@article{Zhao2025, 
author = {Ning Zhao and Ningning Zhang and Kaiwei Liu and Shufen Liu and Yinghui Wang and Ran Jia and Yuxin Dai and Mei Xue and Gang Zhao},
title = {Hierarchical structure based on Fe, Mo co-doped Ni3S2 and NiFe LDH: Dual-anode boosting efficient hydrogen evolution},
year = {2025},
journal = {Nano Research Energy},
volume = {4},
pages = {e9120206},
keywords = {hydrogen evolution reaction, heteroatom doping, DFT calculations, hierarchical structure, urea oxidation reaction, trifunctional electrocatalyst},
url = {https://www.sciopen.com/article/10.26599/NRE.2025.9120206},
doi = {10.26599/NRE.2025.9120206},
abstract = {Hydrogen energy serves as a secondary energy carrier, and water electrolysis for hydrogen production is a core development direction. By combining the cathode hydrogen evolution reaction (HER) with the dual anode reactions—oxygen evolution reaction (OER) and urea oxidation reaction (UOR), it simultaneously achieves mainstream alkaline electrolytic hydrogen production and urea treatment. Here, Ni3S2(Fe, Mo)-NiFe LDH, a trifunctional electrocatalyst, is prepared via a two-step hydrothermal method. Density functional theory (DFT) calculations confirmed that co-doping with Mo and Fe optimizes Gibbs free energy of hydrogen adsorption  (ΔGH∗) of Ni3S2. The doping-modulated Ni3S2(Fe, Mo) and NiFe LDH form a hierarchical structure, not only achieving performance complementarity but also further enhancing the overall catalytic activity through interfacial electronic interactions. At 10 mA·cm–2, the HER overpotential is 91 mV, and the UOR overpotential is 74 mV, which is a reduction of 154 mV compared to OER (228 mV). Moreover, the constructed HER‖OER (HER‖UOR) electrolyzer operates at a voltage as low as 1.55 V (1.41 V), along with 100 h stability.}
}