Bimetallic PdCo catalyst for selective direct formylation of amines by carbon monoxide

Yifeng Chen; Junjie Mao; Rongan Shen; Dingsheng Wang; Qing Peng; Zhixin Yu; Huifang Guo; Wei He

doi:10.1007/s12274-016-1344-y

Nano Research 2017, 10(3): 890-896 https://doi.org/10.1007/s12274-016-1344-y

Research Article | Issue | Published: 19 November 2016

Bimetallic PdCo catalyst for selective direct formylation of amines by carbon monoxide

Show Author's Information Hide Author's Information Yifeng Chen^¹, Junjie Mao^², Rongan Shen^², Dingsheng Wang^², Qing Peng^², Zhixin Yu^³, Huifang Guo^{¹^,^†}(

), Wei He^¹(

)

1School of Pharmaceutical SciencesTsinghua UniversityBeijing

100084

China

2Department of ChemistryTsinghua UniversityBeijing

100084

China

3Department of Petroleum EngineeringUniversity of StavangerStavanger

4036

Norway

^† Present address: Institute of Medicinal Biotechnology, Chinese Academy of Medical Sciences & Peking Union Medical College, Beijing 100050, China

Keywords:

nanoparticle, carbon monoxide, bimetallic, amines, formylation

Cite this article:

Chen Y, Mao J, Shen R, et al. Bimetallic PdCo catalyst for selective direct formylation of amines by carbon monoxide. Nano Research, 2017, 10(3): 890-896. https://doi.org/10.1007/s12274-016-1344-y

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Abstract Electronic supplementary material About this article

Abstract

A highly efficient and selective bimetallic Pd_0.88Co_0.12 nanoparticle catalyst was developed for the direct N-formylation of amines by carbon monoxide. This catalyst is compatible with a wide range of substrates, affording various synthetically useful formamides under practical and mild reaction conditions.

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Acknowledgements

Publication history

Received: 08 October 2016

Accepted: 19 October 2016

Published: 19 November 2016

Issue date: March 2017

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Acknowledgements

We acknowledge financial support from the China Ministry of Science and Technology (No. 2016YFA0202801), National Natural Science Foundation of China (No. 21371107), Tsinghua-Peking Joint Centers for Life Sciences and CAMS Initiative for Innovative Medicine (No. 2016-I2M-3-014).