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Two-dimensional nanomaterials (2DNMs) have attracted increasing attention due to their unique properties and promising applications. Unlike 2DNMs with lamellar structures, metal ultrathin 2DNMs are difficult to synthesize and stabilize because they tend to form close-packed crystal structures. Most reported cases consist of monometallic and heterogeneous nanostructures. The synthesis of metal alloy 2DNMs has been rarely reported. Here, we report the synthesis of PdNi alloy wavy nanosheets (WNSs) using an enhanced CO-confinement strategy. This strategy is also suitable to the synthesis of other Pd-based alloy WNSs such as PdCu, PdFe, and even a trimetallic PdFeNi.


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Free-standing palladium-nickel alloy wavy nanosheets

Show Author's information Weng-Chon CheongChuhao LiuMenglei JiangHaohong DuanDingsheng WangChen Chen( )Yadong Li( )
Department of Chemistry and Collaborative Innovation Center for Nanomaterials Science and EngineeringTsinghua UniversityBeijing100084China

Abstract

Two-dimensional nanomaterials (2DNMs) have attracted increasing attention due to their unique properties and promising applications. Unlike 2DNMs with lamellar structures, metal ultrathin 2DNMs are difficult to synthesize and stabilize because they tend to form close-packed crystal structures. Most reported cases consist of monometallic and heterogeneous nanostructures. The synthesis of metal alloy 2DNMs has been rarely reported. Here, we report the synthesis of PdNi alloy wavy nanosheets (WNSs) using an enhanced CO-confinement strategy. This strategy is also suitable to the synthesis of other Pd-based alloy WNSs such as PdCu, PdFe, and even a trimetallic PdFeNi.

Keywords: Pd, nanosheets, alloy, carbon monoxide, Ni

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Acknowledgements

Publication history

Received: 11 March 2016
Revised: 16 April 2016
Accepted: 18 April 2016
Published: 01 June 2016
Issue date: August 2016

Copyright

© Tsinghua University Press and Springer-Verlag Berlin Heidelberg 2016

Acknowledgements

Acknowledgements

This work was supported by the National Natural Science Foundation of China (Nos. 21573119, 21590792, 21521091, 21131004, 21390393, and U1463202).

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