TY  - JOUR
AU  - Liu, Yihao
AU  - Zhao, Yanming
AU  - Han, Jiada
AU  - Sun, Xianglong
AU  - Yang, Huanhuan
AU  - Huang, Zhuo
AU  - Yan, Hao
AU  - Zhang, Man
AU  - Zhang, Shasha
AU  - Zhang, Yiqiang
AU  - Song, Yanlin
PY  - 2025
TI  - Metal–organic-framework-assisted inhibition of interface oxygen migration for exceptional thermal stability of perovskite solar cells
JO  - Nano Research
SN  - 1998-0124
SP  - 94907685
VL  - 18
IS  - 9
AB  - Formamidinium (FA)-based perovskite solar cells (PSCs) have emerged as one of the most promising candidates for next-generation photovoltaics due to their exceptional power conversion efficiency (PCE). However, their commercial deployment is hindered by poor stability, particularly under strict environmental stresses like high temperature, with interface degradation and ion migration being key challenges. In this work, we introduce metal–organic framework (MOF) materials composed of assembled Zr clusters and functional amino/sulfhydryl groups at the SnO2/perovskite interface within the n–i–p structure to address these issues. The incorporation of MOFs—specifically their robust framework with confined spatial structure and functional groups—plays a pivotal role in hindering oxygen migration from SnO2 to perovskite, leading to enhanced thermal stability of both perovskite films and PSCs. Furthermore, the anchoring of MOF on SnO2 and perovskite is essential for passivating interface defects, promoting perovskite crystallization, and reducing carrier recombination, all of which contribute to enhanced charge transport. As a result, the MOF-modified devices achieve a champion PCE of 25.22%, with the MOF-modified devices retaining 100% of their initial PCE after 2000 h of thermal aging at 85 °C in N2. This study highlights the structural integrity and functionality of MOFs for achieving high-performance and long-term stable PSCs.
UR  - https://doi.org/10.26599/NR.2025.94907685
DO  - 10.26599/NR.2025.94907685