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Research Article

Bimetallic PdCo catalyst for selective direct formylation of amines by carbon monoxide

Yifeng Chen1, Junjie Mao2, Rongan Shen2, Dingsheng Wang2, Qing Peng2, Zhixin Yu3, Huifang Guo1,†( ), Wei He1( )
School of Pharmaceutical SciencesTsinghua UniversityBeijing100084China
Department of ChemistryTsinghua UniversityBeijing100084China
Department of Petroleum EngineeringUniversity of StavangerStavanger4036Norway

† Present address: Institute of Medicinal Biotechnology, Chinese Academy of Medical Sciences & Peking Union Medical College, Beijing 100050, China

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Abstract

A highly efficient and selective bimetallic Pd0.88Co0.12 nanoparticle catalyst was developed for the direct N-formylation of amines by carbon monoxide. This catalyst is compatible with a wide range of substrates, affording various synthetically useful formamides under practical and mild reaction conditions.

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nanoparticleformylationaminescarbon monoxidebimetallic

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Nano Research
Volume 10 Issue 3,
March 2017
Pages 890-896
DOI: 10.1007/s12274-016-1344-y

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Cite this article:
Chen Y, Mao J, Shen R, et al. Bimetallic PdCo catalyst for selective direct formylation of amines by carbon monoxide. Nano Research, 2017, 10(3): 890-896. https://doi.org/10.1007/s12274-016-1344-y

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Received: 08 October 2016
Accepted: 19 October 2016
Published: 19 November 2016
© Tsinghua University Press and Springer-Verlag Berlin Heidelberg 2016