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Nano Research 2016, 9(11): 3181-3208 https://doi.org/10.1007/s12274-016-1230-7
Review Article | Issue | Published: 01 September 2016

Coordination polymers: Challenges and future scenarios for capture and degradation of volatile organic compounds

Show Author's Information Kowsalya Vellingiri1,  Pawan Kumar2,  Ki-Hyun Kim1( )
Department of Civil and Environmental EngineeringHanyang University222 Wangsimni-RoSeoul04763Republic of Korea
Department of Nano Sciences and MaterialsCentral University of JammuJammu181143India
Keywords:
coordination polymers/metal organic frameworks (CPs/MOFs), volatile organic compounds, sorptive removal, catalytic degradation
Cite this article:
Vellingiri K, Kumar P, Kim K-H. Coordination polymers: Challenges and future scenarios for capture and degradation of volatile organic compounds. Nano Research, 2016, 9(11): 3181-3208. https://doi.org/10.1007/s12274-016-1230-7
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Abstract Full text About this article

Over the past few decades, coordination polymers/metal organic frameworks (CPs/MOFs) have drawn a great deal of attention for diverse applications due to their advantages of intrinsically tunable chemical structure, flexible architecture, high pore volume, high surface area, multifunctional properties, etc. To date, numerous CPs/MOFs have been developed and employed for the treatment and control of gaseous pollutants, such as volatile organic compounds (VOCs), through capture, sorptive removal, and catalytic degradation. Nevertheless, there are also some key drawbacks and challenges for the practical application of these systems (e.g., poor selectivity, high energy (and fiscal) cost, high synthesis cost, low capacity, and difficulties in regeneration and recycling). In this review, recent developments in CPs/MOFs research are described with their associated mechanisms for capture, sorptive removal, and catalytic degradation of VOCs. To this end, we discuss the key variables and challenges for afforded abatement of VOCs through CPs/MOFs technologies. Hopefully, this review will help the scientific community set future directions for the advancement of CPs/MOFs techniques for the effective management of diverse environmental issues.


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About this article

Coordination polymers: Challenges and future scenarios for capture and degradation of volatile organic compounds

Show Author's information Kowsalya Vellingiri1, Pawan Kumar2, Ki-Hyun Kim1( )
Department of Civil and Environmental EngineeringHanyang University222 Wangsimni-RoSeoul04763Republic of Korea
Department of Nano Sciences and MaterialsCentral University of JammuJammu181143India

Abstract

Over the past few decades, coordination polymers/metal organic frameworks (CPs/MOFs) have drawn a great deal of attention for diverse applications due to their advantages of intrinsically tunable chemical structure, flexible architecture, high pore volume, high surface area, multifunctional properties, etc. To date, numerous CPs/MOFs have been developed and employed for the treatment and control of gaseous pollutants, such as volatile organic compounds (VOCs), through capture, sorptive removal, and catalytic degradation. Nevertheless, there are also some key drawbacks and challenges for the practical application of these systems (e.g., poor selectivity, high energy (and fiscal) cost, high synthesis cost, low capacity, and difficulties in regeneration and recycling). In this review, recent developments in CPs/MOFs research are described with their associated mechanisms for capture, sorptive removal, and catalytic degradation of VOCs. To this end, we discuss the key variables and challenges for afforded abatement of VOCs through CPs/MOFs technologies. Hopefully, this review will help the scientific community set future directions for the advancement of CPs/MOFs techniques for the effective management of diverse environmental issues.

Keywords: coordination polymers/metal organic frameworks (CPs/MOFs), volatile organic compounds, sorptive removal, catalytic degradation

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Publication history
Copyright
Acknowledgements

Publication history

Received: 06 July 2016
Revised: 23 July 2016
Accepted: 24 July 2016
Published: 01 September 2016
Issue date: November 2016

Copyright

© Tsinghua University Press and Springer-Verlag Berlin Heidelberg 2016

Acknowledgements

Acknowledgements

The corresponding author (K. H. K.) acknowledges support from a National Research Foundation of Korea (NRF) grant funded by the Ministry of Education, Science and Technology (MEST) (No. 2006-0093848) and from the Cooperative Research Program for Agriculture Science & Technology Development (Project title: Study on model development to control odor from hog barn, Project No. PJ010521), Rural Development Administration, Republic of Korea. P. K. also wants to thank the Science and Engineering Research Board (SERB), New Delhi, for funding the Start Research Grant (Young Scientist).

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