TY  - JOUR
AU  - Guo, Maokuan
AU  - Fu, Jie
AU  - Ma, Xiaohong
AU  - Xu, Huajian
AU  - Tian, Xiangyou
AU  - Jiao, Jingmeng
AU  - Guo, Wenqing
AU  - Lu, Jun
PY  - 2026
TI  - Bifunctional photo-assisted hybrid Zn-air battery for efficient solar power storage and glycerol upgrading
JO  - Nano Research
SN  - 1998-0124
SP  - 94907974
VL  - 19
IS  - 1
AB  - Photo-assisted Zn-air batteries (PZABs) hold promise for advancing sustainable energy systems. Herein, to address challenges associated with the cathode charging oxygen evolution reaction (OER), a photo-assisted hybrid Zn-air battery (PHZAB) was constructed by employing photoelectrocatalytic glycerol oxidation reaction (GOR), which is thermodynamically favorable as a replacement for OER during the charging process. Based on element doping and cocatalyst loading strategies, the CoFe-LDH/Mo:BiVO4 photoanode was fabricated. Systematic photoelectrochemical tests demonstrate its excellent performance, with a GOR current density of 4.78 mA·cm−2 at 1.23 V vs. RHE, 2.6 times that of the BiVO4, and an applied bias photon-to-current efficiency (ABPE) of 2.21%, 3.7 times that of the BiVO4. Further analysis proves that these modification strategies enhance bulk carrier density, accelerate surface catalytic reactions, and effectively suppress carrier recombination, thus enhancing the photoelectrochemical (PEC) performance. Benefiting from the excellent performance of the CoFe-LDH/Mo:BiVO4 photoanode and the novel hybrid device structure design, the PHZAB exhibits a maximum round-trip efficiency of 206% (at 0.5 mA·cm−2) and a 68.7% electricity saving ratio under 1 sun illumination. Even at 2 mA·cm−2, a 156% round-trip efficiency and 64.2% electricity saving ratio were maintained. During the photoassisted-charging process, the optimized CoFe-LDH/Mo:BiVO4 photoanode yields a high GOR performance of a total production rate of 225 mmol·m−2·h−1 and formic acid (FA) production rate of 133 mmol·m−2·h−1. This work presents a novel bifunctional system toward the rational design of functional devices and materials for simultaneously converting solar energy into chemical energy and enabling reversible solar power storage for on-demand release.
UR  - https://doi.org/10.26599/NR.2025.94907974
DO  - 10.26599/NR.2025.94907974