@article{Xiao2024, 
author = {Fengping Xiao and Xianggao Meng and Longsheng Wang and Jian Hao and Chunlin Lv and Yongge Wei},
title = {Polyoxometalatocrown ether: A new type of metallacrown ether based on polyoxometalate},
year = {2024},
journal = {Polyoxometalates},
volume = {3},
number = {2},
pages = {9140055},
keywords = {crystal structure, polyoxometalates, crown ethers, organic ammonium cations},
url = {https://www.sciopen.com/article/10.26599/POM.2024.9140055},
doi = {10.26599/POM.2024.9140055},
abstract = {Using chain-like polyethers consisting of two terminal –NH2 groups and (TBA)4[α-Mo8O26] as starting materials, two polyoxometalatocrown ethers were prepared by a cyclization reaction through the formation of Mo≡N triple bonds: (TBA)2[Mo6O17N(o-C6H4OCH2(CH2OCH2)nCH2OC6H4-o)N] (compounds 1, n = 1; 2, n = 2). As confirmed by single-crystal X-ray diffraction and infrared (IR) studies, the polyoxometalatocrown ether 2 can capture primary ammonium cations in solid state.}
}