{Reference Type}: Journal Article {Title}: Development of calcium stabilized nitrogen rich α-sialon ceramics along the Si3N4:1/2Ca3N2:3AlN line using spark plasma sintering {Author}: AHMED, B. A.; LAOUI, T.; A. S., HAKEEM {Journal}: Journal of Advanced Ceramics {ISBN/ISSN}: 2226-4108 {Year}: 2020 {Volume}: 9 {Issue}: 5 {Pages}: 606-616 {DOI}: 10.1007/s40145-020-0400-y {Keywords}: spark plasma sintering (SPS) {Keywords}: nitrogen rich sialon ceramics {Keywords}: α-sialon {Keywords}: calcium sialons {Keywords}: liquid phase sintering {Abstract}: Calcium stabilized nitrogen rich sialon ceramics having a general formula of CaxSi12-2xAl2xN16 with x value (x is the solubility of cation Ca in α-sialon structure) in the range of 0.2-2.2 for compositions lying along the Si3N4:1/2Ca3N2:3AlN line were synthesized using nano/submicron size starting powder precursors and spark plasma sintering (SPS) technique. The development of calcium stabilized nitrogen rich sialon ceramics at a significantly low sintering temperature of 1500 ℃ (typically reported a temperature of 1700 ℃ or greater) remains to be the highlight of the present study. The SPS processed sialons were characterized for their microstructure, phase and compositional analysis, and physical and mechanical properties. Furthermore, a correlation was developed between the lattice parameters and the content (x) of the alkaline metal cation in the α-sialon phase. Well-densified single-phase nitrogen rich α-sialon ceramics were achieved in the range of 0.53(3) ≤ x ≤ 1.27(3). A nitrogen rich α-sialon sample possessing a maximum hardness of 22.4 GPa and fracture toughness of 6.1 MPa·m1/2 was developed. {URL}: https://www.sciopen.com/article/10.1007/s40145-020-0400-y {Language}: en