@article{Chen2025, 
author = {Min Chen and Lei Zhang and Yongping Pu and Fangping Zhuo and Jing Shang and Yu Shi and Hongliang Du},
title = {Stabilization mechanism of antiferroelectric Pnma phase and low-field reversible phase transition in sodium niobate-based ceramics},
year = {2025},
journal = {Journal of Advanced Ceramics},
volume = {14},
number = {10},
pages = {9221170},
keywords = {phase transition, antiferroelectrics (AFE), low-field, sodium niobate (NaNbO3, NN)},
url = {https://www.sciopen.com/article/10.26599/JAC.2025.9221170},
doi = {10.26599/JAC.2025.9221170},
abstract = {The stabilization mechanism of antiferroelectric (AFE) phases in sodium niobate (NaNbO3, NN) ceramics remains unclear, leading to irreversible AFE–ferroelectric (FE) phase transitions and the need for a high operating electric field (E-field), which significantly limits the utilization of AFE properties. In this work, leveraging insights from density functional theory calculations, we design and fabricate xBi2/3SnO3–(1−x)NaNbO3 ceramics, overcoming these limitations by achieving both a reversible AFE–FE phase transition and a low operating field (< 200 kV/cm). Notably, the optimized composition results in exceptionally low remanent polarization compared with that of conventional AFE systems. Structural analysis reveals a three-stage phase evolution with increasing x: FE Q phase (Pmc21, Glazer tilt system: a−a−b+) + AFE P phase (Pbcm, Glazer tilt system: a−a−b+/a−a−b−) (x < 0.02) → pure AFE P phase (x = 0.02) → coexistence of AFE P phase + AFE R phase (0.02 < x < 0.08). The AFE P phase is characterized by a periodically arranged 4-layer multicell structure (~1.65 nm) that is disrupted by 6-layer antiphase boundaries (APBs, ~2.44 nm), which are associated with the dislocation formation and a large energy difference between the P and Q phases (7.20 meV/(f.u.)). These features likely contribute to a reduced domain size and a lower field-induced AFE → FE transition. Furthermore, the stabilization of the AFE R phase is caused primarily by a reduction in the distortion index (from 0.047 to 0.003) and enhanced covalency in A–O and B–O bonds. This study provides new insights and theoretical guidance for the development of low-field-driven reversible phase transitions in AFEs.}
}