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Catalytic hydrogenation is an important process in the chemical industry. Traditional catalysts require the effective cleavage of hydrogen molecules on the metal-catalyst surface, which is difficult to achieve with non-noble metal catalysts. In this work, we report a new hydrogenation method based on water/proton reduction, which is completely different from the catalytic cleavage of hydrogen molecules. Active hydrogen species and photo-generated electrons can be directly applied to the hydrogenation process with Cu1.94S-Zn0.23Cd0.77S semiconductor heterojunction nanorods. Nitrobenzene, with a variety of substituent groups, can be efficiently reduced to the corresponding aniline without the addition of hydrogen gas. This is a novel and direct pathway for hydrogenation using non-noble metal catalysts.

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Publication history
Copyright
Acknowledgements

Publication history

Received: 27 September 2017
Revised: 27 September 2017
Accepted: 30 November 2017
Published: 02 August 2018
Issue date: July 2018

Copyright

© Tsinghua University Press and Springer-Verlag GmbH Germany, part of Springer Nature 2017

Acknowledgements

Acknowledgements

We thank the National Natural Science Foundation of China for support (Nos. 21325101, 21231005, and 21171105) and China Ministry of Science and Technology under Contract of 2016YFA (No. 0202801).

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