@article{Huang2026, 
author = {Kun Huang and Zi-Yuan Wang and Chong-Yu Wang and Yi-Xin Zhang and Ye-Hua Jiang and Jing Feng and Zhen-Hua Ge},
title = {Structural evolution-driven enhancement of thermoelectric performance in Bi–S–Se solid solutions},
year = {2026},
journal = {Journal of Advanced Ceramics},
volume = {15},
number = {2},
pages = {9221239},
keywords = {thermoelectric material, functional ceramics, structural evolution, Bi2S3},
url = {https://www.sciopen.com/article/10.26599/JAC.2026.9221239},
doi = {10.26599/JAC.2026.9221239},
abstract = {Bismuth sulfide (Bi2S3) has garnered extensive attention for thermoelectric (TE) applications due to its earth abundance, nontoxicity, and ultralow lattice thermal conductivity. However, simultaneously improving its electrical and thermal properties remains challenging due to the strong coupling between these parameters. Herein, we propose a structural evolution strategy to synergistically optimize the electrical and thermal transport properties of Bi2S3-based TE compounds. By leveraging the distinct crystal structures of Bi2S3 and Bi2Se3, alloying Se at S sites successfully reconstructs the carrier transport channels within the Bi2S3 matrix, thereby facilitating carrier mobility. Additionally, the weakened chemical bonding leads to a significant increase in carrier concentration, approaching the optimal range. Furthermore, the structural evolution from particle-like to lamellar grains, coupled with the large mass difference between Se and S, induces lattice distortion that effectively reduces the lattice thermal conductivity. Combining the dramatically enhanced power factor and ultralow thermal conductivity, an optimized figure of merit (ZT) of 0.38 at 623 K is achieved in the Bi2SSe2 solid solution. This structural evolution strategy offers a promising avenue for enhancing the TE performance of binary compounds.}
}