2018, 362, 1-23.
DOI Google Scholar
14

Jiao, L.; Wang, Y.; Jiang, H. L. Metal-organic frameworks as platforms for catalytic applications. Adv. Mater. 2018, 30, 1703663.
DOI Google Scholar
15

Jiao, L; Jiang, H. L. Metal-organic-framework-based single-atom catalysts for energy applications. Chem 2019, 5, 786-804.
DOI Google Scholar
16

Meek, S. T.; Greathouse, J. A.; Allendorf, M. D. Metal-organic frameworks: A rapidly growing class of versatile nanoporous materials. Adv. Mater. 2011, 23, 249-267.
DOI Google Scholar
17

Yang, S. J.; Cho, J. H.; Lee, K.; Kim, T.; Park, C. R. Concentration-driven evolution of crystal structure, pore characteristics, and hydrogen storage capacity of metal organic framework-5s: Experimental and computational studies. Chem. Mater. 2010, 22, 6138-6145.
DOI Google Scholar
18

Stock, N.; Biswas, S. Synthesis of metal-organic frameworks (MOFs): Routes to various MOF topologies, morphologies, and composites. Chem. Rev. 2012, 112, 933-969.
DOI Google Scholar
19

Ni, Z.; Masel, R. I. Rapid production of metal-organic frameworks via microwave-assisted solvothermal synthesis. J. Am. Chem. Soc. 2006, 128, 12394-12395.
DOI Google Scholar
20

Ming, Y.; Kumar, N.; Siegel, D. J. Water adsorption and insertion in MOF-5. ACS Omega 2017, 2, 4921-4928.
DOI Google Scholar
21

Kang, J. H.; Kim, T.; Choi, J.; Park, J.; Kim, Y. S.; Chang, M. S.; Jung, H.; Park, K. T.; Yang, S. J.; Park, C. R. Hidden second oxidation step of hummers method. Chem. Mater. 2016, 28, 756-764.
DOI Google Scholar
22

Kim, Y. S.; Kang, J. H.; Kim, T.; Jung, Y.; Lee, K.; Oh, J. Y.; Pank, J.; Park, C. R. Easy preparation of readily self-assembled high-performance graphene oxide fibers. Chem. Mater. 2014, 26, 5549-5555.
DOI Google Scholar
23

Oh, J. Y.; Yang, S. J.; Park, J. Y.; Kim, T.; Lee, K.; Kim, Y. S.; Han, H. N.; Park, C. R. Easy preparation of self-assembled high-density buckypaper with enhanced mechanical properties. Nano Lett. 2015, 15, 190-197.
DOI Google Scholar
24

Oh, J. Y.; Kim, Y. S.; Jung, Y.; Yang, S. J.; Park, C. R. Preparation and exceptional mechanical properties of bone-mimicking size-tuned graphene oxide@carbon nanotube hybrid paper. ACS Nano 2016, 10, 2184-2192.
DOI Google Scholar
25

Burtch, N. C.; Jasuja, H.; Walton, K. S. Water stability and adsorption in metal-organic frameworks. Chem. Rev. 2014, 114, 10575-10612.
DOI Google Scholar
26

Song, F. Z.; Zhu, Q. L.; Yang, X. C.; Zhan, W. W.; Pachfule, P.; Tsumori, N.; Xu, Q. Metal-organic framework templated porous carbon-metal oxide/reduced graphene oxide as superior support of bimetallic nanoparticles for efficient hydrogen generation from formic acid. Adv. Energy Mater. 2018, 8, 1701416.
DOI Google Scholar
27

Taylor, J. M.; Vaidhyanathan, R.; Iremonger, S. S.; Shimizu, G. K. H. Enhancing water stability of metal-organic frameworks via phosphonate monoester linkers. J. Am. Chem. Soc. 2012, 134, 14338-14340.
DOI Google Scholar
28

Zhang, W.; Hu, Y. L.; Ge, J.; Jiang, H. L.; Yu, S. H. A facile and general coating approach to moisture/water-resistant metal-organic frameworks with intact porosity. J. Am. Chem. Soc. 2014, 136, 16978-16981.
DOI Google Scholar
29

Xu, G. Y.; Nie, P.; Dou, H.; Ding, B.; Li, L. Y.; Zhang, X. G. Exploring metal organic frameworks for energy storage in batteries and supercapacitors. Mater. Today 2017, 20, 191-209.
DOI Google Scholar
30

Greathouse, J. A.; Allendorf, M. D. The interaction of water with MOF-5 simulated by molecular dynamics. J. Am. Chem. Soc. 2006, 128, 10678-10679.
DOI Google Scholar
31

Ming, Y.; Purewal, J.; Yang, J.; Xu, C. C.; Soltis, R.; Warner, J.; Veenstra, M.; Gaab, M.; Müller, U.; Siegel, D. J. Kinetic stability of MOF-5 in humid environments: Impact of powder densification, humidity level, and exposure time. Langmuir 2015, 31, 4988-4995.
DOI Google Scholar
32

Rodríguez, N. A.; Parra, R.; Grela, M. A. Structural characterization, optical properties and photocatalytic activity of MOF-5 and its hydrolysis products: Implications on their excitation mechanism. RSC Adv. 2015, 5, 73112-73118.
DOI Google Scholar
33

Yang, S. J.; Park, C. R. Preparation of highly moisture-resistant black-colored metal organic frameworks. Adv. Mater. 2012, 24, 4010-4013.
DOI Google Scholar
34

Tranchemontagne, D. J.; Hunt, J. R.; Yaghi, O. M. Room temperature synthesis of metal-organic frameworks: MOF-5, MOF-74, MOF-177, MOF-199, and IRMOF-0. Tetrahedron 2008, 64, 8553-8557.
DOI Google Scholar
35

Greer, H. F.; Liu, Y. H.; Greenaway, A.; Wright, P. A.; Zhou, W. Z. Synthesis and formation mechanism of textured MOF-5. Cryst. Growth Des. 2016, 16, 2104-2111.
DOI Google Scholar
36

Huang, L. M.; Wang, H. T.; Chen, J. X.; Wang, Z. B.; Sun, J. Y.; Zhao, D. Y.; Yan, Y. S. Synthesis, morphology control, and properties of porous metal-organic coordination polymers. Micropor. Mesopor. Mater. 2003, 58, 105-114.
DOI Google Scholar
37

Hausdorf, S.; Wagler, J.; Moβig, R.; Mertens, F. O. R. L. Proton and water activity-controlled structure formation in zinc carboxylate-based metal organic frameworks. J. Phys. Chem. A 2008, 112, 7567-7576.
DOI Google Scholar
38

Thirumurugan, A.; Rao, C. N. R. 1, 2-, 1, 3- and 1, 4-benzenedicarboxylates of Cd and Zn of different dimensionalities: Process of formation of the three-dimensional structure. J. Mater. Chem. 2015, 15, 3852-3858.
DOI Google Scholar
39

Müller, M.; Turner, S.; Lebedev, O. I.; Wang, Y. M.; Van Tendeloo, G.; Fischer, R. A. Au@MOF-5 and Au/MOx@MOF-5 (M = Zn, Ti; x = 1, 2): Preparation and microstructural characterisation. Eur. J. Inorg. Chem. 2011, 2011, 1876-1887.
DOI Google Scholar
40

Chen, R. Z.; Hu, Y.; Shen, Z.; Chen, Y. L.; He, X.; Zhang, X. W.; Zhang, Y. Controlled synthesis of carbon nanofibers anchored with ZnxCo3-xO4 nanocubes as binder-free anode materials for lithium-ion batteries. ACS Appl. Mater. Interfaces 2016, 8, 2591-2599.
DOI Google Scholar
41

Han, S.; Lah, M. S. Simple and efficient regeneration of MOF-5 and HKUST-1 via acid-base treatment. Cryst. Growth Des. 2015, 15, 5568-5572.
DOI Google Scholar
42

Tan, K.; Nijem, N.; Canepa, P.; Gong, Q. H.; Li, J.; Thonhauser, T.; Chabal, Y. J. Stability and hydrolyzation of metal organic frameworks with paddle-wheel SBUs upon hydration. Chem. Mater. 2012, 24, 3153-3167.
DOI Google Scholar
43

Du, J. H.; Pei, S. F.; Ma, L. P.; Cheng, H. M. 25th anniversary article: Carbon nanotube- and graphene-based transparent conductive films for optoelectronic devices. Adv. Mater. 2014, 26, 1958-1991.
DOI Google Scholar
44

Jeong, Y. C.; Kim, J. H.; Nam, S.; Park, C. R.; Yang, S. J. Rational design of nanostructured functional interlayer/separator for advanced Li-S batteries. Adv. Funct. Mater. 2018, 28, 1707411.
DOI Google Scholar
45

Shan, X. Y.; Wang, Y. Z.; Wang, D. W.; Li, F.; Cheng, H. M. Armoring graphene cathodes for high-rate and long-life lithium ion supercapacitors. Adv. Energy Mater. 2016, 6, 1502064.
DOI Google Scholar
46

Liu, B.; Shioyama, H.; Akita, T.; Xu, Q. Metal-organic framework as a template for porous carbon synthesis. J. Am. Chem. Soc. 2008, 130, 5390-5391.
DOI Google Scholar
47

Yang, S. J.; Kim, T.; Im, J. H.; Kim, Y. S.; Lee, K.; Jung, H.; Park, C. R. MOF-derived hierarchically porous carbon with exceptional porosity and hydrogen storage capacity. Chem. Mater. 2012, 24, 464-470.
DOI Google Scholar
48

Zhu, Q. L.; Xu, Q. Metal-organic framework composites, Chem. Soc. Rev. 2014, 43, 5468-5512.
DOI Google Scholar
49

Fletcher, E. A. Solarthermal and solar quasi-electrolytic processing and separations: Zinc from zinc oxide as an example. Ind. Eng. Chem. Res. 1999, 38, 2275-2282.
DOI Google Scholar
50

Wu, M. C.; Lee, C. S. Synthesis and thermal decomposition of Zn(tda)H2O[tda = S(CH2COO)22-]. Inorg. Chem. 2006, 45, 9634-9636.
DOI Google Scholar
51

Zhao, S. L.; Yin, H. J.; Du, L.; He, L. C.; Zhao, K.; Chang, L.; Yin, G. P.; Zhao, H. J.; Liu, S. Q.; Tang, Z. Y. Carbonized nanoscale metal-organic frameworks as high performance electrocatalyst for oxygen reduction reaction. ACS Nano 2014, 8, 12660-12668.
DOI Google Scholar
52

Yang, S. J.; Nam, S.; Kim, T.; Im, J. H.; Jung, H.; Kang, J. H.; Wi, S.; Park, B.; Park, C. R. Preparation and exceptional lithium anodic performance of porous carbon-coated ZnO quantum dots derived from a metal-organic framework. J. Am. Chem. Soc. 2013, 135, 7394-7397.
DOI Google Scholar
53

Liang, Z. B.; Qu, C.; Xia, D. G.; Zou, R. Q.; Xu, Q. Atomically dispersed metal sites in MOF-based materials for electrocatalytic and photocatalytic energy conversion. Angew. Chem., Int. Ed. 2018, 57, 9604-9633.
DOI Google Scholar
54

Yan, J.; Fan, Z. J.; Sun, W.; Ning, G. Q.; Wei, T.; Zhang, Q.; Zhang, R. F.; Zhi, L. J.; Wei, F. Advanced asymmetric supercapacitors based on Ni(OH)2/graphene and porous graphene electrodes with high energy density. Adv. Funct. Mater. 2012, 22, 2632-2641.
DOI Google Scholar
55

Fan, Z. J.; Yan, J.; Zhi, L. J.; Zhang, Q.; Wei, T.; Feng, J.; Zhang, M. L.; Qian, W. Z.; Wei, F. A three-dimensional carbon nanotube/graphene sandwich and its application as electrode in supercapacitors. Adv. Mater. 2010, 22, 3723-3728.
DOI Google Scholar
56

Wu, Z. S.; Ren, W. C.; Wen, L.; Gao, L. B.; Zhao, J. P.; Chen, Z. P.; Zhou, G. M.; Li, F.; Cheng, H. M. Graphene anchored with Co3O4 nanoparticles as anode of lithium ion batteries with enhanced reversible capacity and cyclic performance. ACS Nano 2010, 4, 3187-3194.
DOI Google Scholar
57

Poizot, P.; Laruelle, S.; Grugeon, S.; Dupont, L.; Tarascon, J. M. Nano-sized transition-metal oxides as negative-electrode materials for lithium-ion batteries. Nature 2000, 407, 496-499.
DOI Google Scholar
58

Li, H.; Balaya, P.; Maier, J. Li-storage via heterogeneous reaction in selected binary metal fluorides and oxides. J. Electrochem. Soc. 2004, 151, A1878-A1885.
DOI Google Scholar
59

Sun, J.; Lee, H. W.; Pasta, M.; Yuan, H. T.; Zheng, G. Y.; Sun, Y. M.; Li, Y. Z.; Cui, Y. A phosphorene-graphene hybrid material as a high-capacity anode for sodium-ion batteries. Nat. Nanotechnol. 2015, 10, 980-985.
DOI Google Scholar
60

Sakaushi, K.; Lyalin, A.; Tominaka, S.; Taketsugu, T.; Uosaki, K. Two-dimensional corrugated porous carbon-, nitrogen-framework/metal heterojunction for efficient multielectron transfer processes with controlled kinetics. ACS Nano 2017, 11, 1770-1779.
DOI Google Scholar
61

Wong, E. M.; Bonevich, J. E.; Searson, P. C. Growth kinetics of nanocrystalline ZnO particles from colloidal suspensions. J. Phys. Chem. B 1998, 102, 7770-7775.
DOI Google Scholar
62

Chmiola, J.; Yushin, G.; Gogotsi, Y.; Portet, C.; Simon, P.; Taberna, P. L. Anomalous increase in carbon capacitance at pore sizes less than 1 nanometer. Science 2006, 313, 1760-1763.
DOI Google Scholar
63

Feng, Y.; Zhang, Y. L.; Song, X. Y.; Wei, Y. Z.; Battaglia, V. S. Facile hydrothermal fabrication of ZnO-graphene hybrid anode materials with excellent lithium storage properties. Sustainable Energy Fuels 2017, 1, 767-779
DOI Google Scholar
64

Yu, S. H.; Lee, D. J.; Park, M.; Kwon, S. G.; Lee, H. S.; Jin, A. H.; Lee, K. S.; Lee, J. E.; Oh, M. H.; Kang, K. et al. Hybrid cellular nanosheets for high-performance lithium-ion battery anodes. J. Am. Chem. Soc. 2015, 137, 11954-11961.
DOI Google Scholar
65

Sun, X.; Zhou, C. G.; Xie, M.; Sun, H. T.; Hu, T.; Lu, F. Y.; Scott, S. M.; George, S. M.; Lian, J. Synthesis of ZnO quantum dot/graphene nanocomposites by atomic layer deposition with high lithium storage capacity. J. Mater. Chem. A 2014, 2, 7319-7326.
DOI Google Scholar
66

Kushima, A.; Liu, X. H.; Zhu, G.; Wang, Z. L.; Huang, J. Y.; Li, J. Leapfrog cracking and nanoamorphization of ZnO nanowires during in situ electrochemical lithiation. Nano Lett. 2011, 11, 4535-4541.
DOI Google Scholar
67

Liu, J. P.; Li, Y. Y.; Huang, X. T.; Li, G. Y.; Li, Z. K. Layered double hydroxide Nano‐ and microstructures grown directly on metal substrates and their calcined products for application as Li‐ion battery electrodes. Adv. Funct. Mater. 2008, 18, 1448-1458.
DOI Google Scholar
68

Belliard, F.; Irvine, J. T. S. Electrochemical performance of ball-milled ZnO-SnO2 systems as anodes in lithium-ion battery. J. Power Sources 2001, 97-98, 219-222.
DOI Google Scholar
69

Zhang, C. Q.; Tu, J. P.; Yuan, Y. F.; Huang, X. H.; Chen, X. T.; Mao, F. Electrochemical performances of Ni-coated ZnO as an anode material for lithium-ion batteries. J. Electrochem. Soc. 2007, 154, A65-A69.
DOI Google Scholar
70

Ahmad, M.; Shi, Y. Y.; Nisar, A.; Sun, H. Y.; Shen, W. C.; Wei, M.; Zhu, J. Synthesis of hierarchical flower-like ZnO nanostructures and their functionalization by Au nanoparticles for improved photocatalytic and high performance Li-ion battery anodes. J. Mater. Chem. 2011, 21, 7723-7729.
DOI Google Scholar
71

Nadimpalli, S. P. V.; Sethuraman, V. A.; Dalavi, S.; Lucht, B.; Chon, M. J.; Shenoy, V. B.; Guduru, P. R. Quantifying capacity loss due to solid-electrolyte-interphase layer formation on silicon negative electrodes in lithium-ion batteries. J. Power Sources 2012, 215, 145-151.
DOI Google Scholar
72

An, S. J.; Li, J. L.; Du, Z. J.; Daniel, C.; Wood Ⅲ, D. L. Fast formation cycling for lithium ion batteries. J. Power Sources 2017, 342, 846-852.
DOI Google Scholar
73

Xia, F.; Kwon, S.; Lee, W. W.; Liu, Z. M.; Kim, S.; Song, T.; Choi, K. J.; Paik, U.; Park, W. I. Graphene as an interfacial layer for improving cycling performance of Si nanowires in lithium-ion batteries. Nano Lett. 2015, 15, 6658-6664.
DOI Google Scholar
74

Su, Q. M.; Dong, Z. M.; Zhang, J.; Du, G. H.; Xu, B. S. Visualizing the electrochemical reaction of ZnO nanoparticles with lithium by in situ TEM: Two reaction modes are revealed. Nanotechnology 2013, 24, 255705
DOI Google Scholar
75

Balaya, P.; Li, H.; Kienle, L.; Maier, J. Fully reversible homogeneous and heterogeneous Li storage in RuO2 with high capacity. Adv. Funct. Mater. 2003, 13, 621-625.
DOI Google Scholar
76

Chen, C. C.; Maier, J. Decoupling electron and ion storage and the path from interfacial storage to artificial electrodes. Nat. Energy 2018, 3, 102-108.
DOI Google Scholar
77

Bekaert, E.; Balaya, P.; Murugavel, S.; Maier, J.; Ménétrier, M. 6Li MAS NMR investigation of electrochemical lithiation of RuO2: Evidence for an interfacial storage mechanism. Chem. Mater. 2009, 21, 856-861.
DOI Google Scholar
78

Kim, J. H.; Byeon, M.; Jeong, Y. C.; Oh, J. Y.; Jung, Y.; Fechler, N.; Yang, S. J.; Park, C. R. Morphochemical imprinting of melamine cyanurate mesocrystals in glucose-derived carbon for high performance lithium ion batteries. J. Mater. Chem. A 2017, 5, 20635-20642.
DOI Google Scholar
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Acknowledgements

Publication history

Received: 03 April 2019
Revised: 22 May 2019
Accepted: 05 June 2019
Published: 06 July 2019
Issue date: August 2019

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© Tsinghua University Press and Springer-Verlag GmbH Germany, part of Springer Nature 2019

Acknowledgements

Acknowledgements

This work was supported by Inha University Research Grant.

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