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In this work, homogeneous Ni0.33Co0.67Se hollow nanoprisms were synthesized successfully in virtue of Kirkendall effect. It is the first time for bimetallic Ni-Co compounds Ni0.33Co0.67Se to be used in lithium-ion batteries (LIBs). Impressively, the Ni0.33Co0.67Se hollow nanoprisms show superior specific capacity (1, 575 mAh/g at the current density of 100 mA/g) and outstanding rate performance (850 mAh/g at 2, 000 mA/g) as anode material for LIBs. This work proves the potential of bimetallic chalcogenide compounds as high performance anode materials for LIBs.
This work was supported by the National Natural Science Foundation of China (Nos. 51425204, 51521001, and 51602239), the National Key R & D Program of China (No. 2016YFA0202603), the Program of Introducing Talents of Discipline to Universities (No. B17034), the Yellow Crane Talent (Science & Technology) Program of Wuhan City, and the International Science & Technology Cooperation Program of China (No. 2013DFA50840).