@article{Zhang2025, 
author = {Ying Zhang and Chenchen Zhang and Chaofeng Chen and Junjun Mao and Qingqing Song and Yuanming Xie and Yongfa Zhu},
title = {The synergistic effect of organic molecules with copper anode material lowers the overall voltage for neutral CO2RR},
year = {2025},
journal = {Nano Research},
volume = {18},
number = {10},
pages = {94907555},
keywords = {anode, electrochemical, synergistic effect, CO product, neutral electrolytes},
url = {https://www.sciopen.com/article/10.26599/NR.2025.94907555},
doi = {10.26599/NR.2025.94907555},
abstract = {The primary objective in researching the anode side of electrochemical CO2 reduction reaction (CO2RR) is to substitute the frequently employed Ir anodic catalyst with more readily available and cost-effective non-noble metal oxide. When organic molecules are loaded on the Cu2O surface, a synergistic effect can be formed between different components. This effect can accelerate electron transfer, provide new active sites, and further enhance the performance of reactants of oxygen evolutionreaction (OER). This study proposes a new type of anodic catalyst, PDI/Cu2O/Cu, and investigates its OER activity and three other anodic catalysts (IrO2/Ti mesh, Ni foam, and Pt mesh) in the CO2RR system. The results show that PDI/Cu2O/Cu exhibited OER activity with an overpotential of 422.1 mV to drive a current density of 70 mA·cm−2 in neutral electrolytes. Compared to IrO2/Ti mesh, the overpotential of perylene tetracarboxylic di-(propyl imidazole) (PDI)/Cu2O/Cu is decreased by 490 mV. This significantly lowers the energy consumption of the CO2RR system without compromising the performance of CO2RR. Furthermore, the use of precious metal materials is unnecessary, leading to a substantial reduction in the cost of the anodic catalyst. PDI/Cu2O/Cu holds the potential to serve as a non-precious metal alternative to Ir in neutral electrolytes as an anodic catalyst.}
}