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Research Article

Monodisperse core-shell structured magnetic mesoporous aluminosilicate nanospheres with large dendritic mesochannels

Jianping Yang1,2,3Dengke Shen2,4Yong Wei2Wei Li2Fan Zhang2Biao Kong2Shaohua Zhang3Wei Teng1Jianwei Fan1Weixian Zhang1( )Shixue Dou3Dongyuan Zhao2( )
College of Environmental Science and EngineeringState Key Laboratory of Pollution Control and Resources ReuseTongji UniversityShanghai200092China
Department of ChemistryShanghai Key Laboratory of Molecular Catalysis and Laboratory of Advanced MaterialsFudan UniversityShanghai200433China
Institute for Superconducting & Electronic MaterialsAustralian Institute of Innovative MaterialsUniversity of WollongongInnovation CampusSquires WayNorth WollongongNSW2500Australia
Key Laboratory of Materials PhysicsCentre for Environmental and Energy NanomaterialsAnhui Key Laboratory of Nanomaterials and NanotechnologyInstitute of Solid State PhysicsHefei Institutes of Physical ScienceChinese Academy of SciencesHefei230031China
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Abstract

The rational design and precise synthesis of multifunctional hybrid nanostructures with a tailored active core and a large, dendritic, modified mesoporous structured shell can promote catalysis, energy storage, and biological applications. Here, an oil-water biphase stratification coating strategy has been developed to prepare monodisperse magnetic dendritic mesoporous silica core-shell structured nanospheres. These sophisticated Fe3O4@SiO2@dendritic-mSiO2 nanospheres feature large dendritic open pores (2.7 and 10.3 nm). Significantly, the silica shells can be converted into dendritic mesoporous aluminosilicate frameworks with unchanged porosity, a Si/Al molar ratio of 14, and remarkably strong acidic sites, through a post-synthesis approach. In addition, the resultant magnetic dendritic mesoporous aluminosilicate nanospheres exhibit outstanding properties and promising application in phosphate removal from wastewater.

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Nano Research
Pages 2503-2514
Cite this article:
Yang J, Shen D, Wei Y, et al. Monodisperse core-shell structured magnetic mesoporous aluminosilicate nanospheres with large dendritic mesochannels. Nano Research, 2015, 8(8): 2503-2514. https://doi.org/10.1007/s12274-015-0758-2

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Received: 22 January 2015
Revised: 17 February 2015
Accepted: 01 March 2015
Published: 29 August 2015
© Tsinghua University Press and Springer-Verlag Berlin Heidelberg 2015
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