@article{Wang2026, 
author = {Ying Wang and Bo Yang and Hanqing Yu and Dingxin Shuai and Xiuqiong Hu and Ying Zhang and Jiyue Hou and Yiyong Zhang},
title = {3D porous carbon gel composite with transition metal particles for anchoring-diffusion-conversion of polysulfides for lithium–sulfur batteries},
year = {2026},
journal = {Journal of Materiomics},
volume = {12},
number = {2},
keywords = {Lithium–sulfur (Li–S) batteries, Gel technology, Catalytic conversion, Shuttling effect},
url = {https://www.sciopen.com/article/10.1016/j.jmat.2025.101156},
doi = {10.1016/j.jmat.2025.101156},
abstract = {Lithium-sulfur batteries (LSBs) exhibit high energy density and high theoretical specific capacity, approximately one order of magnitude higher than traditional lithium-ion batteries. However, the shuttling effect of lithium polysulfides (LiPSs) generated during the charge-discharge process severely compromises battery performance and hinders commercialization. In this paper, a 3D porous carbon gel sulfur host, M@rGO–PCG (M = Ni, Co), composed of transition metal particles and redox graphene, was fabricated through gelation and freeze-drying techniques. This material enhances the conductivity of the cathode, buffers the volume expansion of the electrode, and further accelerates the catalytic conversion of LiPSs. The assembled Ni@rGO–PCG/S and Co@rGO–PCG/S batteries deliver initial discharge specific capacities of 1390.0 mA·h·g−1 and 1603.6 mA·h·g−1 at a current rate of 0.1C, respectively. The findings provide valuable insights into the synergistic suppression of the shuttling effect through multiple functions.}
}