TY - JOUR AU - Yuan, Hao AU - Hu, Shixun AU - Zhou, Yao AU - Yuan, Chao AU - Song, Wenbo AU - Shao, Qing AU - Shi, Hongwei AU - Li, Juan AU - Hu, Jun AU - Li, Qi AU - He, Jinliang PY - 2024 TI - Enhanced Electrical Properties of Styrene-grafted Polypropylene Insulation for Bulk Power Transmission HVDC Cables JO - CSEE Journal of Power and Energy Systems SN - 2096-0042 SP - 361 EP - 370 VL - 10 IS - 1 AB - Polypropylene (PP) is considered to be a rather promising material for HVDC cable insulation. Grafting modification has proved to be an effective method on the electrical property improvements of PP. This paper reports on the highly-enhanced electrical properties of styrene-grafted polypropylene (PP-g-St) and their related mechanism. The influence of grafting styrene on crystallization structures, thermal properties and electrical properties of PP-g-St are characterized and analyzed. These results show that PP-g-St exhibits remarkably enhanced DC volume resistivity, suppressed space charge accumulation and improved DC breakdown strengths as compared to PP. Crystallization observation shows PP-g-St has small, imperfect spherulites with indistinct boundaries, which is strongly correlated to enhanced electrical properties. This study provides an effective grafting strategy to design high-performance HVDC cable insulation materials for bulk power transmission systems. UR - https://doi.org/10.17775/CSEEJPES.2021.00850 DO - 10.17775/CSEEJPES.2021.00850