TY  - JOUR
AU  - Wang, Ying
AU  - Yang, Bo
AU  - Yu, Hanqing
AU  - Shuai, Dingxin
AU  - Hu, Xiuqiong
AU  - Zhang, Ying
AU  - Hou, Jiyue
AU  - Zhang, Yiyong
PY  - 2026
TI  - 3D porous carbon gel composite with transition metal particles for anchoring-diffusion-conversion of polysulfides for lithium–sulfur batteries
JO  - Journal of Materiomics
SN  - 2352-8478
VL  - 12
IS  - 2
AB  - Lithium-sulfur batteries (LSBs) exhibit high energy density and high theoretical specific capacity, approximately one order of magnitude higher than traditional lithium-ion batteries. However, the shuttling effect of lithium polysulfides (LiPSs) generated during the charge-discharge process severely compromises battery performance and hinders commercialization. In this paper, a 3D porous carbon gel sulfur host, M@rGO–PCG (M = Ni, Co), composed of transition metal particles and redox graphene, was fabricated through gelation and freeze-drying techniques. This material enhances the conductivity of the cathode, buffers the volume expansion of the electrode, and further accelerates the catalytic conversion of LiPSs. The assembled Ni@rGO–PCG/S and Co@rGO–PCG/S batteries deliver initial discharge specific capacities of 1390.0 mA·h·g−1 and 1603.6 mA·h·g−1 at a current rate of 0.1C, respectively. The findings provide valuable insights into the synergistic suppression of the shuttling effect through multiple functions.
UR  - https://doi.org/10.1016/j.jmat.2025.101156
DO  - 10.1016/j.jmat.2025.101156