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Research Article

Porous ternary complex metal oxide nanoparticles converted from core/shell nanoparticles

Jaewon Lee2, Huazhang Zhu3, Gautam Ganapati Yadav2,†, James Caruthers2, Yue Wu1,3 ( )
School of Chemical and Environmental EngineeringShanghai Institute of TechnologyShanghai200235China
School of Chemical EngineeringPurdue University, 480 Stadium Mall Drive, West LafayetteIN47907USA
Department of Chemical and Biological EngineeringIowa State University, Sweeney Hall, AmesIA50011USA

† Present address: Energy Institute, City College of New York, New York, NY 10031, USA

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Abstract

We demonstrate an easy and scalable low-temperature process to convert porous ternary complex metal oxide nanoparticles from solution-synthesized core/shell metal oxide nanoparticles by thermal annealing. The final products demonstrate superior electrochemical properties with a large capacity and high stability during fast charging/discharging cycles for potential applications as advanced lithium-ion battery (LIB) electrode materials. In addition, a new breakdown mechanism was observed on these novel electrode materials.

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Keywords

ternary complex metal oxideporousnanoparticlelithium-ion batterycore/shell nanoparticles

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Nano Research
Volume 9 Issue 4,
April 2016
Pages 996-1004
DOI: 10.1007/s12274-016-0987-z

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Cite this article:
Lee J, Zhu H, Yadav GG, et al. Porous ternary complex metal oxide nanoparticles converted from core/shell nanoparticles. Nano Research, 2016, 9(4): 996-1004. https://doi.org/10.1007/s12274-016-0987-z

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Received: 04 November 2015
Revised: 10 December 2015
Accepted: 18 December 2015
Published: 23 February 2016
© Tsinghua University Press and Springer-Verlag Berlin Heidelberg 2016