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The sluggish oxygen evolution reaction (OER) is an important half-reaction of the electrochemical water-splitting reaction. Amorphous Fe/Ni composite oxides have high activity. In this work, we modified the aerosol spray-assisted approach and obtained amorphous Fe-Ni-O x solid-solution nanoparticles (Fe-Ni-O x -NPs) approximately 20 nm in size by choosing iron/nickel acetylacetonates as raw materials instead of inorganic salts. The small-sized Fe-Ni-O x -NPs were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD) analysis, energy-dispersive X-ray spectroscopy (EDX), and X-ray photoelectron spectroscopy (XPS). Furthermore, an investigation of electrochemical OER performance suggests that the small-sized Fe-Ni-O x -NPs have higher activity than the large-sized Fe-Ni-O x -MPs. A small overpotential of 0.315 V was demanded to obtain a working current density of 50 mA/cm2, and the Tafel slope was as low as 38 mV/dec.
This work was supported by the National Natural Science Foundation of China (Nos. 21271009 and 21471006), the Doctoral Fund of the Ministry of Education of China (No. 20123424110002), the National Undergraduate Training Programs for Innovation and Entrepreneurship (No. 201410370043), and the Programs for Science and Technology Development of Anhui Province (No. 1501021019).