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We demonstrate the hydrothermal synthesis of long copper nanowires based on a simple protocol. We show that the purification of the nanowires is very important and can be achieved easily by wet treatment with glacial acetic acid. Fabrication of random networks of purified copper nanowires leads to flexible transparent electrodes with excellent optoelectronic performances (e.g., 55 Ω/sq. at 94% transparency). The process is carried out at room temperature and no post-treatment is necessary. Hybrid materials with the conductive polymer PEDOT: PSS show similar properties (e.g., 46 Ω/sq. at 93% transparency), with improved mechanical properties. Both electrodes were integrated in capacitive touch sensors.


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Synthesis and purification of long copper nanowires. Application to high performance flexible transparent electrodes with and without PEDOT: PSS

Show Author's information Céline MayousseCaroline CelleAlexandre CarellaJean-Pierre Simonato( )
CEA, LITEN / DTNM / LCRE 17 rue des MartyrsGrenoble 38054 France

Abstract

We demonstrate the hydrothermal synthesis of long copper nanowires based on a simple protocol. We show that the purification of the nanowires is very important and can be achieved easily by wet treatment with glacial acetic acid. Fabrication of random networks of purified copper nanowires leads to flexible transparent electrodes with excellent optoelectronic performances (e.g., 55 Ω/sq. at 94% transparency). The process is carried out at room temperature and no post-treatment is necessary. Hybrid materials with the conductive polymer PEDOT: PSS show similar properties (e.g., 46 Ω/sq. at 93% transparency), with improved mechanical properties. Both electrodes were integrated in capacitive touch sensors.

Keywords: transparent electrodes, copper nanowires, PEDOT: PSS, touch sensor, metallic nanowires

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Publication history
Copyright
Acknowledgements

Publication history

Received: 18 October 2013
Revised: 28 November 2013
Accepted: 10 December 2013
Published: 13 January 2014
Issue date: March 2014

Copyright

© Tsinghua University Press and Springer-Verlag Berlin Heidelberg 2013

Acknowledgements

Acknowledgements

This work was funded by DGA (French Ministry of Defense) through a PhD grant to CM.

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