TY - JOUR AU - Lv, Chunlin AU - Cheng, Hao AU - He, Wei AU - Shah, Muhammad Ishaq Ali AU - Xu, Congqiao AU - Meng, Xiangjian AU - Jiao, Lei AU - Wei, Shiqiang AU - Li, Jun AU - Liu, Lei AU - Li, Yadong PY - 2016 TI - Pd3 cluster catalysis: Compelling evidence from in operando spectroscopic, kinetic, and density functional theory studies JO - Nano Research SN - 1998-0124 SP - 2544 EP - 2550 VL - 9 IS - 9 AB - Identification of metal cluster catalysis is a topic that is being investigated since a long time. Here, we report a Pd3 metal cluster catalytic reaction investigated by means of operando studies. We discovered that atomically defined tri-nuclear palladium (Pd3) is a surprisingly active catalyst for the cycloisomerization of 2-phenylethynylaniline. Operando 1H NMR spectroscopy and X-ray extended absorption fine structure (EXAFS) measurements have indicated that the structural integrity of such a catalyst remains intact throughout the reaction, which has also been confirmed by an ex situ X-ray photoelectron spectroscopy (XPS) study and catalyst recycling experiments. Kinetic data derived from operando IR spectroscopy measurements have shown that Pd3 is the active catalytic species. Density functional theory calculations have revealed a reaction pathway consistent with the kinetic data, further supported by NMR titration and X-ray crystal structure studies. Overall, the present study presents a clear example of metal cluster catalysis. UR - https://doi.org/10.1007/s12274-016-1140-8 DO - 10.1007/s12274-016-1140-8