@article{Li2025, 
author = {Yurui Li and Zheng Li and Jing Li and Tianfu Liu and Hongjin Lv and Guo-Yu Yang},
title = {Decatungstate-based photocatalysts for organic transformations},
year = {2025},
journal = {Polyoxometalates},
volume = {4},
number = {4},
pages = {9140101},
keywords = {photocatalysis, polyoxometalates, organic transformation, decatungstate},
url = {https://www.sciopen.com/article/10.26599/POM.2025.9140101},
doi = {10.26599/POM.2025.9140101},
abstract = {The functionalization of C−H bonds is critical in organic syntheses. However, their direct functionalization under mild conditions is complicated by their inherent inertness. To address this challenge, decatungstates (W10O324−), as versatile, inexpensive, and easily accessible hydrogen-atom transfer (HAT) photocatalysts, have emerged as powerful catalysts that can activate inert C−H bonds under ultraviolet irradiation to generate carbon-centered radicals for constructing C−C, C−N, C−S, and C−F bonds. This review highlights recent advances in W10O324−-based photocatalysts and their applications in organic transformations. Overall, this article explores various W10O324−-photocatalyzed organic transformations. In addition to summarizing the reported literatures, it critically discusses the current challenges and offers insights for future developments in this promising research field.}
}