@article{Wang2026, 
author = {Zhongqi Wang and Shuibin Wang and Han Fei and Tianxing Jiang and Bo Feng and Qingbo Wen and Xiang Xiong},
title = {Atomic-scale elucidation of attenuation mechanisms underlying exceptional electromagnetic wave absorption of SiZrBCN ceramic nanocomposites},
year = {2026},
journal = {Journal of Advanced Ceramics},
volume = {15},
number = {1},
pages = {9221221},
keywords = {polymer-derived ceramics, polarization loss, microstructure, electromagnetic wave absorption, density functional theory},
url = {https://www.sciopen.com/article/10.26599/JAC.2025.9221221},
doi = {10.26599/JAC.2025.9221221},
abstract = {To elucidate the atomic-scale mechanisms governing electromagnetic wave (EMW) attenuation in polymer-derived ceramics, a SiZrBCN ceramic nanocomposite was prepared via chemical modification of polyborosilazane with tetrakis(dimethylamino)zirconium(IV), followed by pyrolysis and annealing. Advanced characterization methods combined with first-principles calculations via density functional theory (DFT) were employed to investigate the structural evolution, dielectric properties, and attenuation mechanisms of the nanocomposites. The results show that after pyrolysis at T ≤ 1400 °C, the SiZrBCN is in an amorphous state. As the annealing temperature increases, ZrCxN1−x, SiC, and β-Si3N4 initially precipitate at 1500 °C. When the temperature increases to 1800 °C, ZrCxN1−x transforms into ZrB2, forming SiC/ZrB2 multiphase ceramic nanocomposites. With the incorporation of Zr, SiZrBCN-16, after annealing at 1600 °C, exhibits excellent EMW absorption performance, achieving a maximum effective absorption bandwidth of 6.03 GHz (thickness: 1.65 mm) and a minimum reflection loss of −44.1 dB (thickness: 1.9 mm). In addition to the conductive loss caused by the free carbon network, DFT analysis revealed two primary dielectric loss mechanisms that result in exceptional absorbing performance: (1) Electronegativity-driven charge separation in ZrCxN1−x solid solutions facilitates the formation of electric dipoles; (2) interfacial lattice distortion and atomic disparity across the interface at the ZrC(001)/β-Si3N4(001) and ZrN(100)/SiC(110) boundaries induce electronic reconstruction and charge separation.}
}