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A highlight on reshaping aqueous electrolyte solvation structure for high-energy batteries is provided. Firstly, the recent key design routes for regulating solvation structure to widen electrochemical stability window (ESW) of aqueous electrolyte are briefly summarized. Then, the groundbreaking work of Wang et al. on reshaping electrolyte structure using urea as the diluent is elaborated. Finally, the significance of Wang’s work is highlighted.
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